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Corrosion Inhibition of Aluminium by Deposition of Polypyrrole and Silane Compounds


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1 Autonomous University of Madrid, Department of Applied Chemistry Fisica. cantoblanco s / n 28049 Madrid, Spain
     

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In this work it has been studied the electrodeposition of polypyrrole over 2024-T3 aluminum electrodes and deposition of silanes of short and long chain, either at the aluminum surface as over the deposited polypyrrole. It has been analyzed the inhibition that these deposits present towards corrosion in aggressive media, such as a 3 % NaCl solution. Results show that deposits composed by polypyrrole and long chain silanes conduct to a better protection as a result of their low porosity. This characteristic allows the insertion of chloride ions nor permits oxygen diffusion to the substrate’s surface.

Keywords

Polypyrrole and Silone Compound Aluminium.
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  • Corrosion Inhibition of Aluminium by Deposition of Polypyrrole and Silane Compounds

Abstract Views: 410  |  PDF Views: 1

Authors

E. Mazario
Autonomous University of Madrid, Department of Applied Chemistry Fisica. cantoblanco s / n 28049 Madrid, Spain
L. Cabrera
Autonomous University of Madrid, Department of Applied Chemistry Fisica. cantoblanco s / n 28049 Madrid, Spain
P. Herrasti
Autonomous University of Madrid, Department of Applied Chemistry Fisica. cantoblanco s / n 28049 Madrid, Spain

Abstract


In this work it has been studied the electrodeposition of polypyrrole over 2024-T3 aluminum electrodes and deposition of silanes of short and long chain, either at the aluminum surface as over the deposited polypyrrole. It has been analyzed the inhibition that these deposits present towards corrosion in aggressive media, such as a 3 % NaCl solution. Results show that deposits composed by polypyrrole and long chain silanes conduct to a better protection as a result of their low porosity. This characteristic allows the insertion of chloride ions nor permits oxygen diffusion to the substrate’s surface.

Keywords


Polypyrrole and Silone Compound Aluminium.