Asian Journal of Research in Chemistry

Open Access Open Access  Restricted Access Subscription Access
Open Access Open Access Open Access  Restricted Access Restricted Access Subscription Access

Research into the Sorption of Perrhenate Ions by Aminoquinoid Redox-Polymers


Affiliations
1 JSC Institute of Chemical Sciences named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Kazakhstan
     

   Subscribe/Renew Journal


The synthesis features and the properties of an aminоquinoid redox-polymer based on Polyethyleneimine and Chloranil have been studied. The structure of a redox-polymer so obtained has been corroborated by elemental analysis and IR-spectroscopy data. The sorption capacity of samples with respect to perrhenate ions has been studied through polarography. Sorption has been observed on the basis of model solutions NH4ReO4, at different pH, various concentrations of primary solutions and different duration of exposure. Comparative data in respect of the sorption of perrhenate ions by industrial designs are set forth herein.

Keywords

Quinone, Polyamine, Redox-Polymers, Sorption, Polarography, Rhenium (VII).
Subscription Login to verify subscription
User
Notifications
Font Size


  • Snurnikov AP. Kompleksnoe ispol'zovanie syr'ja v cvetnoj metallurgii. M.: Metallurgija. 1977: 272 (In Russian).

  • Abisheva ZS, Zagorodnjaja AN, Ospanov NA i dr. Issledovanie sorbcii renija iz proizvodstvennyh rastvorov promyvnoj sernoj kisloty Balhashskogo medeplavil'nogo zavoda na anionite A170. Cvetnye metally. 7; 2012: 57-61 (In Russian).

  • Zagorodnyaya AN, Abisheva ZS, Sharipova AS aa. Sorption of rhenium and uranium by strong base anion exchange resin from solutions with different anion compositions. Hydrometallurgy. 131/132; 2013: 127–132.

  • Lebedev KB, Kazancev EI, Rozmanov V.M. i dr. Ionity v cvetnoj metallurgii. M.: Metallurgija. 1975: 352 (In Russian).

  • Troshkina ID, Khaing HN, Ushanova ON i dr. Izvlechenie renija iz sernokislyh rastvorov aktivnymi ugljami. Zhurn. prikl. him. 79; 2006:1435-1438 (In Russian).

  • Abisheva ZS, Zagorodnjaja AN, Sadykanova S.Je. i dr. Vlijanie soderzhanija DVB v anionite AN-21 i krupnosti ego zeren na sorbciju renija i urana iz individual'nyh rastvorov i rastvorov ih sovmestnogo prisutstvija. Kompleksnoe ispol'zovanie mineral'nogo syr'ja. 4; 2011: 16-23 (In Russian).

  • Zagorodnjaja AN, Lebedev KB. Vlijanie koncentracii i vneshnego rastvora, temperatury i diametra zerna anionitom AN21h16 na kinetiku sorbcii renija. Trudy Kazmehanobra. AlmaAta. 3; 1970: 101-112 (In Russian).


Abstract Views: 271

PDF Views: 2




  • Research into the Sorption of Perrhenate Ions by Aminoquinoid Redox-Polymers

Abstract Views: 271  |  PDF Views: 2

Authors

B. A. Mukhitdinova
JSC Institute of Chemical Sciences named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Kazakhstan
E. E. Ergozhin
JSC Institute of Chemical Sciences named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Kazakhstan
A. I. Nikitina
JSC Institute of Chemical Sciences named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Kazakhstan
K. Kh. Khakimbolatova
JSC Institute of Chemical Sciences named after A. B. Bekturov, 106, Sh. Ualichanov Str., 050010 Almaty, Kazakhstan

Abstract


The synthesis features and the properties of an aminоquinoid redox-polymer based on Polyethyleneimine and Chloranil have been studied. The structure of a redox-polymer so obtained has been corroborated by elemental analysis and IR-spectroscopy data. The sorption capacity of samples with respect to perrhenate ions has been studied through polarography. Sorption has been observed on the basis of model solutions NH4ReO4, at different pH, various concentrations of primary solutions and different duration of exposure. Comparative data in respect of the sorption of perrhenate ions by industrial designs are set forth herein.

Keywords


Quinone, Polyamine, Redox-Polymers, Sorption, Polarography, Rhenium (VII).

References