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Novel synthesis, characterization and antimicrobial activities of coordination compounds of Titanium and Zirconium with Schiff base


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1 Department of Chemistry, Banasthali Vidyapith, Tonk- Newai Rajasthan-304022, India
     

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The titanium(IV) and Zirconium(IV) complexes derived from Schiff base [(Z)-2-(1-(4-((4-methyl-3Hbenzo[b][1,4]diazepin-2-yl)oxy)phenyl)ethylidene)hydrazine-1-carboxamide] are reported and characterized based on (Infra-red) IR spectra, 1H NMR spectra, mass spectra. Complexes were found to possess 1:2 (metal:ligand) stoichiometry. The prepared ligands were act as bidentate ligands. The synthesized ligand, in comparison to their titanium(IV) and zirconium(IV) complexes, were screened for antimicrobial activity.

Keywords

Schiff bases, titanium(IV) complexes, zirconium(IV) complexes, IR spectra, 1H NMR spectra, mass spectra, anti-microbial activity.
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  • Novel synthesis, characterization and antimicrobial activities of coordination compounds of Titanium and Zirconium with Schiff base

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Authors

Priyanka Ghanghas
Department of Chemistry, Banasthali Vidyapith, Tonk- Newai Rajasthan-304022, India
Anita Choudhary
Department of Chemistry, Banasthali Vidyapith, Tonk- Newai Rajasthan-304022, India
Kavita Poonia
Department of Chemistry, Banasthali Vidyapith, Tonk- Newai Rajasthan-304022, India

Abstract


The titanium(IV) and Zirconium(IV) complexes derived from Schiff base [(Z)-2-(1-(4-((4-methyl-3Hbenzo[b][1,4]diazepin-2-yl)oxy)phenyl)ethylidene)hydrazine-1-carboxamide] are reported and characterized based on (Infra-red) IR spectra, 1H NMR spectra, mass spectra. Complexes were found to possess 1:2 (metal:ligand) stoichiometry. The prepared ligands were act as bidentate ligands. The synthesized ligand, in comparison to their titanium(IV) and zirconium(IV) complexes, were screened for antimicrobial activity.

Keywords


Schiff bases, titanium(IV) complexes, zirconium(IV) complexes, IR spectra, 1H NMR spectra, mass spectra, anti-microbial activity.

References