Asian Journal of Research in Chemistry

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Synthesis and Characterization of new Dithiocarbamate Complexes


Affiliations
1 Dept. of Chemistry, Sri Krishnadevaraya University, Anantapur, A.P, India
     

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New series of bidentate ligands such as dithocarbamates of 2-Amino-3-Methyl pyridine (2A3MPDTC) and 2- Amino-4-Methyl pyridine (2A4MPDTC) were prepared by new synthetic methods as their sodium salts. In the reaction of Copper Chloride and Cobalt Chloride with 2A3MPDTC and 2A4MPDTC the corresponding complexes were prepared. The complexes were characterized by elemental analysis, IR, 1H NMR, UV, ESR and TGA - DTA. These metal complexes play a good activity against E. coli and Basillus subtilis. The investigations revealed that the complexes are better anti-bacterial agents than the Ligands.

Keywords

2–amino–3–methyl Pyridine, 2–amino–4–methyl Pyridine, Copper Chloride, Cobalt Chloride, Dithiocarbamates, Synthesis, Characterization, Anti Bacterial Activity
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  • Synthesis and Characterization of new Dithiocarbamate Complexes

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Authors

K. Venugopal
Dept. of Chemistry, Sri Krishnadevaraya University, Anantapur, A.P, India
P. Sivajyothi
Dept. of Chemistry, Sri Krishnadevaraya University, Anantapur, A.P, India
P. Ashok Gajapathi Raju
Dept. of Chemistry, Sri Krishnadevaraya University, Anantapur, A.P, India
J. Sreeramulu
Dept. of Chemistry, Sri Krishnadevaraya University, Anantapur, A.P, India

Abstract


New series of bidentate ligands such as dithocarbamates of 2-Amino-3-Methyl pyridine (2A3MPDTC) and 2- Amino-4-Methyl pyridine (2A4MPDTC) were prepared by new synthetic methods as their sodium salts. In the reaction of Copper Chloride and Cobalt Chloride with 2A3MPDTC and 2A4MPDTC the corresponding complexes were prepared. The complexes were characterized by elemental analysis, IR, 1H NMR, UV, ESR and TGA - DTA. These metal complexes play a good activity against E. coli and Basillus subtilis. The investigations revealed that the complexes are better anti-bacterial agents than the Ligands.

Keywords


2–amino–3–methyl Pyridine, 2–amino–4–methyl Pyridine, Copper Chloride, Cobalt Chloride, Dithiocarbamates, Synthesis, Characterization, Anti Bacterial Activity

References