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Bijender,
- Electrochemical Properties of Fullerene C60 and C70
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Authors
Bijender
1
Affiliations
1 CMJ University, Meghalaya
1 CMJ University, Meghalaya
Source
Asian Journal of Research in Chemistry, Vol 6, No 1 (2013), Pagination: 11-16Abstract
The electrochemical properties of Ni, Pd, and Pt complexes with fullerenes were studied most thoroughly and systematically; this is why the analysis of these results allows one to elucidate the dependence of the electronic structure of complexes on such factors as the nature of metal and the metal-bound ligands, the number of added metallofragments. The progress in the synthesis of various fullerene complexes in tandem with studying their electrochemical properties make it possible to choose the best objects for studying the prospects of their application as the catalysts of different processes and also as the components for the development of materials and devices for molecular electronics.Keywords
Fullerenes, metallofragments C60, C70
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- Electronic Structure of Fullerene C60 and C70
Abstract Views :265 |
PDF Views:2
Authors
Bijender
1
Affiliations
1 CMJ University, Meghalaya
1 CMJ University, Meghalaya
Source
Asian Journal of Research in Chemistry, Vol 6, No 8 (2013), Pagination: 722-726Abstract
Among the properties of fullerenes that can be related to their electronic structure and their symmetry, the optical properties are of particular relevance in view of the potential applications that might be based on them, such as the production of fullerene-based optical limiters. In this contribution we review the optical properties of the two most abundant fullerenes, C60 and C70 by focusing on electronic spectroscopy studies carried out in solution, noble gas matrices or in the gas phase, in other words in conditions where the properties of approximately isolated molecules can be monitored. These spectroscopic studies represent an important source of information about the effect of intramolecular couplings, although the interactions with the solvent will also cause significant with the results of quantumchemical computational studies carried out on isolated fullerene molecules perturbations that appear in the spectra. On the other hand, these spectroscopic data are directly comparable.Keywords
Fullerenes, C60, C70, Electronic Structure, IcosahedralReferences
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