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Authors
Affiliations
1 Chemistry Research Laboratory, Patkar College, Goregaon (W), Mumbai 400 062, IN
2 Chemistry Research Laboratory, Patkar College, Goregaon (W), Mumbai 400 062
3 Department of Chemistry, Willingdon College, Sangli, Maharashtra, IN
Source
Asian Journal of Research in Chemistry, Vol 4, No 12 (2011), Pagination: 1861-1863
Abstract
The kinetics of oxidation of the Schiff base 2-hydroxy - 1 - Naphthalidene anil and substituted anils such as 2' - methoxy - 2 - hydroxy - 1 - naphthalidene anil, 3' - Methoxy - 2 - Hydroxy - 1 - Naphthalidene anil and 4' - Methoxy - 2 - Hydroxy - 1- Naphthalidene anil by Ce (IV) as oxidant in aqueous sulphuric acid medium. The kinetic study is carried out by using various concentrations of oxidants and the substrates, which is found to be the first order reaction. A suitable plaussible mechanism has been suggested on the basis of kinetic results.
Keywords
Kinetics of Oxidation, Schiff Base, Redox System, Reaction Mechanism.
