Open Access Open Access  Restricted Access Subscription Access

Evaluation of Inorganic Fractions of Arsenic in Relation to Soil Properties in Affected Areas of West Bengal, India


Affiliations
1 Department of Soil Science and Agricultural Chemistry, Uttar Banga Krishi Viswavidyalaya, Pundibari, Cooch Behar 736 165, India
2 Department of Agricultural Chemistry and Soil Science, Bidhan Chandra Krishi Viswavidyalaya, Mohanpur, Nadia 741 252, India
 

Inorganic soil arsenic (As) in three soils was fractionated adopting phosphorus fractionation schemes. Among these fractions, iron-bound arsenic (Fe-As) was found highest, followed by aluminium-bound arsenic (Al-As). The freely exchangeable arsenic was relatively small compared to the arsenic held by internal surfaces of soil aggregates. The arsenic fractions exhibited positive correlation with phosphorus content presumably due to the fact that high P in soil releases more arsenic from soil adsorption sites owing to the competition for the same adsorption sites. Predominantly, negative correlation of arsenic with organic carbon confirms the fact of lowering of arsenic mobility in presence of organics in soil.

Keywords

Arsenic Fractions, Arsenic Extractants, Soil Properties, Resin Extractable Arsenic.
User
Notifications
Font Size

  • Mandal, B. K. and Suzuki, K. T., Arsenic round the world: a review. Talanta, 2002, 58, 201–235.
  • Sanyal, S. K. and Dhillon, K. S., Arsenic and selenium dynamics in water–soil–plant system: a threat to environmental quality. Invited Lead Lecture. In Proceedings of the International Conference on Soil Water and Environmental Quality: Issues and Strategies, New Delhi, India, 2005, Indian Society of Soil Science, New Delhi, pp. 239–263.
  • Sanyal, S. K, Jeevan Rao, K. and Sadana, U. S., Toxic elements and other pollutants – a threat to nutritional quality. In Soil Science in Service of Nation (eds Goswami, N. et al.), Indian Society of Soil Science, New Delhi, 2012, pp. 266–291.
  • Sanyal, S. K., Gupta, S. K., Kukal, S. S. and Jeevan Rao, K., Soil degradation, pollution and amelioration. In State of Indian Agriculture – Soil (eds Pathak, H., Sanyal, S. K. and Takkar, P. N.), National Academy of Agricultural Sciences (India), New Delhi, 2015, pp. 234-266.
  • Das, I., Ghosh, K., Das, D. K. and Sanyal, S. K., Transport of arsenic in some affected soils of Indian sub-tropics. Soil Res., 2014, 52, 822–832.
  • Ashjaei, S., Miller, W. P., Cabrera, M. L. and Hassan, S. M., Arsenic in soils and forages from poultry litter – amended pastures. Int. J. Environ. Res. Public Health, 2011, 8, 1534–1546.
  • Girouard, E. and Zagury, G. J., Arsenic bioaccessibility in CCAcontaminated soils: influence of soil properties arsenic fractionation and particle-size fraction. Sci. Total Environ., 2009, 407, 2576–2585.
  • Huang, R. Q., Gao, S. F., Wang, W. L., Staunton, S. and Wangm, G., Soil arsenic availability and the transfer of soil arsenic to crops in suburban areas in Fujian province southeast China Sci. Total Environ., 2006, 368, 531–541.
  • Asagba, E. U., Okieimen, F. E. and Osokpor, J., Screening and speciation of heavy metal contaminated soil from an automobile spare-part market. Chem. Spec. Bioavail., 2007, 19, 9–15.
  • Vacha, R., Macurova, H., Sakala, J. and Cechmankova, J., Evaluation of methods for determination of selected arsenic forms in soils. Pedologist, 2011, 302–313.
  • Wenzel, W. W., Kirchbaumer, N., Prohaska, T., Stingeder, G., Lombi, E. and Adriano, D. C., Arsenic fractionation in soils using an improved sequential extraction procedure. Anal. Chim. Acta, 2001, 436, 309–323.
  • Chang, S. C. and Jackson, M. L., Fractionation of soil phosphorus. Soil Sci., 1957, 84, 133–144.
  • Johnston, S. E. and Barnard, W. M., Comparative effectiveness of fourteen solutions for extracting arsenic from Western New York soils. Soil Sci. Soc. Am. J., 1979, 43, 304–308.
  • McLaren, R. G., Naidu, R., Smith, J. and Tiller, K. G., Fractionation and distribution of arsenic in soils contaminated by cattle dip. J. Environ. Qual., 1998, 27, 348–354.
  • Das, I., Ghosh, K., Das, D. K. and Sanyal, S. K., Studies on fractionation of arsenic in soil in relation to crop Uptake. Soil Sediment Contam., 2011, 20, 790–809.
  • Page, A. L., Miller, R. H. and Keeney, D. R., Methods of Soil Analysis, Part 2: Chemical and Microbiological Properties, ASA and SSSA, Madison, Wisconsin, 2nd edn, 1982.
  • Sparks, D. L. et al., Methods of Soil Analysis. Part 3. Chemical Methods (ed. Sparks, D. L.), Soil Science Society of America, Inc., American Society of Agronomy, Inc.: Madison, Wisconsin, 1996.

Abstract Views: 357

PDF Views: 132




  • Evaluation of Inorganic Fractions of Arsenic in Relation to Soil Properties in Affected Areas of West Bengal, India

Abstract Views: 357  |  PDF Views: 132

Authors

G. C. Banik
Department of Soil Science and Agricultural Chemistry, Uttar Banga Krishi Viswavidyalaya, Pundibari, Cooch Behar 736 165, India
S. K. Sanyal
Department of Agricultural Chemistry and Soil Science, Bidhan Chandra Krishi Viswavidyalaya, Mohanpur, Nadia 741 252, India

Abstract


Inorganic soil arsenic (As) in three soils was fractionated adopting phosphorus fractionation schemes. Among these fractions, iron-bound arsenic (Fe-As) was found highest, followed by aluminium-bound arsenic (Al-As). The freely exchangeable arsenic was relatively small compared to the arsenic held by internal surfaces of soil aggregates. The arsenic fractions exhibited positive correlation with phosphorus content presumably due to the fact that high P in soil releases more arsenic from soil adsorption sites owing to the competition for the same adsorption sites. Predominantly, negative correlation of arsenic with organic carbon confirms the fact of lowering of arsenic mobility in presence of organics in soil.

Keywords


Arsenic Fractions, Arsenic Extractants, Soil Properties, Resin Extractable Arsenic.

References





DOI: https://doi.org/10.18520/cs%2Fv111%2Fi8%2F1371-1377