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One-Step Production of Biodiesel from Waste Cooking Oil Catalysed by So3H-Functionalized Quaternary Ammonium Ionic Liquid


Affiliations
1 College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China
 

The catalytic conversion of waste cooking oil (WCO) with high acid value (120.37 mg KOH/g) to biodiesel has been studied in low-cost SO3H-functionalized quaternary ammonium ionic liquid as catalyst. The ionic liquid (IL) catalyst was efficient in catalysing the simultaneous esterification and transesterification reactions of WCO and methanol. Moreover, it can be separated and reused for six cycles without any significant decrease in the biodiesel yield. Under the optimal reaction conditions (methanol/oil/IL molar ratio = 10 : 1 : 0.063, 120°C, 1 h), a maximum biodiesel yield of 95% was achieved.

Keywords

Biodiesel, Esterification and Transesterification, Ionic Liquid, Waste Cooking Oil.
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  • One-Step Production of Biodiesel from Waste Cooking Oil Catalysed by So3H-Functionalized Quaternary Ammonium Ionic Liquid

Abstract Views: 373  |  PDF Views: 108

Authors

Jing-Juan Qi
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China
Jin-Qing Lin
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China
Hong-Quan Fu
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China

Abstract


The catalytic conversion of waste cooking oil (WCO) with high acid value (120.37 mg KOH/g) to biodiesel has been studied in low-cost SO3H-functionalized quaternary ammonium ionic liquid as catalyst. The ionic liquid (IL) catalyst was efficient in catalysing the simultaneous esterification and transesterification reactions of WCO and methanol. Moreover, it can be separated and reused for six cycles without any significant decrease in the biodiesel yield. Under the optimal reaction conditions (methanol/oil/IL molar ratio = 10 : 1 : 0.063, 120°C, 1 h), a maximum biodiesel yield of 95% was achieved.

Keywords


Biodiesel, Esterification and Transesterification, Ionic Liquid, Waste Cooking Oil.



DOI: https://doi.org/10.18520/cs%2Fv110%2Fi11%2F2129-2134