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Atomic Hydrogen Storage in a Two-Dimensional Hydrogenated Diamond-Like Carbon Film


Affiliations
1 Centre for Indological Studies and Research, The Ramakrishna Mission Institute of Culture, Gol Park, Kolkata 700 029, India
 

The present communication describes the two-dimensional hydrogenated diamond-like carbon (2D-HDLC) film as a system for storing atomic hydrogen, having hydrogen content in atomic per cent ~37.5 corresponding to gravimetric density of hydrogen ~5.8 wt%.

Keywords

Graphane, Gravimetric Density, Green Fuel, Hydrogen Storage.
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  • Schlapbach, L. and Zϋttel, A., Hydrogen-storage materials for mobile applications. Nature, 2001, 414, 353–358.

  • Das, A. K., Fundamental Concepts of Inorganic Chemistry-Part II, CBS Publishers & Distributors, New Delhi, 2004, pp. 838–846.

  • Strobel, R. et al., Hydrogen storage by carbon materials. J. Power Sources, 2006, 159, 781–801.

  • D.O.E. Office of Energy Efficiency and Renewable Energy Hydrogen, Fuel cells and infrastructure technologies program multiyear research, development and demonstration plan. Available at https://energy.gov/sites/prod/files/2015/05/f22/fcto_myrdd_storage.pdf (accessed on 12 July 2016).

  • Robertson, J., Diamond-like carbon. Pure Appl. Chem., 1994, 66, 1789–1796.

  • Grill, A., Diamond-like carbon: state of the art. Diamond Relat. Mater., 1999, 8, 428–434.

  • Zeng, A., Diamond-like carbon (DLC) films as electrochemical electrodes. Diamond Relat. Mater., 2014, 43, 12–22.

  • Steele, B. C. H. et al., Materials for fuel-cell technologies. Nature, 2001, 414, 345–352.

  • Novoselov, K. S. et al., Electric field effect in atomically thin carbon films. Science, 2004, 306, 666–669.

  • Sofo, J. O. et al., Graphane: a two-dimensional hydrocarbon. Phys. Rev. B, 2005, 75, 153401-1–153404-4.

  • Elias, D. C. et al., Control of graphene’s properties by reversible hydrogenation: evidence for graphane. Science, 2009, 323, 610–613.

  • Savchenko, A., Transforming graphene. Science, 2009, 323, 589–590.

  • Srinivas, G. et al., Graphene-based materials: synthesis and gas sorption, storage and separation. Prog. Mater. Sci., 2015, 69, 1–60.

  • Ray, N. R. et al., In search of graphane – a two-dimensional hydrocarbon. Cond. Mat. Mtrl. Sci., 2008, preprint; arXiv: 0802-3998v1.

  • Biswas, H. S. et al., Covalent immobilization of protein onto a functionalized hydrogenated diamond-like carbon substrate, Langmuir, 2010, 26, 17413–17418.

  • Datta, J. et al., Structure of hydrogenated diamond like carbon by micro-Raman spectroscopy. Mater. Lett., 2012, 71, 131–133.

  • Ray, N. R. et al., Signature of misoriented bilayer graphene-like and graphane-like structure in the hydrogenated diamond like carbon film. IEEE Trans. Plasma Sci., 2012, 40, 1789–1793.

  • Tuinstra, F., Raman spectrum of graphite. J. Chem. Phys., 1970, 53, 1126–1130.

  • Lifshitz, Y. et al., Visualization of diamond nucleation and growth from energetic species. Phys. Rev. Lett., 2004, 93, 056101-1–056101-4.

  • Murooka, Y. et al., Electron energy loss spectroscopy of carbon films prepared by electron cyclotron resonance plasma sputtering. Mater. Trans., 2002, 43, 2092–2096.

  • Openov, L. A. and Podlivaev, A. I., Thermal desorption of hydrogen from graphane. Cond. Mat. Mes-Hall, 2010, preprint; arXiv: 1001-1124v1.

  • Antipina, L. Y. et al., High hydrogen-adsorption-rate material based on graphane decorated with alkali metals. Phys. Rev. B, 2012, 86, 085435-1–085435-7.

  • Hussain, T. et al., Calcium doped graphane as a hydrogen storage material. Appl. Phys. Lett., 2012, 100, 183902-1–183902-5.

  • Singha, A. et al., Quantative analysis of hydrogenated diamondlike carbon films by visible Raman spectroscopy. J. Appl. Phys., 2006, 100, 044910-1–044910-8.

  • Nebesny, K. W. et al., Quantitation of auger and X-ray photoelectron spectroscopies. Anal. Chem., 1989, 61, 469A–477A.

  • Liech, D. A. et al., A technique for measuring hydrogen concentration versus depth in solid samples. Nucl. Instrum. Methods, 1973, 108, 67–71.

  • Ziegler, J. F., Profiling hydrogen in materials using ion beams. Nucl. Instrum. Methods, 1978, 149, 19–39.

  • Datta, J. et al., Study of depth profile of hydrogen in hydrogenated diamond like carbon thin film using ion beam analysis techniques. Nucl. Inst. Methods Phys. Res. B, 2014, 328, 27–32.

  • Spyrou, K. et al., Hydrogen storage in graphene-based materials: efforts towards enhanced hydrogen absorption. ECS J. Solid State Sci. Technol., 2013, 2, M3160–M3169.


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  • Atomic Hydrogen Storage in a Two-Dimensional Hydrogenated Diamond-Like Carbon Film

Abstract Views: 290  |  PDF Views: 117

Authors

Nihar Ranjan Ray
Centre for Indological Studies and Research, The Ramakrishna Mission Institute of Culture, Gol Park, Kolkata 700 029, India

Abstract


The present communication describes the two-dimensional hydrogenated diamond-like carbon (2D-HDLC) film as a system for storing atomic hydrogen, having hydrogen content in atomic per cent ~37.5 corresponding to gravimetric density of hydrogen ~5.8 wt%.

Keywords


Graphane, Gravimetric Density, Green Fuel, Hydrogen Storage.

References





DOI: https://doi.org/10.18520/cs%2Fv112%2Fi07%2F1564-1567