Current Science

Open Access Open Access  Restricted Access Subscription Access

Removal of Colour and Chemical Oxygen Demand from Textile Effluent by Fenton Oxidation Method


Affiliations
1 Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
 

The main objective of this study is to focus on the removal of colour and chemical oxygen demand (COD) from the secondary treated effluent (SE) and reverse osmosis (RO) concentrate, using Fenton oxidation as an advanced oxidation process. In order to identify the feasibility and economics, the experiments were conducted in these two streams of the textile-based effluent treatment plant. In this study, COD and colour removal efficiencies were observed as 75% and 94% in the SE and 85% and 99% in the RO concentrate respectively. After comparing the operating cost between these two streams, treating of SE with Fenton oxidation was found to be an economical, sustainable option for removing the colour and COD from the SE. This option will improve the performance of membrane filtration systems in effluent treatment plants that are based on zero liquid discharge.

Keywords

Chemical Oxygen Demand, Colour, Fenton, Textile Effluent, ZLD.
User
Notifications
Font Size

  • Carmen, Z. and Daniela, S., Textile organic dyes – characteristics, polluting effects and separation/elimination procedures from industrial effluents – a critical overview, In Tech, 2012, pp. 55–79.

  • Schrank, S. G., Santos, J. N. R., Dos, Souza, D. S. and Souza, E. E. S., Decolourisation effects of Vat Green 01 textile dye and textile wastewater using H2O2/UV process. J. Photochem. Photobiol. A: Chem., 2007, 186, 125–129.

  • Correia, V. M., Stephenson, T. and Judd, S. J., Characterization of textile wastewaters – a review. Environ. Technol., 1994, 15, 917–929.

  • Allegre, C., Maisseu, M., Charbit, F. and Moulin, P., Coagulation–flocculation–decantation of dye house effluents: concentrated effluents. J. Hazard. Mater., 2004, 116, 57–64.

  • Banat, I. M., Nigam, P., Singh. D. and Marchant, R., Microbial decolourization of textile dye containing effluents: a review. Biores. Technol., 1996, 58, 217–227.

  • Sundararaman, T. R., .Ramamurthi, V. and Partha, N., Decolourization and COD removal of reactive yellow 16 by Fenton oxidation and comparison of dye removal with photo Fenton and sono Fenton process. Mod. Appl. Sci., 2009, 3, 15–22.

  • Robinson, T., McMullan, G., Marchant, R. and Nigam, P., Remediation of dyes in textile effluents: a critical review on current treatment technologies with a proposed alternative. Bioresour. Technol., 2001, 77, 247–255.

  • Kuo, W. G., Decolorizing dye wastewater with Fenton’s reagent. Water Res., 1992, 26, 881–886.

  • Mahmud, K., Hossain, M. D. and Ahmed, S., Advanced landfill leachate treatment with least sludge production using modified Fenton process. Int. J. Env. Sci., 2011, 2, 259–270.

  • Soon, A. N. and Hameed, B. H., Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo assisted Fenton process. Desalination, 2011, 269, 1–16.

  • Bahmani, P., Kalantary, R. R., Esrafili, A., Gholami, M. and Jafari, A. J., Evaluation of Fenton oxidation process coupled with biological treatment for the removal of reactive black 5 from aqueous solution. J. Environ. Health Sci. Eng., 2013, 11, 1–9.

  • Miller, C. M., Valentine, R. L., Roehl, M. E. and Alvarez, P. J. J., Chemical and microbiological assessment of pendimethalincontaminated soil after treatment with Fenton’s reagent. Water Res., 1996, 30, 2579–2586.

  • Miled, W., Haj Said, A. and Roudesli, S., Decolourization of high polluted textile wastewater by indirect electrochemical oxidation process. J. Tex. Apparel Technol. Manage, 2010, 6, 1–6.

  • Metcalf and Eddy-Wastewater Engineering Treatment Disposal Reuse, Mc-Graw Hill, 2003, 4th edn, pp. 1037 and 1196.

  • Rande, V. and Bhandari, V. M., Industrial wastewater treatment recycling and Reuse. I. Chem. E, 1st edn, 2014.

  • Papic, S., Vujevic, D., Koprivanac, N. and Sinko, D., Decolourization and mineralization of commercial reactive dyes by using homogeneous and heterogeneous Fenton and UV/Fenton processes. J. Hazard. Mater., 2008, 164, 1137–1145.

  • Kang, Y. W., Cho, M. J. and Hwang, K. Y., Correction of hydrogen peroxide interference on standard chemical oxygen demand test. Water Res., 1999, 33, 1247–1251.

  • Yeh Ruth, Y. L. and Thomas, A., Color removal for dye wastewaters by adsorption using powdered activated carbon mass transfer studies. J. Chem. Technol. Biotechnol., 1995, 63, 48–54.

  • Kalyani, D. C., Patil, P. S., Jadhav, J. P. and Govindwar, S. P., Biodegradation of reactive textile dye red BLI by an isolated bacterium pseudomonas sp. SUK1. Bioresour. Technol., 2008, 99, 4635–4641.

  • Joshi, M., Bansal, R. and Purwar, R., Colour removal from textile effluent. Indian J. Fibre Text. Res., 2004, 29, 239–259.

  • Supaka, N., Juntongjin, K., Damronglerd, S., Delia, M. L. and Strehaiano, P., Microbial decolourization of reactive azo dyes in a sequential anaerobic–aerobic system. Chem. Eng. J., 2004, 99, 169–176.

  • Kim, Y. K. and Huh, I. R., Enhancing biological treatability of landfill leachate by chemical oxidation. Environ. Eng. Sci., 1997, 14, 73–79.

  • Perkowski, J. and Kos, L., Treatment of textile dyeing wastewater by hydrogen peroxide and ferrous ions. Fibres Text. Eastern Europe, 2002, 10, 78–81.

  • Mansoorian, H. J., Bazrafshan, E., Yari, A. and Alizadeh, M., Removal of azo dyes from aqueous solution using Fenton and modified Fenton processes. Health Scope, 2014, 3, 1–9.

  • Christopher, J. G., Franklin, J. C., Yoram, C. and Suffet, I. H., Reverse osmosis pre-treatment: challenges with conventional treatment, American Water Works Association (AWWA) Annual Conference and Exposition, 2004.

  • Sarria, V., Parra, S., Invernizzi, M., Péringer, P. and Pulgarin, C., Photochemical–biological treatment of a real industrial bio recalcitrant wastewater containing 5-amino-6-methyl-2-benzimidazolone. Water Sci. Technol., 2002, 44, 93–101.

  • Kang, S. F. and Chang, H. M., Coagulation of textile secondary effluents with Fenton’s reagent. Water Sci. Technol., 1997, 36, 215–222.

  • Fenton, H. J. H., Oxidation of tartaric acid in the presence of iron. J. Chem. Soc., 1894, 65, 899–910.

  • Mahmud, K., Hossain, M. D. and Shams, S., Different treatment strategies for highly polluted landfill leachate in developing countries, Waste Manage, 2012, 32, 2096–2105.

  • APHA, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington, DC, 1992, 18th edn.

  • Demir, G., Ozcan, H. K., Tufekci, N. and Borat, M., Decolourization of Remazol RR Gran by white rot fungus Phanerochaetechrysosporium, J. Environ. Biol., 2007, 28, 813–817.

  • Al-Kdasi, A., Idris, A., Saed, K. and Guan, C. T., Treatment of textile wastewater by advanced oxidation processes – a review. Global Nest Int. J., 2004, 6, 222–230.

  • Meric, S., Kaptan, D. and Hanci, T. O., Color and COD removal from wastewater containing reactive black 5 using Fenton’s oxidation process. Chemosphere, 2004, 54, 435–441.

  • Wang, S., Comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater. Dyes Pigments, 2008, 76, 714–720.

  • Ankita, P., Fenton process: a case study for treatment of industrial wastewater. Int. J. Innov. Emerg. Res. Eng., 2014, 2, 23–30.

  • Lucas, M. S., Dias, A. A., Sampaio, A., Amaral, C. and Peres, J. A., Degradation of a textile reactive Azo dye by a combined chemical–biological process: Fenton’s reagent-yeast. Water Res., 2007, 41, 1103–1109.

  • Han, Z., Dong, Y. and Dong, S., Copper–iron bimetal modified PAN fibre complexes as novel heterogeneous Fenton catalysts for degradation of organic dye under visible light irradiation. J. Hazar. Mater., 2011, 189, 241–248.


Abstract Views: 349

PDF Views: 128




  • Removal of Colour and Chemical Oxygen Demand from Textile Effluent by Fenton Oxidation Method

Abstract Views: 349  |  PDF Views: 128

Authors

K. Ramesh
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
M. Balakrishnan
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
B. Vigneshkumar
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
A. Manju
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
S. Dhanakumar
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
M. Palanivel
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India
K. Kalaiselvi
Department of Environmental Science, PSG College of Arts and Science, Coimbatore 641 014, India

Abstract


The main objective of this study is to focus on the removal of colour and chemical oxygen demand (COD) from the secondary treated effluent (SE) and reverse osmosis (RO) concentrate, using Fenton oxidation as an advanced oxidation process. In order to identify the feasibility and economics, the experiments were conducted in these two streams of the textile-based effluent treatment plant. In this study, COD and colour removal efficiencies were observed as 75% and 94% in the SE and 85% and 99% in the RO concentrate respectively. After comparing the operating cost between these two streams, treating of SE with Fenton oxidation was found to be an economical, sustainable option for removing the colour and COD from the SE. This option will improve the performance of membrane filtration systems in effluent treatment plants that are based on zero liquid discharge.

Keywords


Chemical Oxygen Demand, Colour, Fenton, Textile Effluent, ZLD.

References





DOI: https://doi.org/10.18520/cs%2Fv113%2Fi11%2F2112-2119