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Crystallization Evolution of Accessory Minerals in Palaeoproterozoic Granites of Bastar Craton, India
The Malanjkhand and Dongargarh granitoids are compared to study the role of accessory minerals (apatite, zircon, titanite and titanomagnetite) to understand crystallization evolution of Palaeoproterozoic granitic magmatism in the Bastar Craton, central India. Two varieties of titanite (magmatic and hydrothermal types) are observed in the Palaeoproterozoic granitoids. Occurrence of zircon, apatite, titanite and titanomagnetite as accessory phases in the Palaeoproterozoic granitoids indicates that the early stage of crystallization of granitic magma was saturated with Zr, P and Ti. Petrography and mineral equilibria reaction suggest that magmatic titanite in the Palaeoproterozoic granitoids was formed due to hydration of amphiboles and biotites which favours high f O2 and f H2O conditions. Apatite composition suggests that it was formed in the granitic magma at nearliquidus to near-solidus temperature (900–1000°C) which increased fugacity ratio log(fH2O/fHF) and also controlled the halogen budget during magma crystallization. Relatively high halogen content in the apatites from the Malanjkhand Granitoid (MG) indicates that the parental magma was enriched in F and Cl compared to Dongargarh Granitoids (DG), implying a dominant role of halogens in metal transportation and hydrothermal mineralization. In MG, apatite was the earl iest phase to be crystallized in granitic magma followed by zircon and titanite whereas, in DG, crystallization of zircon was followed by apatite and titanite. Two contemporaneous plutons, DG and MG, represent a unique Palaeoproterozoic granitic magmatism wherein early progressive crystallization is dominated by accessory mineral saturation in a relatively static environment with constant magma composition.
Keywords
Accessory Minerals, Bastar Craton, Dongargarh, Granite, Malanjkhand.
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- Watson, E. B. and Harrison, T. M., Accessory minerals and the geochemical evolution of crustal magmatic systems: a summary and prospectus of experimental approaches. Phys. Earth Planet. Int., 1984, 35, 19–30.
- Robinson, D. M. and Miller, C. F., Record of magma chamber processes preserved in accessory minerals assemblages, Aztec Wash pluton, Nevada. Am. Mineral., 1999, 84, 1346–1353.
- Piccoli, P. M., Candela, P. and Rivers, M., Interpreting magmatic processes from accessory phases: titanite – a small scale recorder of large-scale processes. Trans. R. Soc. Edinb. Earth Sci., 2000, 91, 25–267.
- Green, T. H. and Adam, J., Pressure effect on Ti- or P-rich accessory mineral saturation in evolved granitic melts with differing K2O/Na2O ratios. Lithos, 2002, 61, 271–282.
- Hanchar, J. M. and Watson, E. B., Zircon saturation thermometry. Rev. Mineral. Geochem., 2003, 53, 89–112.
- Miller, C. F., Meschter, S., Dowell, M. and Mapes, R. W., Hot and cold granites? Implication of zircon saturation temperatures and preservation of inheritance. Geology, 2003, 31, 529–532.
- Troitzsch, U. and Ellis, D. J., The synthesis and crystal structure of CaAlFSiO5, the Al–F analog of titanite. Am. Mineral., 1999, 84, 1162–1169.
- Troitzsch, U. and Ellis, D. J., Thermodynamic properties and stability of AlF-bearing titanite CaTiOSiO4–CaAlFSiO4. Contrib. Mineral. Petrol., 2002, 142, 543–563.
- Tropper, P., Manning, C. E. and Essene, E. J., The substitution of Al and F in titanite at high pressure and temperature: experimental constraints on phase relations and solid solution properties. J. Petrol., 2002, 43, 1787–1814.
- Piccoli, P. M. and Candela, P. A., Apatite in Igneous Systems. Phosphates–Geochemical, Geobiological and Materials Importance. Rev. Mineral. Geochem., 2002, 48, 255–292.
- Enami, M., Suzuki, K., Liou, J. G. and Bird, D. K., Al–Fe3+ and F–OH substitutions in titanite and constraints on their P–T dependence. Eur. J. Mineral., 1993, 5, 219–231.
- Xirouchakis, D. and Lindsley, D. H., Equilibria among titanite, hedenbergite, fayalite, quartz, ilmenite, and magnetite: experiments and internally consistent thermodynamic data for titanite. Am. Mineral., 1998, 83, 712–749.
- Broska, I., Harlov, D., Tropper, P. and Siman, P., Formation of magmatic titanite and titanite–ilmenite phase relations during granite alteration in the Tribec Mountains, Western Carpathians, Slovakia. Lithos, 2007, 95, 58–71.
- Harlov, D., Tropper, P., Seifert, W., Nijland, T. and Forster, H. J., Formation of Al-rich titanite (CaTiSiO4O–CaAlSiO4OH) reaction rims on ilmenite in metamorphic rocks as a function of fH2O and fO2. Lithos, 2006, 88, 72–84.
- Bonamici, C. E., Kozdon, R., Ushikubo, T. and Valley, J. W., Intragrain oxygen isotope zoning in titanite by SIMS: cooling rates and fluid infiltration along the Carthage–Colton Mylonite Zone, Adirondack Moundains, NY, USA. J. Metamorph. Geol., 2014, 32, 71–92.
- Ogasawara, Y., Fukasawa, K. and Maruyama, S., Coesite exsolution from supersilicic titanite in UHP marble from the Kokchetav Massif, northern Kazakhstan. Am. Mineral., 2002, 87, 454–461.
- Naqvi, S. M. and Rogers, J. J. W., Precambrian Geology of India, Oxford University Press, Oxford, 1987.
- Yedekar, D. B., Jain, S. C., Nair, K. K. K. and Dutta, K. K., The central Indian collision suture. Geol. Surv. India Spec. Publ., 1990, 28, 1–43.
- Acharyya, S. K., The nature of Mesoproterozoic Central Indian Tectonic Zone with exhumed and reworked older granulites. Gondwana Res., 2003, 6, 197–214.
- Sarkar, S. N., Stratigraphy and tectonics of the Dongargarh System, a new system in the Precambrians of Bhandara – Durg – Balaghat area, Bombay and Madhya Pradesh, Part-I. J. Sci. Eng. Res., 1957–58, 1, 237–268; 2, 145–160.
- Neogi, S., Miura, H. and Hariya, Y., Geochemistry of the Dongargarh volcanic rocks, Central India: implications for the Precambrian mantle. Precambrian Res., 1996, 76, 77–91.
- Sensarma, S. and Mukhopadhyay, D., New insight on the stratigraphy and volcanic history of the Dongargarh Belt, Central India. Gond. Geol. Magz. Spl., 2003, 7, 129–136.
- Sensarma, S. and Mukhopadhyay, D., Stratigraphy of the ~2.5 Ga Dongargarh belt, Central India: key observations and suggested revisions. Gond. Geol. Magz. Spl., 2014, 16.
- Sensarma, S., Hoernes, S. and Mukhopadhyay, D., Relative contributions of crust and mantle to the origin of the Bijli Rhyolite in a palaeoproterozoic bimodal volcanic sequence (Dongargarh Group), central India. Proc. Indian Acad. Sci. (Earth Planet. Sci.), 2004, 113, 619–648.
- Chakraborty, T. and Sensarma, S., Shallow marine and coastal eolian quartz arenites in the Neoarchean–Palaeoproterozoic Karutaola Formation, Dongargarh volcanoc-sedimentary succession, central India. Precambrian Res., 2008, 162, 284–301.
- Bandyopadhyay, B. K., Roy, A. and Huin, A. K., Structure and tectonics of a part of the central Indian shield. Geol. Soc. India, Memoir, 1990, 31, 433–467.
- Roy, A., Kagami, H., Yoshida, M., Roy, A., Bandyopadhyay, B. K. and Chattopadhyay, A., Rb/Sr and Sm/Nd dating of different metamorphic events from the Sausar mobile belt, central India: implications for Proterozoic crustal evolution. J. Asian Earth Sci., 2006, 26, 61–76.
- Srivastava, R. K. and Gautam, G. C., Precambrian mafic dyke swarms from the southern Bastar Central India craton: present and future perspectives. In Indian Dykes: Geochemistry, Geophysics, and Geochronology (eds Srivastava, R. K., Sivaji, C. and Chalapati Rao, N. V.), Narosa Publishing Ltd, New Delhi, 2008, pp. 367–376.
- Meert, J. G. et al., Precambrian crustal evolution of Peninsular India: A 3.0 billion year odyssey. J. Asian Earth Sci., 2010, 39, 483–515.
- Panigrahi, M. K., Naik, R. K., Pandit, D. and Misra, K. C., Reconstructing physico-chemical parameters of hydrothermal mineralization at the Malanjkhand copper deposit, India from mineral chemistry of biotite, chlorite and epidote. Geochem. J., 2008, 42, 443–460.
- Panigrahi, M. K., Pandit, D. and Naik, R. K., Genesis of the granitoid affiliated Paleoproterozoic copper-molybdenum deposit at Malanjkhand: a review of status. In Magmatism, Tectonism and Mineralization (ed. Kumar, S.), Macmillan Publisher Ltd, India, 2009, pp. 265–292.
- Panigrahi, M. K., Pandit, D., Moriyama, T. and Ishihara, S., Paleoproterozoic granite-ore systems in the perspective of crustal evolution: insights from the Malanjkhand copper deposit and surrounding granitoids in the Central Indian craton. In Smart Science for Exploration and Mining: Proc. Soc Geol Applied to Mineral Deposits (eds William, P. J. et al.), Townsville Australia, 2009, vol. 2, pp. 957–959.
- Pandit, D., Panigrahi, M. K., Moriyama, T. and Ishihara, S., Comparative geochemical, magnetic susceptibility, and fluid inclusion studies on the Paleoproterozoic Malanjkhand and Dongargarh granitoids, Central India and implications to metallogeny. Mineral. Petrol., 2014, 108, 663–680.
- Pandit, D., Panigrahi, M. K. and Moriyama, T., Constrains from magmatic and hydrothermal epidotes on crystallization of granitic magma and sulfide mineralization in Paleoproterozoic Malanjkhand granitoid, Central India. Chem. Erde-Geochem., 2014, 74, 715–733.
- Pandit, D., Geochemistry of feldspar intergrowth microtextures from Paleoproterozoic granitoids in Central India: implications to exsolution processes in granitic system. J. Geol. Soc. India, 2015, 85, 163–182.
- Pandit, D., Thermodynamic model for hydrothermal sulfide deposition in the Paleoproterozoic granite ore system at Malanjkhand, India. Indian J. Geomar. Sci., 2015, 44(11), 1697–1711.
- Pandit, D., Chloritization in Paleoproterozoic granite ore system at Malanjkhand, Central India: mineralogical studies and mineral fluid equilibria modelling. Curr. Sci., 2014, 106, 565–581.
- Pandit, D., A comparative study of the Paleoproterozoic Malanjkhand and Dongargarh granitoids Central India: Implications to crustal evolution and metallogeny, Ph D thesis, Indian Institute of Technology Kharagpur, India, 2008.
- Pandit, D., Lattice preferred orientation analysis of deformed quartz: an advanced application of high resolution X-ray diffractometer. J. Geol. Soc. India, 2012, 79, 169–174.
- Pandit, D. and Panigrahi, M. K., Comparative petrogenesis and tectonics of Paleoproterozoic Malanjkhand and Dongargarh granitoids, Central India. J. Asian Earth Sci., 2012, 50, 14–26.
- Kumar, S. and Rino, V., Mineralogy and geochemistry of microgranular enclaves in Palaeoproterozoic Malanjkhand granitoids, central India: evidence of magma mixing, mingling, and chemical equilibration. Contrib. Mineral. Petrol., 2006, 152, 591–609.
- Narayana, B. L., Mallikharjuna, J., Subba Rao, M. V., Murthy, N. N. and Divakara Rao, V., Geochemistry and origin of Early Proterozoic Dongargarh Rapakavi Granite complex, Central India, an example for magma mixing and differentiation. Gondwana Res., 2000, 3, 507–520.
- Kumar, S., Rino, V. and Pal, A. B., Field evidence of magma mixing from microgranular enclaves hosted in Palaeoproterozoic Malanjkhand granitoids, Central India. Gondwana Res., 2004, 7, 539–548.
- Sarkar, S. C., Kabiraj, S., Bhattacharya, S. and Pal, A. B., Nature, origin and evolution of the granitoid-hosted early Proterozoic copper–molybdenum mineralization at Malanjkhand, central India. Miner. Deposita, 1996, 31, 419–431.
- Pandit, D., Panigrahi, M. K. and Naik, R. K., Fluid characteristics in the leucogranite phase of the Malanjkhand Granitoid Complex: implications to copper–molybdenum mineralization. In Proceedings of Asian Current Research on Fluid Inclusions (ACROFI-2), 2008, pp. 144–146.
- Sensarma, S., A bimodal large igneous province and the plume debate: the Paleoproterozoic. Geol. Soc. Am. Spec. Paper, 2007, 430, 831–839.
- Sensarma, S., Hoernes, S. and Mukhopadhyah, D., Relative contribution of crust and mantle to the origin of the Bijli Rhyolite in a palaeoproterozoic bimodal volcanic sequence (Dongargarh Group), central India. Proc. Indian Acad. Sci. (Earth Planet. Sci.), 2004, 113, 619–648.
- Srivastava, R. K., Global intracratonic boninite–norite magmatism during the Neoarchean–Paleoproterozoic: evidence from the Central Indian Bastar Craton. Int. Geol. Rev., 2008, 50, 61–74.
- Chalapathi Rao, N. V. and Srivastava, R. K., A new find of boninite dyke from the Paleoproterozoic Dongargarh Supergroup: inference for a fossil subduction zone in the Archaean of the Bastar craton, Central India. Neues Jb. Miner. Abh., 2009, 186, 271–282.
- Naganjaneyulu, K. and Santosh, M., The Central Indian Tectonic Zone: a geophysical perspective on continental amalgamation along a Mesoproterozoic suture. Gondwana Res., 2010, 18, 547–564.
- Kumar, S., Rino, V., Hayasaka, Y., Kimura, K., Raju, S., Terada, K. and Pathak, M., Contribution of Columbia and Gondwana Super continent assembly- and growth-related magmatism in the evolution of the Meghalaya Plateau and the Mikir Hills, Northeast India: constraints from U–Pb SHRIMP zircon geochronology and geochemistry. Lithos, 2017, 277, 356–375.
- Gromet, L. P. and Silver, L. T., Rare earth element distribution among minerals in a granodiorite and their petrogenetic implications. Geochim. Cosmochim. Acta, 1983, 47, 925–940.
- McLeod, G. W., Dempster, T. J. and Faithfull, J. W., Deciphering magma-mixing processes using zoned titanite from the Ross of Mull Granite, Scotland. J. Petrol., 2011, 52, 55–82.
- Mitchell, R. S., Pseudomorphs of anatase after sphene from Roanoke County, Virginia. Am. Mineral., 1964, 49, 1136–1139.
- Shore, M. and Fowler, A. D., Oscillatory zoning in minerals: a common phenomenon. Can. Mineral., 1996, 34, 1111–1126.
- Watson, E. B. and Liang, Y., A simple model for sector zoning in slowly grown crystals: implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks. Am. Mineral., 1995, 80, 1179–1187.
- Chakhmouradian, A. R., Reguir, E. P. and Mitchell, R. H., Titanite in carbonatitic rocks: genetic dualism and geochemical significance. Period. Mineral., 2003, 72, 107–113.
- Panigrahi, M. K. and Mookherjee, A., The Malanjkhand copper (+molybdenum) deposit, India: mineralization from a low – temperature ore – fluid of granitoid affiliation. Miner. Deposita, 1997, 32, 133–148.
- Panigrahi, M. K., Pandit, D., Naik, R. K. and Ishihara, S., Reconstruction of physicochemical environment of hydrothermal mineralization at Malanjkhand copper deposit, Central India: constraints from sulfur isotope ratios in pyrite, molybdenite and chalcopyrite. Resour. Geol., 2013, 63, 110–116.
- Buddington, A. F. and Lindsley, D. H., Iron-titanium oxide mineral and synthetic equivalents. J. Petrol., 1964, 5, 310–357.
- Yavuz, F., A revised program for microprobe-derived amphibole analysis using the IMA rules. Comput. Geosci., 1999, 25, 909–927.
- Martin, R. F., Amphiboles in the igneous environment. Rev. Mineral. Geochem., 2007, 67, 323–358.
- Henry, D. J., Guidotti, C. V. and Thomson, J. A., The Tisaturation surface for low-to-medium pressure metapelitic biotites: implications for geothermometry and Ti-substitution mechanisms. Am. Mineral., 2005, 90, 316–328.
- Henry, D. J. and Guidotti, C. V., Ti in biotite from metapelitic rocks: temperature effects, crystallochemical controls and petrol ogic applications. Am. Mineral., 2002, 87, 375–382.
- Tacker, R. C. and Stormer Jr, J. C., A thermodynamic model for apatite solid solution, application to high-temperature geologic problems. Am. Mineral., 1989, 74, 877–888.
- Sallet, R., Fluorine as a tool in the study of quartz bearing magmatic associations: applications of an improved F–OH biotitea patite thermometer grid. Lithos, 2000, 50, 241–253.
- Harrison, T. M. and Watson, E. B., The behavior of apatite during crustal anatexis: equilibrium and kinetic considerations. Geochim. Cosmochim. Acta, 1984, 48, 1467–1477.
- Wass, Y., Hendersoon, P. and Elliott, C. J., Chemical homogeneity and metasomatism in the upper mantle: evidence from rare earth and other elements in apatite-rich xenoliths in basaltic nodules from eastern Australia. Philos. Trans. R. Soc. London, 1980, A297, 333–346.
- Dempster, T. J., Jolivet, M., Tubrett, M. N. and Braithwaite, C. J. R., Magmatic zoning in apatite: a monitor of porosity and permeability change in granites. Contrib. Mineral. Petrol., 2003, 145, 568–577.
- Paterson, B. A., Stephens, W. E. and Herd, D. A., Zoning in granitoid accessory minerals as revealed by backscattered electron imagery. Mineral. Mag., 1989, 53, 55–61.
- Wones, D. R., Significance of the assemblage titanite + magnetite quartz in granitic rocks. Am. Mineral., 1989, 74, 744–749.
- Deer, W. A., Howie, R. A. and Zussman, J., An Introduction of the Rock – Forming Minerals, Longman Group, London, 1979.
- Schmidt, M. W., Amphibole composition in tonalite as a function of pressure: an experimental calibration of the Al-in-hornblende barometer. Contrib. Mineral. Petrol., 1992, 110, 304–310.
- Guidotti, C. V., Teichmann, F. and Henry, D. J., Chlorite-bearing polymetamorphic metapelites in the Rangeley area, Maine: evidence from equilibrium assemblages. Am. Mineral., 1991, 76, 867–879.
- Zhu, C. and Sverjensky, D. A., F–Cl–OH partitioning between biotite and apatite. Geochim. Cosmochim. Acta, 1992, 56, 3435–3467.
- Hoskin, P. W. O., Kinny, P. D., Wyborn, D. and Chappell, B. W., Identifying accessory mineral saturation during differentiation in granitoid magmas: an integrated approach. J. Petrol., 2000, 41, 1365–1396.
- Panigrahi, M. K., Copper–molybdenum mineralization and associated granitoids of Malanjkhand, MP, India, Ph D thesis, Indian Institute of Technology Kharagpur, India, 1992.
- Naik, R. K., The Late Archean/Early Proterozoic granitoid complex and associated Cu–Mo mineralization at Malanjkhand, Central India: towards working model of ore genesis. Ph D thesis, Indian Institute of Technology Kharagpur, India, 2006.
- Watson, E. B. and Harrison, T. M., Zircon saturation revisited: temperature and composition effects in a variety of crustal magma types. Earth Planet. Sci. Lett., 1983, 64, 295–304.
- Pandit, D., Accessory minerals in Paleoproterozoic granites of Bastar Craton. In National Conference and Field Workshop on Precambrians of India, Society of Earth Scientists India, Jhansi, 2016, pp. 32–33.
- Ryerson, F. J. and Watson, E. B., Rutile saturation in magmas: implication for Ti–Nb–Ta depletion in island-arc basalts. Earth Planet. Sci. Lett., 1987, 86, 225–239.
- Hyden, L. A. and Watson, E. B., Rutile saturation in hydrous siliceous melts and its bearing on Ti-thermometry of quartz and zircon. Earth Planet. Sci. Lett., 2007, 258, 561–568.
- Sarkar, S. C. and Gupta, A., Crustal evolution and metallogeny in India, Cambridge University Press, Cambridge, Great Britain, 2012.
- Holland, H. D., Granite, solutions, and base metal deposits. Econ. Geol., 1972, 67, 281–301.
- Candela, P. A. and Holland, H. D., A mass transfer model for copper and molybdenum in magmatic hydrothermal system: the origin of porphyry-type Ore deposits. Econ. Geol., 1986, 81, 1–19.
- William-Jones, A. E. and Heinrich, C. A., Vapor transport of metals and the formation of magmatic-hydrothermal ore deposits. Econ. Geol., 2005, 100, 1287–1312.
- Jain, S. C., Nair, K. K. and Yedekar, D. B., Geology of Son-Narmada–Tapti lineament zone of Central India. Geol. Surv. India Spec. Publ., 1995, 10, 1–154.
- Whitney, D. L. and Evans, B. W., Abbreviations for names of rock-forming minerals. Am. Mineral., 2010, 95, 185–187.
- Lepage, L. D., ILMAT: an Excel worksheet for ilmenite–magnetite geothermometry and geobarometry. Comput. Geosci., 2003, 29, 673–678.
- Yavuz, F., Evaluating micas in petrologic and metallogenic aspect: I-definitions and structure of the computer program MICA+. Comput. Geosci., 2003, 29, 1203–1213.
- Carmichael, I. S. E., The iron-titanium oxides of salic volcanic rocks and their associated ferromagnesian silicates. Contrib. Mineral. Petrol., 1967, 14, 36–64.
- Yavuz, F., BIOPAG-PC: Program for an apatite and biotite geo-thermometer. Comput. Geosci., 1998, 24, 885–891.
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