Open Access Open Access  Restricted Access Subscription Access

Bhagawati Charan Guha and Discovery of the Molecular Magnet


Affiliations
1 Department of Chemistry, The University of Burdwan, Burdwan 713 104, India
 

The discovery of molecular magnet by Bhagawati Charan Guha is not well-discussed in the history of Indian science. On studying a series of inorganic crystals, Guha found some anomalous magnetic behaviour of copper(II) acetate which was not structurally characterized then. After the discovery of the structure, copper(II) acetate appeared as a dimeric dihydrate molecule rather than an inorganic solid. Guha then put a structure-function correlation between the newly discovered structure of copper(II) acetate and its lowtemperature magnetic data. This dimeric copper(II) acetate dihydrate is now regarded as the first reported molecular magnet.
User
Notifications
Font Size

  • Guha, B. C., Proc. R. Soc. London, Ser. A, 1951, 206, 353–373.
  • van Niekerk, J. N. and Schoening, F. R. L., Acta Crystallogr., 1953, 6, 227–232.
  • Bhattacharyya, K., Indian J. Hist. Sci., 2014, 49(4), 374.
  • Wickman, H. H., Trozzolo, A. M., Williams, H. J., Hull, G. W. and Merritt, F. R., Phys. Rev., 1967, 155, 563–566.
  • Bleaney, B. and Bowers, K. D., Proc. R. Soc. London, Ser. A, 1952, 214, 451–465.
  • Guha, B. C., Philos. Mag., 1965, 109, 175– 177.
  • Brown, G. M. and Chindambaram, R., Acta Crystallogr., Sect. B., 1973, 29, 2393– 2403.
  • Kahn, O., Molecular Magnetism, WileyVCH, New York, USA, 1993, p. 106.
  • Ghosh, R., Jnan-O-Bijnan, 2017, 11, 715– 716.

Abstract Views: 378

PDF Views: 129




  • Bhagawati Charan Guha and Discovery of the Molecular Magnet

Abstract Views: 378  |  PDF Views: 129

Authors

Rajarshi Ghosh
Department of Chemistry, The University of Burdwan, Burdwan 713 104, India

Abstract


The discovery of molecular magnet by Bhagawati Charan Guha is not well-discussed in the history of Indian science. On studying a series of inorganic crystals, Guha found some anomalous magnetic behaviour of copper(II) acetate which was not structurally characterized then. After the discovery of the structure, copper(II) acetate appeared as a dimeric dihydrate molecule rather than an inorganic solid. Guha then put a structure-function correlation between the newly discovered structure of copper(II) acetate and its lowtemperature magnetic data. This dimeric copper(II) acetate dihydrate is now regarded as the first reported molecular magnet.

References





DOI: https://doi.org/10.18520/cs%2Fv118%2Fi2%2F312-313