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Development of carbon membrane for CO2/N2 and CO2/CH4 separation


Affiliations
1 Petroleum Research Center, Kuwait Institute for Scientific Research, P.O. Box 24885 Safat, 13109, Kuwait
 

Carbon membranes were prepared using stainless steel supports and evaluated for the separation of two mixtures, i.e. CO2/N2 and CO2/CH4. The effect of seve­ral operating variables, including temperature, pre­ssure and precursor concentration was examined. In this study, carbon membranes were synthesized using a sucrose precursor. Sucrose was subjected to pyrolysis in the temperature range 300–700°C, leading to the complete formation of carbon structure. The gas separation characteristics of the produced membranes were estimated by evaluating CO2, CH2 and N2 permeation. The highest selectivity obtained for CO2/CH4 and CO2/N2 was 1.64 and 1.41 respectively. The emphasis towards CO2/CH4 and CO2/N2 separation is due to their importance and direct relevance to the gas industry processes.

Keywords

Carbon membrane, greenhouse gases, pyrolysis temperature, separation mechanism, sucrose precursor.
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  • Torres, F., Gutierrez, J., Ruiz, L., Bertuzzi, M. and Erdmann, E., Comparative analysis of absorption, membrane, and hybrid technologies for CO2 recovery. J. Nat. Gas Sci. Eng., 2021, 94, 104082.

  • Zeppini, P. and van den Bergh, J., Global competition dynamics of fossil fuels and renewable energy under climate policies and peak oil: a behavioural model. Energy Policy, 2020, 136, 110907.

  • Benhelal, E., Shamsaei, E. and Rashid, M., Challenges against CO2 abatement strategies in cement industry: a review. J. Environ. Sci., 2021, 104, 84–101.

  • Song, C., Liu, Q., Deng, S., Li, H. and Kitamura, Y., Cryogenicbased CO2 capture technologies: state-of-the-art developments and current challenges. Renew. Sustain. Energy Rev., 2019, 101, 265– 278.

  • Borgohain, R., Pattnaik, U., Prasad, B. and Mandal, B., A review on chitosan-based membranes for sustainable CO2 separation applications: mechanism, issues, and the way forward. Carbohydr. Polym., 2021, 267, 118178.

  • Solangi, N., Anjum, A., Tanjung, F., Mazari, S. and Mubarak, N., A review of recent trends and emerging perspectives of ionic liquid membranes for CO2 separation. J. Environ. Chem. Eng., 2021, 9(5), 105860.

  • Godin, J., Liu, W., Ren, S. and Xu, C., Advances in recovery and utilization of carbon dioxide: a brief review. J. Environ. Chem. Eng., 2021, 9(4), 105644.

  • Tomić, L., Danilović, D., Karović-Maričić, V., Leković, B. and Crnogorac, M., Application of membrane technology for separation of CO2 from natural gas. Podzemni Radovi, 2020, 36, 61–68.

  • Kiani, A., Jiang, K. and Feron, P., Techno-economic assessment for CO2 capture from air using a conventional liquid-based absorption process. Front. Energy Res., 2020, 8, 8–18.

  • Ooi, Z., Tan, P., Tan, L. and Yeap, S., Amine-based solvent for CO2 absorption and its impact on carbon steel corrosion: a perspective review. Chin. J. Chem. Eng., 2020, 28(5), 1357–1367.

  • Chakravartula Srivatsa, S. and Bhattacharya, S., Amine-based CO2 capture sorbents: a potential CO2 hydrogenation catalyst. J. CO2 Util., 2018, 26, 397–407.

  • Baker, R., Membrane Technology and Applications, Wiley, Hoboken, NJ, USA, 2013.

  • Strathmann, H., Giorno, L. and Drioli, E., Introduction to Membrane Science and Technology, Wiley-VCH Verlag and Company, Germany, 2011.

  • Iulianelli, A. and Drioli, E., Membrane engineering: latest advancements in gas separation and pre-treatment processes, petrochemical industry and refinery, and future perspectives in emerging applications. Fuel Proc. Technol., 2020, 206, 106464.

  • Ramírez-Santos, Á., Bozorg, M., Addis, B., Piccialli, V., Castel, C. and Favre, E., Optimization of multistage membrane gas separation processes. Example of application to CO2 capture from blast furnace gas. J. Membr. Sci., 2018, 566, 346–366.

  • Kamble, A., Patel, C. and Murthy, Z., A review on the recent advances in mixed matrix membranes for gas separation processes. Renew. Sustain. Energy Rev., 2021, 145, 111062.

  • Brunetti, A., Scura, F., Barbieri, G. and Drioli, E., Membrane technologies for CO2 separation. J. Membr. Sci., 2010, 359(1–2), 115–125.

  • Scofield, J., Gurr, P., Kim, J., Fu, Q., Kentish, S. and Qiao, G., Development of novel fluorinated additives for high performance CO2 separation thin-film composite membranes. J. Membr. Sci., 2016, 499, 191–200.

  • Singh, S., Varghese, A. and Karanikolos, G., Mixed matrix CO2 separation membranes based on polysulfone with Cu-BTC metal– organic framework and poly(ethylene glycol)-grafted carbon nanotubes. SSRN Electron. J., 2021, 2, 193–206.

  • Han, Y. and Ho, W., Polymeric membranes for CO2 separation and capture. J. Membr. Sci., 2021, 628, 119244.

  • Yang, Z. et al., A critical review on thin-film nanocomposite membranes with interlayered structure: mechanisms, recent developments, and environmental applications. Environ. Sci. Technol., 2020, 54(24), 15563–15583.

  • Alomair, A., Al-Jubouri, S. and Holmes, S., A novel approach to fabricate zeolite membranes for pervaporation processes. J. Mater. Chem. A, 2015, 3(18), 9799–9806.

  • Chen, X., Kaliaguine, S. and Rodrigue, D., Correlation between performances of hollow fibers and flat membranes for gas separation. Separ. Purif. Rev., 2017, 47(1), 66–87.

  • Jones, C. and Koros, W., Carbon molecular sieve gas separation membranes-I. Preparation and characterization based on polyimide precursors. Carbon, 1994, 32(8), 1419–1425.

  • Ning, X. and Koros, W., Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation. Carbon, 2014, 66, 511–522.

  • Wei, W., Qin, G., Hu, H., You, L. and Chen, G., Preparation of supported carbon molecular sieve membrane from novolac phenol–formaldehyde resin. J. Membr. Sci., 2007, 303(1–2), 80–85.

  • Ismail, A. and David, L., A review on the latest development of carbon membranes for gas separation. J. Membr. Sci., 2001, 193(1), 1–18.

  • Sazali, N., Salleh, W., Nur Izwanne, M., Harun, Z. and Kadirgama, K., Precursor selection for carbon membrane fabrication: a review. J. Appl. Membr. Sci. Technol., 2018, 22(2).

  • Alomair, A., Alqaheem, Y. and Holmes, S., The use of a sucrose precursor to prepare a carbon membrane for the separation of hydrogen from methane. RSC Adv., 2019, 9(19), 10437–10444.

  • Lei, L., Bai, L., Lindbråthen, A., Pan, F., Zhang, X. and He, X., Carbon membranes for CO2 removal: status and perspectives from materials to processes. Chem. Eng. J., 2020, 401, 126084.

  • Zulhairun, A., Fachrurrazi, Z., Nur Izwanne, M. and Ismail, A., Asymmetric hollow fiber membrane coated with polydimethylsiloxane–metal organic framework hybrid layer for gas separation. Separ. Purif. Technol., 2015, 146, 85–93.

  • Esposito, E. et al., Pebax®/PAN hollow fiber membranes for CO2/CH4 separation. Chem. Eng. Process., 2015, 94, 53–61.

  • He, X., Kim, T. and Hägg, M., Hybrid fixed-site-carrier membranes for CO2 removal from high pressure natural gas: membrane optimization and process condition investigation. J. Membr. Sci., 2014, 470, 266–274.

  • Qin, J. and Chung, T., Development of high-performance polysulfone/poly(4-vinylpyridine) composite hollow fibers for CO2/CH4 separation. Desalination, 2006, 192(1–3), 112–116.

  • Cai, Y., Wang, Z., Yi, C., Bai, Y., Wang, J. and Wang, S., Gas transport property of polyallylamine–poly(vinyl alcohol)/polysulfone composite membranes. J. Membr. Sci., 2008, 310(1–2), 184–196.

  • Chuah, C., Lee, J., Song, J. and Bae, T., CO2/N2 separation properties of polyimide-based mixed-matrix membranes comprising UiO-66 with various functionalities. Membranes, 2020, 10(7),154.

  • Oh, J., Kang, Y. and Kang, S., Poly(vinylpyrrolidone)/KF electrolyte membranes for facilitated CO2 transport. Chem. Commun., 2013, 49(86), 10181.

  • Park, C., Lee, J., Jung, J., Jung, B. and Kim, J., A highly selective PEGBEM-g-POEM comb copolymer membrane for CO2/N2 separation. J. Membr. Sci., 2015, 492, 452–460.

  • Mondal, A. and Mandal, B., CO2 separation using thermally stable

  • crosslinked poly(vinyl alcohol) membrane blended with polyvinylpyrrolidone/polyethyleneimine/tetraethylenepentamine. J. Membr. Sci., 2014, 460, 126–138.


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  • Development of carbon membrane for CO2/N2 and CO2/CH4 separation

Abstract Views: 254  |  PDF Views: 93

Authors

Abdulaziz A. Alomair
Petroleum Research Center, Kuwait Institute for Scientific Research, P.O. Box 24885 Safat, 13109, Kuwait

Abstract


Carbon membranes were prepared using stainless steel supports and evaluated for the separation of two mixtures, i.e. CO2/N2 and CO2/CH4. The effect of seve­ral operating variables, including temperature, pre­ssure and precursor concentration was examined. In this study, carbon membranes were synthesized using a sucrose precursor. Sucrose was subjected to pyrolysis in the temperature range 300–700°C, leading to the complete formation of carbon structure. The gas separation characteristics of the produced membranes were estimated by evaluating CO2, CH2 and N2 permeation. The highest selectivity obtained for CO2/CH4 and CO2/N2 was 1.64 and 1.41 respectively. The emphasis towards CO2/CH4 and CO2/N2 separation is due to their importance and direct relevance to the gas industry processes.

Keywords


Carbon membrane, greenhouse gases, pyrolysis temperature, separation mechanism, sucrose precursor.

References





DOI: https://doi.org/10.18520/cs%2Fv122%2Fi4%2F405-409