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Composite Materials for Supercapacitor Electrodes Utilizing Polypyrrole Nanotubes, Reduced Graphene Oxides and Metal–Organic Framework


Affiliations
1 Conducting Polymers in Composites and Applications Research Group, Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Viet Nam
2 University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
3 Polymer Institute, Slovak Academy of Science, Dubravska Cesta, 9, 845 41 Bratislava, Slovakia

Polypyrrole (PPy) is favoured in energy storage for its high pseudo-capacitive performance, notably as poly­pyrrole nanotubes (PPyNTs) due to their easy synthesis, cost-effectiveness and electrochemical solid properties. Metal–organic frameworks (MOFs) have also gained attention for enhancing supercapacitors (SCs). In this study, we fabricated aerogel composites with PPyNTs, MOFs and reduced graphene oxide (rGO) as SC electrode materials. Varying concentrations of PPyNTs and rGO were explored, with MOFs added to assess their impact. Electrochemical tests revealed that the composite with PPyNTs and Zn-MOF achieved the highest specific capa­citance of approximately 270 F/g at 0.5 A/g.

Keywords

Electrochemical devices, metal–organic framework, polypyrrole nanotubes, reduced graphene oxide, supercapacitor electrodes.
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  • Composite Materials for Supercapacitor Electrodes Utilizing Polypyrrole Nanotubes, Reduced Graphene Oxides and Metal–Organic Framework

Abstract Views: 106  | 

Authors

Rudolf Kiefer
Conducting Polymers in Composites and Applications Research Group, Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Viet Nam
Irina Sapurina
University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
Constantin Bubulinca
University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
Lukas Munster
University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
Ahmad Reshad Delawary
University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
Nikola Bugarova
Polymer Institute, Slovak Academy of Science, Dubravska Cesta, 9, 845 41 Bratislava, Slovakia
Matej Mičušík
Polymer Institute, Slovak Academy of Science, Dubravska Cesta, 9, 845 41 Bratislava, Slovakia
Maria Omastova
Polymer Institute, Slovak Academy of Science, Dubravska Cesta, 9, 845 41 Bratislava, Slovakia
Natalia E. Kazantseva
University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
Petr Saha
University Institute, Tomas Bata University in Zlin, Nad Ovčírnou 3685, 760 01, Zlin, Czech Republic
Quoc Bao Le
Conducting Polymers in Composites and Applications Research Group, Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Viet Nam

Abstract


Polypyrrole (PPy) is favoured in energy storage for its high pseudo-capacitive performance, notably as poly­pyrrole nanotubes (PPyNTs) due to their easy synthesis, cost-effectiveness and electrochemical solid properties. Metal–organic frameworks (MOFs) have also gained attention for enhancing supercapacitors (SCs). In this study, we fabricated aerogel composites with PPyNTs, MOFs and reduced graphene oxide (rGO) as SC electrode materials. Varying concentrations of PPyNTs and rGO were explored, with MOFs added to assess their impact. Electrochemical tests revealed that the composite with PPyNTs and Zn-MOF achieved the highest specific capa­citance of approximately 270 F/g at 0.5 A/g.

Keywords


Electrochemical devices, metal–organic framework, polypyrrole nanotubes, reduced graphene oxide, supercapacitor electrodes.



DOI: https://doi.org/10.18520/cs%2Fv127%2Fi5%2F537-543