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Development of Hydrophobic Platinum-Doped Carbon Aerogel Catalyst for Hydrogen-Deuterium Exchange Process at High Pressure


Affiliations
1 Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, India
2 Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, Iceland
3 Heavy Water Board, Vikram Bhawan, Anushakti Nagar, Mumbai 400 094, India
 

The use of catalysed exchange of deuterium (D) between hydrogen (H) gas and liquid water using the bithermal hydrogen water (BHW) process is a promising and environment-friendly approach for the production of heavy water. However, the use of this approach is limited by the lack of a suitable catalyst that has good activity at high operating pressures required for practical applications. We report the development of hydrophobic platinum-doped carbon aerogel (PtCA) catalyst which shows good catalytic activity for H/D isotope exchange reactions at operating pressures up to 20 bar.

Keywords

Carbon Dioxide Activation, Hydrogen Isotope Separation, Hydrophobic Catalyst, Platinum-Doped Carbon Aerogel.
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  • Development of Hydrophobic Platinum-Doped Carbon Aerogel Catalyst for Hydrogen-Deuterium Exchange Process at High Pressure

Abstract Views: 205  |  PDF Views: 89

Authors

Rashmi Singh
Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, India
M. K. Singh
Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, India
D. K. Kohli
Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, India
Ashish Singh
Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, India
Sushmita Bhartiya
Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, Iceland
A. K. Agarwal
Heavy Water Board, Vikram Bhawan, Anushakti Nagar, Mumbai 400 094, India
P. K. Gupta
Nano Functional Materials Laboratory, Laser Materials Development and Devices Division, Raja Ramanna Centre for Advanced Technology, Indore 452 013, India

Abstract


The use of catalysed exchange of deuterium (D) between hydrogen (H) gas and liquid water using the bithermal hydrogen water (BHW) process is a promising and environment-friendly approach for the production of heavy water. However, the use of this approach is limited by the lack of a suitable catalyst that has good activity at high operating pressures required for practical applications. We report the development of hydrophobic platinum-doped carbon aerogel (PtCA) catalyst which shows good catalytic activity for H/D isotope exchange reactions at operating pressures up to 20 bar.

Keywords


Carbon Dioxide Activation, Hydrogen Isotope Separation, Hydrophobic Catalyst, Platinum-Doped Carbon Aerogel.



DOI: https://doi.org/10.18520/cs%2Fv109%2Fi10%2F1860-1864