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X-ray Diffraction, Infrared and Isotope Study of the Lakadong Limestone, Meghalaya


Affiliations
1 Regional Research Laboratory, Jorhat-785 006, Assam, India
2 Department of Applied Geology, Dibrugarh University, Dibrugarh-786 004, Assam, India
     

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X-ray diffraction (XRD) and infrared (IR) spectral analyses of the Lakadong Limestone, Meghalaya indicate calcite as its dominant mineral phase. Association of dolomite at the base and presence of silica at the top of the sequence is evidenced from the spectra. A significant relationship between CaO content and the peak intensity of IR-spectra is found and needs standardisation before it can be utilised for rapid estimation of quality of limestone and can be an alternative for different time consuming analytical procedures. Stable isotope of δ13C {0.63 to 1.12‰( av.0.87±0.01‰)} points to enrichment of heavier C isotope and δ18O values {-7.34 to-10.55‰ (av.-9.06±0.01‰) ) to lighter O isotope enrichment. Isotopic grid analysis confirms the marine origin for the limestone. Biochemical fractionation along with diagenetic reorganisation might have played critical roles in controlling the isotopic ratios of this limestone.

Keywords

Geochemistry, Palaeocene, Limestone, Stable Isotope, Lakadong, Meghalaya.
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  • X-ray Diffraction, Infrared and Isotope Study of the Lakadong Limestone, Meghalaya

Abstract Views: 207  |  PDF Views: 2

Authors

P. Kotoky
Regional Research Laboratory, Jorhat-785 006, Assam, India
Baby Baruah
Regional Research Laboratory, Jorhat-785 006, Assam, India
R. Borgohain
Department of Applied Geology, Dibrugarh University, Dibrugarh-786 004, Assam, India

Abstract


X-ray diffraction (XRD) and infrared (IR) spectral analyses of the Lakadong Limestone, Meghalaya indicate calcite as its dominant mineral phase. Association of dolomite at the base and presence of silica at the top of the sequence is evidenced from the spectra. A significant relationship between CaO content and the peak intensity of IR-spectra is found and needs standardisation before it can be utilised for rapid estimation of quality of limestone and can be an alternative for different time consuming analytical procedures. Stable isotope of δ13C {0.63 to 1.12‰( av.0.87±0.01‰)} points to enrichment of heavier C isotope and δ18O values {-7.34 to-10.55‰ (av.-9.06±0.01‰) ) to lighter O isotope enrichment. Isotopic grid analysis confirms the marine origin for the limestone. Biochemical fractionation along with diagenetic reorganisation might have played critical roles in controlling the isotopic ratios of this limestone.

Keywords


Geochemistry, Palaeocene, Limestone, Stable Isotope, Lakadong, Meghalaya.