Journal of Surface Science and Technology

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Mixed Micelle Properties of Anionic Dimeric Surfactants with Anionic, Cationic, and Nonionic Surfactants


Affiliations
1 Department of Chemistry, Shobhit University, Gangoh, Saharanpur - 247341, Uttar Pradesh, India
2 Department of Chemistry, Jaypee University of Engineering & Technology, Guna - 473226, Madhya Pradesh, India
     

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Herein, we have investigated the mixed micellar behavior of carboxylate anionic dimeric surfactants (CAD12 and CAD16) with commercial surfactants; anionic type i.e., sodium dodecyl sulfate, cationic i.e., cetyltrimethylammonium bromide and nonionic i.e., polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether. The CMC values of mixed surfactants obtained from conductivity data decrease with a mole fraction of dimeric surfactants. The micellar characteristics (ideal CMC) and mutual interaction parameters (β) have been computed with the aid of theoretical models proposed by Clint, and Rubingh. In addition to this, thermodynamic parameters of micellization like ∆Gmic0, ∆Hmic0 , and ∆Smic0 were evaluated and discussed.

Keywords

Conventional Surfactants, Critical Micelle Concentration, Dimeric Surfactants, Interaction Parameter, Mixed Micellization.
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  • Mixed Micelle Properties of Anionic Dimeric Surfactants with Anionic, Cationic, and Nonionic Surfactants

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Authors

Naveen Kumar
Department of Chemistry, Shobhit University, Gangoh, Saharanpur - 247341, Uttar Pradesh, India
Rashmi Tyagi
Department of Chemistry, Jaypee University of Engineering & Technology, Guna - 473226, Madhya Pradesh, India

Abstract


Herein, we have investigated the mixed micellar behavior of carboxylate anionic dimeric surfactants (CAD12 and CAD16) with commercial surfactants; anionic type i.e., sodium dodecyl sulfate, cationic i.e., cetyltrimethylammonium bromide and nonionic i.e., polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether. The CMC values of mixed surfactants obtained from conductivity data decrease with a mole fraction of dimeric surfactants. The micellar characteristics (ideal CMC) and mutual interaction parameters (β) have been computed with the aid of theoretical models proposed by Clint, and Rubingh. In addition to this, thermodynamic parameters of micellization like ∆Gmic0, ∆Hmic0 , and ∆Smic0 were evaluated and discussed.

Keywords


Conventional Surfactants, Critical Micelle Concentration, Dimeric Surfactants, Interaction Parameter, Mixed Micellization.

References