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Aher, Kumudini
- Solvent Free Synthesis, Characterization and Evaluation of Dimethylaminopropylamine based Double Tailed Amidoamine Cationic Surfactant
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PDF Views:11
Authors
Affiliations
1 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, IN
2 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, Maharashtra, IN
1 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, IN
2 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai - 400019, Maharashtra, IN
Source
Journal of Surface Science and Technology, Vol 34, No 1-2 (2018), Pagination: 7-18Abstract
Lauramidopropyl dimethylamine was quaternised using Lauryl Bromide to synthesize a double chain cationic surfactant. The surfactant was obtained in good yield without the use of any solvent. Amidoamine cationic surfactant chemical structure was analyzed using mass spectroscopic technique. The physicochemical properties of the amidoamine surfactant were calculated from surface tension and conductance measurements giving a critical micelle concentration of 8.04 × 10-3 mM which is quite lower than conventional surfactants. The amidoamine also exhibits a good foaming ability and wettability. The amidoamine cationic surfactant was evaluated for efficacy against different microorganisms and the results show that it has good antimicrobial activity against both Gram positive and Gram negative bacteria.Keywords
Amidoamine, Critical Micelle Concentration, Quaternization, Surfactant, Synthesis.
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- Synthesis, Surface Active Properties and Antimicrobial Activity of Novel Ester – Amidoamine Linked Double Tailed Cationic Surfactants
Abstract Views :145 |
PDF Views:2
Authors
Affiliations
1 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai – 400019, Maharashtra, IN
1 Department of Chemical Engineering, Institute of Chemical Technology, Mumbai – 400019, Maharashtra, IN
Source
Journal of Surface Science and Technology, Vol 37, No 3-4 (2021), Pagination: 141-157Abstract
Three novel ester-amidoamine linked cationic surfactants bearing a double tail were synthesized. Their chemical structures were interpreted with FTIR, 1H and 13C NMR spectroscopy. These surfactants consist of hydrophobes that may be obtained from sustainable resources. The objective was to synthesize a double tailed amidoamine having two functional groups in the structure and to investigate the effect of these groups on the interfacial as well as physical properties of the surfactants. The interfacial properties of the surfactants were determined using tensiometry, conductometry measurements and dye solubilization techniques. The synthesized surfactants have been found to exhibit quite low CMC in comparison with conventional surfactants of similar structure. The effect of sodium chloride on their surface properties was also studied. They were found to possess good and stable foaming ability and wettability. All the synthesized surfactants delivered appreciable antimicrobial activity against three tested microorganisms, Staphylococcus aureus and Escherichia coli.Keywords
Double Tailed Ester-Amidoamine, Critical Micelle Concentration, Quaternization, Surfactant, Synthesis.References
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