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Enhance the Photocurrent of Cu/n-Cu2O Solid State Solar Cell Using Coconut Shell Activated Carbon (CAC) as Upper - Electrode
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Coconut shells are used for production of activated carbon. In this research, alkaline-bio scoured coconut shell powder was subjected to one step pyrolysis activation by using Phosphoric acid. The acid treated coconut shell particles were fed into a tube furnace with a heating rate of 10 °C min-1 until the temperature reached at 360 °C and dwell time 15 min in N2 atmosphere. Next, they were cooled into room temperature. A thin film of n-Cu2O was fabricated by immersing a well cleaned copper sheet in a 10-3 M HCl solution for 60 h. CAC was placed on Cu/n-Cu2O substrate and ITO conductive glass plate was placed to fabricate Cu/n-Cu2O/CAC/ITO solid state photovoltaic cell. Here, CAC acts as an upper electrode, separate photo-generated charge carriers and enhance photocurrent. BET surface area analysis, diffuse reflectance spectra, photocurrent action spectra, time development of photocurrent and SEM morphology were used to analyse the prepared samples.
Keywords
Activated Carbon, BET, Coconut Shell, n-Cu2O.
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- J. N. Nian, C. C. Hu, and H. Teng, “Electrodeposited p-type Cu2O for H2 evolution from photoelectrolysis of water under visible light illumination,” International Journal of Hydrogen Energy, vol. 33, no. 12, pp. 28972903, 2008.
- T. Mahalingam, J. S. P. Chitra, J. P. Chu, S. Velumani, and P. J. Sebastian, “Structural and annealing studies of potentiostatically deposited Cu2O thin films,” Solar Energy Materials and Solar Cells, vol. 88, no. 2, pp.209-216, 2005.
- B. P. Rai, “Cu2O Solar Cells: A Review,” Solar Cells, vol. 25, pp. 265-272, 1988.
- R. S. Toth, R. Kilkson, and D. Trivich, “Preparation of large area single-crystal cuprous oxide,” Journal of Applied Physics, vol. 31, no. 6, pp. 1117-1121, 1960.
- M. O’Keeffe, and W. J. Moore, “Electrical conductivity of monocrystalline cuprous oxide,” The Journal of Chemical Physics, vol. 35, no. 4, pp. 1324-1328, 1961.
- A. P. Young, and C. M. Schwartz, “Electrical conductivity and thermoelectric power of Cu2O,” Journal of Physics and Chemistry of Solids, vol. 30, no. 2, pp. 249252, 1969.
- H. L. McKinzie, and M. O’Keeffe, “High temperature hall effect in cuprous oxide,” Physics Letters A, vol. 24, no. 3, pp. 137-139, 1967.
- L. Wang, and M. Tao, “Fabrication and characterization of p-n homojunctions in cuprous oxide by electrochemical deposition,” Electrochemical and Solid-State Letters, vol. 10, no. 9, pp. H248-H250, 2007.
- C. A. N. Fernando, T. M. W. J. Bandara, and S. K.Wethasingha, “H2 evolution from a photoelectrochemical cell with n-Cu2O photoelectrode under visible light irradiation,” Solar Energy Materials and Solar Cells, vol. 70, no. 2, pp. 121-129, 2001.
- G.-W. Sun, C. Wang, L. Zhan, W.-M. Qiao, X.-Y. Liang, and L.-C. Ling, “Influence of high temperature treatment of activated carbon on performance of supercapacitors,” Journal of Materials Science and Engineering, vol. 2,no. 12, pp. 41-48, 2008.
- A. Kay, and M. Gratzel, “Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder,” Solar Energy Materials and Solar Cells, vol. 44, no. 1, pp. 99-117, 1996.
- D. H. Jurcakova, M. Seredych, G. Q. Lu, and T. J. Bandosz, “Combined effect of nitrogen-and oxygencontaining functional groups of microporous activated carbon on its electrochemical performance in supercapacitors,” Advanced Functional Materials, vol. 19, no.3, pp. 438-447, 2009.
- A. Aygün, S. Y. Karakaş, and I. Duman, “Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties,” Microporous and Mesoporous Materials, vol. 66, no. 2, pp. 189-195, 2003.
- K. Imoto, K. Takahashi, T. Yamaguchi, T. Komura, J. I.Nakamura, and K. Murata, “High-performance carbon counter electrode for dye-sensitized solar cells,” Solar Energy Materials and Solar Cells, vol. 79, no. 4, pp. 459-469, 2003.
- Z. Huang, X. Liu, K. Li, D. Li, Y. Luo, H. Li, W. Song, L. Chen, and Q. Meng, “Application of carbon materials as counter electrodes of dye-sensitized solar cells,” Electrochemistry Communications, vol. 9, no. 4, pp.596-598, 2007.
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