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A Spectroscopic Ferrozine-Based Assay for the Calculation of Corrosion Rate and Inhibition Efficiency by Schleichera oleosa Leaf and Bark as an Inhibitor


Affiliations
1 Department of Chemistry, Avinashilingam Institute for Home Science and Higher Education for Women, Coimbatore‐641043, Tamilnadu, India
 

In the present investigation, corrosion inhibition of mild steel in acidic solutions has been tested primarily via weight loss tests. Further the test solutions were tested by spectroscopic method as ferrozine as a reagent. By using this method, the corrosion rate of mild steel in various time interval and inhibition efficiencies of leaf and bark extracts of Schleichra oleosa were calculated. Ferrous ion chelating ability of extracts and total phenol content in extracts were calculated using the reagents such as ferric chloride and foloin-ciocalteau reagents respectively. The results of both weight loss as well as spectroscopic methods were found to comparable. The result of the present study has a promising effect in both industrial and day to day livings.

Keywords

Corrosion, Schleichra oleosa, Mild Steel, Corrosion Rate, Inhibition Efficiency, Spectroscopic Method.
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  • Acker VS, van Den Berg DJ, Tromp JL, Griffioen DH, van Bennekom W P, van Der Vijgh WJ Bast A. (1996). Structural aspects of antioxidant activity of flavonoids. Free Radical Biology and Medicine, 20, 331–342.
  • Ajmal M, Jamal D, Quraishi MA. (2000). Fatty acid oxadiazoles as acid corrosion inhibitors for mild steel. Anti-Corrosion Methods and Materials, 47(2), 77-88.
  • Andjelkovic M, Camp JV, Meulenaer BD, Depaemelaere G, Socaciu C, Verloo M, Verhe V.(2006). Iron-chelation properties of phenolic acids bearing catechol and galloyl groups. Food Chemistry, 98, 23–31.
  • Brittenham GM. Iron chelators and iron toxicity. (2003). Iron chelators and iron toxicity. Alcohol, 30(2), 151–158.
  • Chen YK, Li X S, Yang GY, Chen ZY, Hu QF, Miao MM.(2012). Phenolic compounds from Nicotiana tabacum and their biological activities. Journal of Asian Natural Products Research, 14, 450-456.
  • Dan S, Dan SS. (1986). Phytochemical study of Adnsonia digitata,Coccoloba excoriate, Psychotria adenophylla, and Schleichera oleosa. Fitoterapia. 57, 445-446.
  • Dinis TCP, Madeira VMC, Almeida LM.(1994). Action of phenolic derivatives (acetaminophen, salicylate, and 5-aminosalicylate) as inhibitors of membrane lipid peroxidation and as peroxyl radical scavengers. Journal of Archives of Biochemistry and Biophysics, 315, 161–169.
  • Fish WW. (1988). Rapid colorimetric micro method for the quantitation of complexed iron in biological samples, Methods Enzymology, 158, 357-364.
  • Folin O, Ciocalteu V. (1927).On tyrosine and tryptophane determination in proteins. Journal of Biological Chemistry, 27, 627-650.
  • George S, Brat P, Alter P, Amiot MJ. (2005). Rapid determination of polyphenols and vitamin C in plant-derived products. Journal of Agricultural and Food Chemistry, 53, 1370–1373.
  • Ghosh P, Chakraborty P, Mandal A, Rasul MG, Chakraborty Madhumita, Saha A. (2011).Triterpenoids from Schleichera oleosa of Darjeeling foothills and their antimicrobial activity. Indian Journal of Pharmaceutical Sciences, 73,231-233.
  • Mu GN, Zhao TP, Liu M, Gu T. (1996). Effect of metallic cations on corrosion inhibition of an anionic surfactant for mild steel. Corrosion, 52, 853.
  • Rekha C, Poornima G, Manasa M, Abhipsa V, Devi J P, Kumar HTV, Kekuda TR P.(2012). Ascorbic acid, total phenol content and antioxidant activity of fresh juices of four ripe and unripe Citrus fruits. Chemical Science Transactions, 1(2), 303-310.
  • Tan KW, Kassim MJ.(2011). A correlation study on the phenolic profiles and corrosion inhibition properties of mangrove tannins (Rhizophora apiculata) as affected by extraction solvents. Corrosion Science, 53, 569–574.

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  • A Spectroscopic Ferrozine-Based Assay for the Calculation of Corrosion Rate and Inhibition Efficiency by Schleichera oleosa Leaf and Bark as an Inhibitor

Abstract Views: 243  |  PDF Views: 8

Authors

V. N. Sheeja
Department of Chemistry, Avinashilingam Institute for Home Science and Higher Education for Women, Coimbatore‐641043, Tamilnadu, India
S. Subhashini
Department of Chemistry, Avinashilingam Institute for Home Science and Higher Education for Women, Coimbatore‐641043, Tamilnadu, India

Abstract


In the present investigation, corrosion inhibition of mild steel in acidic solutions has been tested primarily via weight loss tests. Further the test solutions were tested by spectroscopic method as ferrozine as a reagent. By using this method, the corrosion rate of mild steel in various time interval and inhibition efficiencies of leaf and bark extracts of Schleichra oleosa were calculated. Ferrous ion chelating ability of extracts and total phenol content in extracts were calculated using the reagents such as ferric chloride and foloin-ciocalteau reagents respectively. The results of both weight loss as well as spectroscopic methods were found to comparable. The result of the present study has a promising effect in both industrial and day to day livings.

Keywords


Corrosion, Schleichra oleosa, Mild Steel, Corrosion Rate, Inhibition Efficiency, Spectroscopic Method.

References