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Ultrasonic Speed Measurements in Binary Mixtures Containing Esters at Temperatures from 303.15 to 318.15 K


Affiliations
1 Department of Chemistry, V.R. Siddhartha Engineering College, Vijayawada - 520007, India
2 Department of Physics, V.R. Siddhartha Engineering College, Vijayawada - 520007, India
 

Density and ultrasonic speed have been measured in pure and binary mixtures containing o-anisidine and butyl acetate or propyl acetate over the whole composition range at 303.15, 308.15, 313.15 and 318.15 K. From these values, isentropic compressibility and intermolecular free lengths as well as excess quantities for sound speed, isentropic compressibility and intermolecular free length have been calculated. The results have been fitted to Redlich-Kister polynomial equation. The results have been explained on the basis of intermolecular interactions.

Keywords

O-Anisidine, Butyl Acetate, Propyl Acetate, Ultrasonic Speed, Thermodynamic Parameter.
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  • Ultrasonic Speed Measurements in Binary Mixtures Containing Esters at Temperatures from 303.15 to 318.15 K

Abstract Views: 247  |  PDF Views: 2

Authors

M. Srilakshmi
Department of Chemistry, V.R. Siddhartha Engineering College, Vijayawada - 520007, India
K. Narendra
Department of Physics, V.R. Siddhartha Engineering College, Vijayawada - 520007, India
Ch. Kavitha
Department of Chemistry, V.R. Siddhartha Engineering College, Vijayawada - 520007, India
M. Durga Bhavani
Department of Chemistry, V.R. Siddhartha Engineering College, Vijayawada - 520007, India

Abstract


Density and ultrasonic speed have been measured in pure and binary mixtures containing o-anisidine and butyl acetate or propyl acetate over the whole composition range at 303.15, 308.15, 313.15 and 318.15 K. From these values, isentropic compressibility and intermolecular free lengths as well as excess quantities for sound speed, isentropic compressibility and intermolecular free length have been calculated. The results have been fitted to Redlich-Kister polynomial equation. The results have been explained on the basis of intermolecular interactions.

Keywords


O-Anisidine, Butyl Acetate, Propyl Acetate, Ultrasonic Speed, Thermodynamic Parameter.