Journal of Pure and Applied Ultrasonics

Open Access Open Access  Restricted Access Subscription Access

Acoustical and Excess Parameters in Binary Liquid Mixture at Temperature 303.15 K


Affiliations
1 Department of Physics, Shivchhatrapati College, Aurangabad-431003, India
2 Department of Physics, Sanjivani Rural Educational Society, College of Engineering, Kopargaon-423603,, India
3 Department of Physics, Pratishthan Mahavidyalaya, Paithan, Aurangabad-431107, India
4 Department of Physics, Vivekananda College, Aurangabad-431001, India
5 Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004, India
 

Acoustical and excess parameters have been calculated from the experimentally measured data of ultrasonic velocity, density and viscosity in binary liquid mixtures containing herbal extract of drug Piper Nigrum with ZnCl2 over the composition range (number of moles (n) of drug = 0.7009, 1.4018, 2.1027, 2.8036 and 3.5045) at 303.15 K temperature. Obtained results are fitted to the Redlich - Kister polynomial equation. These results have been explained on the basis of the intermolecular interactions present in the liquid mixtures. Present investigation provides important information about the physiological system and used to understand the mechanism of their metabolism in the living system.

Keywords

Ultrasonic Velocity, Density, Adiabatic Compressibility, Excess Intermolecular Free Length, Molecular Interaction.
User
Notifications
Font Size

  • Chiappe C. and Rajamani S., Structural effects on the physico chemical and catalytic properties of acidic ionic liquids: An Overview, Eur. J. Org. Chem. 2011 (2011) 5517-5539.

  • Hawrylak B., Gracie K. and Palepu R., Ultrasonic velocity and volumetric properties of isomeric butanediols plus water systems, Can. J. Chem. 76 (1998) 464-468.

  • Mehra R. and Sajnani H., Acoustical parameters of CuClKCl system in acetonitrile-water solvent mixture, Phys. Chem. Liq. 39 (2001) 581-588.

  • Panda S. and Kar A., Water and ethanol extracts of Piper nigrum in regulating thyroid function and lipid peroxidation in mice, Pharma. Bio. 41 (2003) 479-482.

  • Al-Moflehi A., Alhaider A. and Mossa J., Al-Sohaibani M., Rafatullah S. and Qureshi S., Inhibition of gastric mucosal damage by Piper nigrum (Black pepper) pretreatment in Wistar albino rats, Pharma. Mag. 1 (2005) 64.

  • Yang J.-z., Chang X.-h. and Lu X.-m., Thermodynamics of ion pair of magnesium sulfate in mixed solvent, Chem. Res. in Chinese Univers. 22 (2006) 403-405.

  • Ong E.S., Extraction methods and chemical standardization of botanicals and herbal preparations, J.

  • Chrom. B 812 (2004) 23-33.

  • Aswale S., Aswale S.S., Gowardipe V. and Yavatmal W.D., Variation of acoustical parameters of herbal extract pomegranate solutions at frequency 4 MHz, Int. J. Chem. Physic. Sci. 4 (2015) 308-313.

  • Kavanagh J., Sodium, potassium, calcium, magnesium, zinc, citrate and chloride content of human prostatic and seminal fluid, J. Reprod. Fert. 75 (1985) 35-41.

  • Mazik M., Cavga H. and Jones P.G., Molecular recognition of carbohydrates with artificial receptors: mimicking the binding motifs found in the crystal structures of protein-carbohydrate complexes, J. Am.

  • Chem. Soc. 127 (2005) 9045-9052.

  • Bhaskar V. and Patel P., Formulation and evaluation of reservoir type transdermal patches of 18-B-glycyrrhetic acid with piperine as bioenhancer, Ind. Am. J. Pharm. Res. 4 (2014) 1298-1308.

  • Das B., Muhuri P. and Hazra D., Ultrasonic studies on alkali metal bromides in 2-methoxyethanol at 25°C, Acoust. Lett. 18 (1994) 69-73.

  • Shamkuwar P.B., Shahi S.R. and Jadhav S.T., Evaluation of antidiarrhoeal effect of black pepper (Piper nigrum L.), Asian J. Plant Sci. Res. 2 (2012) 48-53.

  • Suryanarayana C. and Kuppusamy J., Free volume and internal pressure of liquid from ultrasonic velocity, J. Acoust. Soc. Ind 4 (1976) 75.

  • Polák J., Murakami S., Lam V., flug H. P. and Benson G., Molar excess enthalpies, volumes, and Gibbs free energies of methanol-isomeric butanol systems at 25°C, Can. J. Chem. 48 (1970) 2457-2465.

  • Prakash O. and Darbari S., Excess thermodynamic properties of binary liquid mixtures, Acoust. Lett. 12 (1988) 35-39.

  • Naidu P.S. and Prasad K.R., Ultrasonic velocity and allied parameters in solutions of cypermethrin with xylene and ethanol, Indian J. Pure Appl. Phys. 42 (2004) 512517.

  • Rassing J. and Attwood D., Ultrasonic velocity and lightscattering studies on the polyoxyethylenepolyoxypropylene copolymer Pluronic F127 in aqueous solution, Int. J. Pharm. 13 (1982) 47-55.

  • Wadi R.K. and Ramasami P., Partial molal volumes and adiabatic compressibilities of transfer of glycine and DLalanine from water to aqueous sodium sulfate at 288.15, 298.15 and 308.15 K, J. Chem. Soc., Faraday Transac. 93 (1997) 243-247.

  • Hammes G.G. and Schimmel P.R., An investigation of water-urea and water-urea-polyethylene glycol interactions, J. Am. Chem. Soc. 89 (1967) 442-446.

  • Rao N. and Verrall R.E., Ultrasonic velocity, excess adiabatic compressibility, apparent molar volume, and apparent molar compressibility properties of binary liquid mixtures containing 2-butoxyethanol, Can. J. Chem. 65 (1987) 810-816.

  • Nithya R., Nithiyanantham S., Mullainathan S. and Rajasekaran M., Ultrasonic investigation of molecular interactions in binary mixtures at 303 K, J. Chem. 6 (2009) 138-140.

  • Awasthi A. and Shukla J., Ultrasonic and IR study of intermolecular association through hydrogen bonding in ternary liquid mixtures, Ultrasonics 41 (2003) 477-486.

  • Kessler L. and Dunn F., Ultrasonic investigation of the conformal changes of bovine serum albumin in aqueous solution, J. Phys. Chem. 73 (1969) 4256-4263.

  • Nithiyanantham S. and Palaniappan L., Thermodynamical and excess thermoacoustical study on some

  • monosaccharide (glucose) with enzyme amylase in aqueous media at 298.15 K, Eur. Phys. J. Appl. Phys. 53 (2011) 31101.

  • Rastogi M., Awasthi A., Gupta M. and Shukla J., Ultrasonic investigations of X... HO bond complexes, Indian J. Pure Appl. Phys. 40 (2002) 256-263.

  • Fort R. and Moore W., Viscosities of binary liquid mixtures, Transact. Faraday Soc. 62 (1966) 1112-1119.

  • G. Arul. and L. Palaniappan., Molecular interaction studies in the ternary mixture of cyclohexane+ toluene+ 2-propanol, Indian J. Pure Appl. Phys. 39 (2001) 561564.

  • Thirumaran S. and George D., Ultrasonic study of intermolecular association through hydrogen bonding in ternary liquid mixtures, ARPN J. Eng. Appl. Sci. 4 (2009) 1-11.

  • Sumathi T. and Maheswari J.U., Ultrasonic and theoretical studies of some ternary liquid mixtures at various temperatures, Indian J. Pure Appl. Phys. 47 (2009) 782-786.


Abstract Views: 373

PDF Views: 2




  • Acoustical and Excess Parameters in Binary Liquid Mixture at Temperature 303.15 K

Abstract Views: 373  |  PDF Views: 2

Authors

Pallavi B. Nalle
Department of Physics, Shivchhatrapati College, Aurangabad-431003, India
B. R. Shinde
Department of Physics, Sanjivani Rural Educational Society, College of Engineering, Kopargaon-423603,, India
S. U. Shinde
Department of Physics, Pratishthan Mahavidyalaya, Paithan, Aurangabad-431107, India
R. G. Dorik
Department of Physics, Vivekananda College, Aurangabad-431001, India
K. M. Jadhav
Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004, India

Abstract


Acoustical and excess parameters have been calculated from the experimentally measured data of ultrasonic velocity, density and viscosity in binary liquid mixtures containing herbal extract of drug Piper Nigrum with ZnCl2 over the composition range (number of moles (n) of drug = 0.7009, 1.4018, 2.1027, 2.8036 and 3.5045) at 303.15 K temperature. Obtained results are fitted to the Redlich - Kister polynomial equation. These results have been explained on the basis of the intermolecular interactions present in the liquid mixtures. Present investigation provides important information about the physiological system and used to understand the mechanism of their metabolism in the living system.

Keywords


Ultrasonic Velocity, Density, Adiabatic Compressibility, Excess Intermolecular Free Length, Molecular Interaction.

References