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Ultrasonic Studies of Cu (II) Soaps Derived from Groundnut and Seasame Oils


Affiliations
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, India
2 Department of Chemistyr, S.D. Govt. College Beawar-305901, India
 

Ultrasonic speed have been measured in pure and binary mixtures containing copper soaps derived from groundnut and sesame oils in 20 % and 40% methanol benzene mixture. From these values, the specific acoustic impedance, adiabatic compressibility, intermolecular free length, apparent molar compressibility, molar sound velocity, primary solvation number have been calculated. The results have been fitted to Masson equation. The results have been explained on the basis of intermolecular interactions.

Keywords

Copper Soaps, Methanol, Groundnut Oil, Sesame Oil, Ultrasonic Speed.
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  • Pawar N.R. and Chimankar O.P., Comparative study of ultrasonic absorption and relaxation behavior of polar solute and non-polar solvent, J. Pure Appl. Ultrason. 34 (2012) 49-52.
  • Sivakumar V., Verma R.V., Rao P.G. and Swaminathan G., Studies on the use of power ultrasound in solid liquid myrobal an extraction process. J. Clean Prod. 15 (2007) 1813-1818.
  • Nath G., Ultrasonic Study of Binary Mixture of Acetone with Bromo benzene and Chloro benzene at Different Frequencies, Chem. Sci. Trans. 1(3) (2012) 516-521.
  • Moharatha D., Talukdar M., Roy G.S. and Dash U.N., Evaluation of acoustic parameters of halides of alkali metals and Ammonium in aqueous and aqueous Dextran solutions at 298.15K, Researcher 3 (2011) 6-12.
  • Palani R. and Balakrishnan S., Acoustical properties of ternary mixtures of 1-alkanols in di-isopropyl ether and 2, 2, 2-trifluoroethanol mixed solvent, Indian J. Pure Appl. Phys. 48 (2010) 644-650.
  • Singh G. and Banipal T.S., Partial molar adiabatic compressibilities and viscosities of some amino acids in aqueous glycerol solutions at 298.15K, Indian J. Chem. 47A (2008) 1355.
  • Sharma R., Bhutra R. and Khan S., Micellar Behaviour of Copper Surfactants Derived from Fresh (Untreated) Sesame Oil and Used (Treated at High Temperature) Sesame Oil, Tenside Surf Det. 47 106-112.
  • Das J., Dash K., Swain S.K. and Swain N., Ultrasonic investigation in a polar-polar system, methyl-Isobutyl Ketone and aliphatic alcohols, J. Mol. Liquids. 81 (1999) 163-179.
  • Ranganayakulu S.V., Reddy C.S. and Reddy D.L., Ultrasonic studies of the binary mixtures of ethyl acetateand cresols-application of Kosower and Dimroth treatments, Mat. Chem. Phys. 90 (2005) 213-216.
  • Kanhekar S.R., Pravina P. and Govind K.B., Thermodynamic properties of electrolytes in aqueous solutions of glycine at different temperatures, Indian J. Pure Appl. Phys. 48 (2010) 95-99.
  • Fort R.J. and Moore W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc. 61 (1965) 2102-2111.
  • Banipal P.K. Chakal A.K. and Banipal T.S., Studies on volumetric properties of some saccharides in aqueous potassium chloride solutions over temperature range (288.15-318.15 K), J. Chem. Thermodynamic. 41 (2009) 452-483.
  • Savaroglu G. and Ozdemir M., Apparent molar volume and apparent molar isentropic compressibility of glycerol in fructose water at different temperature, J. Mol. Liquids. 137 (2008) 51-57.
  • Syal V.K., Chauhan S. and Gautam R., Ultrasonic velocity measurements of carbohydrates in binarymixtures of DMSO + H2O at 25°C, Ultrasonics. 36 (1998) 619621.
  • Ali A., Hyder S. and Nain A.K., Intermolecular and ion solvent interaction of sodium iodide and potassium iodide in dimethyl formamide + I-propanol mixtures at 303K, J. Pure Appl. Ultrason. 21 (1999) 127-131.
  • Punitha S. and Uvarani R., Physico-chemical studies on some saccharides in aqueous cellulose solutions at different temperatures- Acoustical and FTIR analysis J. Saudi Chem. Soc. 18 (2014) 657-665.
  • Kagathara V.M., Sanariya M.R. and Parsania P.H., Sound velocity and molecular interaction studies on chloroepoxy resins solutions at 30°C, Eur. Polym. J. 36 (2000) 2371-2374.
  • Dash A.K. and Paikaray R., Acoustical study on ternary mixture of dimethyl acetamide (DMAC) in diethyl ether and isobutyl methyl ketone at different frequencies, Phys.Chem. Liq. 51(6) (2013) 749-763.
  • Singh S. and Bahadur I., Density and speed of sound of 1-ethyl-3-methylimidazolium ethylsulphate with acetic or propionic acid at different temperatures, J. Mol. Liq. 199 (2014) 518-523.
  • Jahagirdar B.V., Arbad. B.R., Walvekar. A.A., Shankarwer A.G. and Lande M., Studies in partial molar volumes, partial molar compressibilities and viscosity Bcoefficients of caffeine in water at four temperatures, J. mol. liq. 85 (2000) 361-373.

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  • Ultrasonic Studies of Cu (II) Soaps Derived from Groundnut and Seasame Oils

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Authors

Arun Kumar Sharma
Department of Chemistry, S.P.C. Govt. College Ajmer-305001, India
Meenakshi Saxena
Department of Chemistyr, S.D. Govt. College Beawar-305901, India
Rashmi Sharma
Department of Chemistry, S.P.C. Govt. College Ajmer-305001, India

Abstract


Ultrasonic speed have been measured in pure and binary mixtures containing copper soaps derived from groundnut and sesame oils in 20 % and 40% methanol benzene mixture. From these values, the specific acoustic impedance, adiabatic compressibility, intermolecular free length, apparent molar compressibility, molar sound velocity, primary solvation number have been calculated. The results have been fitted to Masson equation. The results have been explained on the basis of intermolecular interactions.

Keywords


Copper Soaps, Methanol, Groundnut Oil, Sesame Oil, Ultrasonic Speed.

References