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Acoustical Studies of Molecular Interaction in Ternary Liquid Mixture of Cresols With Benzaldehyde and Tetrachloromethane Solutions at 303, 308 and 313K


Affiliations
1 Department of Physics, D.D.E., Annamalai University, Annamalainagar-608002, India
2 Department of Physics, Sri Chandrasekarendra Saraswathi Viswa Mahavidyalaya, Enathur, Kanchipuram-631561, India
 

Ultrasonic velocity (U), density (ρ) and viscosity (η) for the ternary liquid mixtures of benzaldehyde+tetrachloromethane+o-cresol, benzaldehyde+tetrachloromethane+m-cresol and benzaldehyde+tetrachloromethane+p-cresol have been measured as a function of the composition at 303, 308 and 313K. The experimental data have been used to calculate some excess acoustical parameters, such as adiabatic compressibility (βE), free length (LfE) and free volume (VfE). The results are discussed and interpretered in terms of specific interaction predominated by hydrogen bonding.

Keywords

Ultrasonic Velocity, Adiabatic Compressibility, Free Length (LfE), Free Volume (VfE), Hydrogen Bonding.
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  • Acoustical Studies of Molecular Interaction in Ternary Liquid Mixture of Cresols With Benzaldehyde and Tetrachloromethane Solutions at 303, 308 and 313K

Abstract Views: 271  |  PDF Views: 0

Authors

R. Palani
Department of Physics, D.D.E., Annamalai University, Annamalainagar-608002, India
S. Kalavathy
Department of Physics, Sri Chandrasekarendra Saraswathi Viswa Mahavidyalaya, Enathur, Kanchipuram-631561, India

Abstract


Ultrasonic velocity (U), density (ρ) and viscosity (η) for the ternary liquid mixtures of benzaldehyde+tetrachloromethane+o-cresol, benzaldehyde+tetrachloromethane+m-cresol and benzaldehyde+tetrachloromethane+p-cresol have been measured as a function of the composition at 303, 308 and 313K. The experimental data have been used to calculate some excess acoustical parameters, such as adiabatic compressibility (βE), free length (LfE) and free volume (VfE). The results are discussed and interpretered in terms of specific interaction predominated by hydrogen bonding.

Keywords


Ultrasonic Velocity, Adiabatic Compressibility, Free Length (LfE), Free Volume (VfE), Hydrogen Bonding.