Journal of Pure and Applied Ultrasonics

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Speeds of Sound and Isentropic Compressibilities of Nonelectrolyte Liquid Mixtures Containing Ethylene Glycol and Amines


Affiliations
1 Department of Chemistry, Sri Krishnadevaraya University, Anantapur, India
2 Departnent of Chemistry, Sri Sai Baba National PG College, Anantapur, India
 

The speeds of sound and densities were measured for the binary liquid mixture of ethylene glycol with n-butylamine (NBA), sec-butylamihe (SBA), tertbutylamine(TBA), n-hexylamine (NHA), n-octylamine (NOA) and cyclohexylamine (CHA) over the whole mole fraction range at 308.15 K. From the experimental data various acoustical parameters, such as isentropic compressibility (ks), intermolecular free-length (Lf), relative association (RA), acoustic impendence (z), excess isentropic compressibility (KsE), excess inter molecular free-length (LfE), excess ultrasonic velocity (UE) and excess acoustic impedance (ZE) have been calculated. The behavior, of the present binary liquid mixtures is discussed in terms of possible molecular interactions between unlike molecules. The molecular interactions are discussed from the increasing number of methylene groups in amines, branching and cyclic nature of the amines which indicates the presence of AB type of interactions exist in these binary liquid mixtures.
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  • Speeds of Sound and Isentropic Compressibilities of Nonelectrolyte Liquid Mixtures Containing Ethylene Glycol and Amines

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Authors

K. G. Neerajakshi
Department of Chemistry, Sri Krishnadevaraya University, Anantapur, India
K. S. V. Krishna Rao
Departnent of Chemistry, Sri Sai Baba National PG College, Anantapur, India
R. Bharathi
Department of Chemistry, Sri Krishnadevaraya University, Anantapur, India
A. B. V. Kiran Kumar
Department of Chemistry, Sri Krishnadevaraya University, Anantapur, India
M. C. S. Subha
Department of Chemistry, Sri Krishnadevaraya University, Anantapur, India
G. Narayana Swamy
Department of Chemistry, Sri Krishnadevaraya University, Anantapur, India

Abstract


The speeds of sound and densities were measured for the binary liquid mixture of ethylene glycol with n-butylamine (NBA), sec-butylamihe (SBA), tertbutylamine(TBA), n-hexylamine (NHA), n-octylamine (NOA) and cyclohexylamine (CHA) over the whole mole fraction range at 308.15 K. From the experimental data various acoustical parameters, such as isentropic compressibility (ks), intermolecular free-length (Lf), relative association (RA), acoustic impendence (z), excess isentropic compressibility (KsE), excess inter molecular free-length (LfE), excess ultrasonic velocity (UE) and excess acoustic impedance (ZE) have been calculated. The behavior, of the present binary liquid mixtures is discussed in terms of possible molecular interactions between unlike molecules. The molecular interactions are discussed from the increasing number of methylene groups in amines, branching and cyclic nature of the amines which indicates the presence of AB type of interactions exist in these binary liquid mixtures.