Journal of Pure and Applied Ultrasonics

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Acoustical and Excess Parameter Studies of Piperine with MgCl2


Affiliations
1 Department of Physics, Shivchhatrapati College, Aurangabad-431005, India
2 Department of Physics, Vivekanand College, Aurangabad-431005, India
3 Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431005, India
 

Ultrasonic velocity, density and viscosity of drug Piperine with MgCl2 have been measured as a function of number of moles n = (0.7009, 1.4018, 2.1027, 2.8036 and 3.5045) at 323.15 K, 328.15 K and 333.15 K. The experimentally collected data have been used to calculate various acoustical, thermodynamic and excess parameters such as excess values of adiabatic compressibility, excess intermolecular free length, excess specific acoustic impedance, excess relaxation amplitude and excess relaxation time have been calculated. Above excess parameters are fitted to the Redlich-Kister equation. The results of acoustical, thermodynamic and excess properties reveal the existence of strong molecular interaction in the mixtures. The drug works as a structure breaker (it breaks the structure of MgCl2) and there is ion formation in the system. Acoustic, thermodynamic and excess parameter of mixture reflects the structural deformation in terms of intermolecular interaction.

Keywords

Excess Adiabatic Compressibility, Molecular Interaction, Redlich-Kister Equation, Ultrasonic Investigation.
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  • Acoustical and Excess Parameter Studies of Piperine with MgCl2

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Authors

Pallavi B. Nalle
Department of Physics, Shivchhatrapati College, Aurangabad-431005, India
R. G. Dorik
Department of Physics, Vivekanand College, Aurangabad-431005, India
K. M. Jadhav
Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431005, India

Abstract


Ultrasonic velocity, density and viscosity of drug Piperine with MgCl2 have been measured as a function of number of moles n = (0.7009, 1.4018, 2.1027, 2.8036 and 3.5045) at 323.15 K, 328.15 K and 333.15 K. The experimentally collected data have been used to calculate various acoustical, thermodynamic and excess parameters such as excess values of adiabatic compressibility, excess intermolecular free length, excess specific acoustic impedance, excess relaxation amplitude and excess relaxation time have been calculated. Above excess parameters are fitted to the Redlich-Kister equation. The results of acoustical, thermodynamic and excess properties reveal the existence of strong molecular interaction in the mixtures. The drug works as a structure breaker (it breaks the structure of MgCl2) and there is ion formation in the system. Acoustic, thermodynamic and excess parameter of mixture reflects the structural deformation in terms of intermolecular interaction.

Keywords


Excess Adiabatic Compressibility, Molecular Interaction, Redlich-Kister Equation, Ultrasonic Investigation.

References