Journal of Pure and Applied Ultrasonics

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Ultrasonic study of calcium soaps (laurate and myristate)


Affiliations
1 Department of Chemistry, RBS College, Agra-282 002, India., India
2 Department of Chemistry, V.S.S.D. College, Kanpur-208 002, India., India
3 Department of Chemistry, Agra College Agra College, Agra-282 002, India., India
 

Ultrasonic studies on calcium soaps (laurate and myristate) were performed to determine the critical micelle concentration (CMC), soap-solvent interaction, and various acoustic parameters. The values of the CMC decrease with the increase in the chain length of the soap molecules. The ultrasonic velocity, specific acoustic impedance, apparent molar compressibility, and relative association increase while the adiabatic compressibility, intermolecular free length, and solvation number, decrease with increasing soap concentration. The ultrasonic velocity results show that calcium soaps behave like a simple electrolyte in the solutions and that there is significant interaction between the soap and solvent molecules in dilute solutions.

Keywords

Ultrasonic Velocity, Specific Acoustic Impedance.
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  • Wilfred Gallay Ira Euddington, The Recrystalisation of calcium soaps in Mineral oils, Canadian Journal of Research, 22(b)6, (1994) 76-89.

  • Varma R.P. and Jindal R., Studies of Infrared Spectra of Cerium (IV) Soaps and their Solubilities in Benzene and Benzene-Methanol Mixtures, Tenside detergents, 22, (1982) 193.

  • Mehrotra K.N., Gahlaut A.S. and Meera Sharma, Conductometric investigations on lanthanum soap solutions Conductometric investigations on lanthanum soap solutions, Journal of the American Oil Chemists Society, 63,(1986) 1571-1575.

  • Mehrotra K.N., Mithlesh Chauhan and Shukla R.K., Influence of alkanols on the micellar behavior of samarium soaps, Surfactants & detergents, Journal of the American oil Chemists, 67,(1990) 446-450.

  • Mehrotra K.N. and Rawat M.K., Ultrasonic and Viscometric Studies on Magnisium Dicaprate in Organic Solvants, Indian Journal of Pure and Applied Physics, 29,(1991) 131-133.

  • Shukla R.K., Mithlesh Chauhan and Vikas Mishra, Effect of electrolytes and non-electrolyte on micellar behaviour of lanthanum soaps in non-aqueous solvents, Physics and Chemistry of Liquids an International Journal, 45,(2007) 345-349.

  • Rawat M.K. and Singh N., Ultrasonic Velocity and other Allied Parameters of Fe(III) Soaps in Non Aqueous Medium, Journal of Material Science Research India, 3(1), (2006) 72-77.

  • Rawat M.K., Ultrasonic Measurements and other Allied Parameters of Alkaline Earthmetal soaps in Mixed organic Solvents, Journal of Chemtracs Bodhgaya, 9,(2007)

  • Rawat M.K. and Sharma G., Ultrasonic velocity and allied properties of manganese, cobalt and copper soaps in non-aqueous medium. Journal of the Indian Chemical Society, 84,(2007) 46-49.

  • Rawat M.K., Sharma Y. and Kumari S., Molecular interaction and compressibility behaviour of beryllium soaps in non-aqueous medium, Asian Journal of Chemistry, 20(2), (2008) 1464-1472.

  • Rawat M.K., Ultrasonic study of molecular interaction and Compressibility Behavior of Magnisium Carboxylates, Journal of Applicable Chemistry, 3(2), (2013) 168-175.

  • Sangeeta and M.K. Rawat, ultrasonic velocity and other allied Parameters of Dysprosium Laurate and Myristate, Journal of applicable chemistry, 3(1), (2014) 354-359.

  • Rawat M.K. and Sangeeta, Ultrasonic study of molecular interactions and compressibility behaviour of strontium soaps in chloroform-propylene glycol mixture, Journal of Pure and Applied Physics, 46,(2008), 187-192.

  • Francesca Caterina Izzo, Matilde Kratter, AustinNevin and Elisabetta Zendri, A Critical Review on the Analysis of Metal Soaps in Oil Paintings, Chemistry Open, 10, (2021) 904-921.

  • Wei-Chuwan Lin and Shyr-Jin Tsay, Nuclear magnetic resonance studies on the intermolecular association in some binary mixtures. I. Chloroform and proton-acceptor solvents, The Journal of Physical Chemistry, 74(5), (1970) 1037-1041 .

  • Coburn W.C. Jr. and Ernest Grunwald, Infrared Measurements of the Association of Ethanol in Carbon Tetrachloride, Journal of American Chemical Society, 80(6), (1958) 1318-1322.

  • Ryszard Zielinski, Shoichi lkeda, Hiroyasu Nonura and Shigeokato, Effect temperature on micelle formation in Aqueous solution of Alkyl tri methyl ammonium bromide, Journal of Collide and Interface Science. 129,(1989) 175-184.

  • Subramanyam Naidu P. and Ravindra Prasad K., Ultrasonic velocity and allied parameters in solutions of cypermethrin with xylene and ethanol, Indian J. Pure & Appl. Phys., 42,(2004) 512.

  • Furniss A.S., Ilannaford A.J., Rogers V., Smith P.W.G. and Tachell A.R., Vogel's Text Book of Practical Organic Chemistry, 4th Edition, (1980). Longmann.

  • Subramanyam Naidu P. and Ravindra Prasad K., Molecular interactions in binary mixtures -an ultrasonic study, Indian J. Pure & Appl. Phys., 40,(2002) 264.

  • Jacobson B., Anderson W.A. and Arnold J.T., A proton magnetic resonance study of the hydration of deoxyribonucleic acid. Nature, 173,(1954) 772-773.

  • Garnsey R., Boe R.J., Mohoney R. and Litovitz T.A., J. Chem. Phys., 50,5222 (1969).


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  • Ultrasonic study of calcium soaps (laurate and myristate)

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Authors

Mahesh Singh Khirwar
Department of Chemistry, RBS College, Agra-282 002, India., India
Ashish K. Singh
Department of Chemistry, V.S.S.D. College, Kanpur-208 002, India., India
Sandeep K. Singh
Department of Chemistry, V.S.S.D. College, Kanpur-208 002, India., India
M.K. Rawat
Department of Chemistry, Agra College Agra College, Agra-282 002, India., India
Gyan Prakash
Department of Chemistry, V.S.S.D. College, Kanpur-208 002, India., India

Abstract


Ultrasonic studies on calcium soaps (laurate and myristate) were performed to determine the critical micelle concentration (CMC), soap-solvent interaction, and various acoustic parameters. The values of the CMC decrease with the increase in the chain length of the soap molecules. The ultrasonic velocity, specific acoustic impedance, apparent molar compressibility, and relative association increase while the adiabatic compressibility, intermolecular free length, and solvation number, decrease with increasing soap concentration. The ultrasonic velocity results show that calcium soaps behave like a simple electrolyte in the solutions and that there is significant interaction between the soap and solvent molecules in dilute solutions.

Keywords


Ultrasonic Velocity, Specific Acoustic Impedance.

References