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Dorik, R. G.
- Acoustical and Excess Parameters in Binary Liquid Mixture at Temperature 303.15 K
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Authors
Affiliations
1 Department of Physics, Shivchhatrapati College, Aurangabad-431003, IN
2 Department of Physics, Sanjivani Rural Educational Society, College of Engineering, Kopargaon-423603,, IN
3 Department of Physics, Pratishthan Mahavidyalaya, Paithan, Aurangabad-431107, IN
4 Department of Physics, Vivekananda College, Aurangabad-431001, IN
5 Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004, IN
1 Department of Physics, Shivchhatrapati College, Aurangabad-431003, IN
2 Department of Physics, Sanjivani Rural Educational Society, College of Engineering, Kopargaon-423603,, IN
3 Department of Physics, Pratishthan Mahavidyalaya, Paithan, Aurangabad-431107, IN
4 Department of Physics, Vivekananda College, Aurangabad-431001, IN
5 Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 39, No 1 (2017), Pagination: 1-7Abstract
Acoustical and excess parameters have been calculated from the experimentally measured data of ultrasonic velocity, density and viscosity in binary liquid mixtures containing herbal extract of drug Piper Nigrum with ZnCl2 over the composition range (number of moles (n) of drug = 0.7009, 1.4018, 2.1027, 2.8036 and 3.5045) at 303.15 K temperature. Obtained results are fitted to the Redlich - Kister polynomial equation. These results have been explained on the basis of the intermolecular interactions present in the liquid mixtures. Present investigation provides important information about the physiological system and used to understand the mechanism of their metabolism in the living system.Keywords
Ultrasonic Velocity, Density, Adiabatic Compressibility, Excess Intermolecular Free Length, Molecular Interaction.References
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- Acoustical and Excess Parameter Studies of Piperine with MgCl2
Abstract Views :244 |
PDF Views:0
Authors
Affiliations
1 Department of Physics, Shivchhatrapati College, Aurangabad-431005, IN
2 Department of Physics, Vivekanand College, Aurangabad-431005, IN
3 Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431005, IN
1 Department of Physics, Shivchhatrapati College, Aurangabad-431005, IN
2 Department of Physics, Vivekanand College, Aurangabad-431005, IN
3 Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431005, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 41, No 2 (2019), Pagination: 27-35Abstract
Ultrasonic velocity, density and viscosity of drug Piperine with MgCl2 have been measured as a function of number of moles n = (0.7009, 1.4018, 2.1027, 2.8036 and 3.5045) at 323.15 K, 328.15 K and 333.15 K. The experimentally collected data have been used to calculate various acoustical, thermodynamic and excess parameters such as excess values of adiabatic compressibility, excess intermolecular free length, excess specific acoustic impedance, excess relaxation amplitude and excess relaxation time have been calculated. Above excess parameters are fitted to the Redlich-Kister equation. The results of acoustical, thermodynamic and excess properties reveal the existence of strong molecular interaction in the mixtures. The drug works as a structure breaker (it breaks the structure of MgCl2) and there is ion formation in the system. Acoustic, thermodynamic and excess parameter of mixture reflects the structural deformation in terms of intermolecular interaction.Keywords
Excess Adiabatic Compressibility, Molecular Interaction, Redlich-Kister Equation, Ultrasonic Investigation.References
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- Nithiyanantham S. and Palaniappan L., Thermodynamical and excess thermoacoustical study on some monosaccharide (glucose) with enzyme amylase on aqueous media at 298.15 K, Euro. Phys. J. Appl. Phys. 53 (2011) 31101.
- Kessler L. and Dunn F., Ultrasonic investigation of the conformal changes of bovine serum albumin in aqueous solution, J. Phys. Chem. 73 (1969) 4256-4263.
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