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Dey, Ranjan
- Theoretical Prediction of Ultrasonic Velocities and Interaction Studies for the Pb-Sn Alloy
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Affiliations
1 Department of Chemistry, University of Allahabad, Allahabad-211 002, IN
2 Department of Physics, Brahmanand College, Kanpur, IN
1 Department of Chemistry, University of Allahabad, Allahabad-211 002, IN
2 Department of Physics, Brahmanand College, Kanpur, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 29, No 4 (2007), Pagination: 111-115Abstract
A comparative study of ultrasonic velocity evaluated from Schaaffs collision factor theory (CFT), Nomoto relation, ideal mixing relation and Junjie relation has been carried out for the Pb-Sn alloy at three different temperatures and at various compositions. The agreement between experimental and theoretical values is quite satisfactory. The computed values of sound velocities from ideal-mixing relation have been used to obtain the degree of molecular interaction. Interaction studies have also been made in terms of excess intermolecular free-length and excess acoustic impedance.- Modified Flory Theory and Pseudo Spinodal Equation of State for the Evaluation of Isothermal Compressibility, Isentropic Compressibility, Internal Pressure and Pseudo Gruneisen Parameter of Binary Liquid Mixtures at Elevated Pressure
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Authors
Affiliations
1 Department of Chemistry, University of Allahabad, Allahabad-211002, IN
2 Department of Electronics, E.C.C., Allahabad, IN
1 Department of Chemistry, University of Allahabad, Allahabad-211002, IN
2 Department of Electronics, E.C.C., Allahabad, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 28, No 1 (2006), Pagination: 20-28Abstract
Flory's statistical theory has been extended for the computation of internal pressure, isentropic compressibility, isothermal compressibility and Pseudo Gruneisen parameter of binary mixture nitrobenzene+benzene at pressure up to 10 MPa and at two different temperatures (293.15K, 303.15K & 313.15K). For a comparative study of the isothermal compressibility of this system, equation of state based on the psuedo spinodal hypothesis developed by Baonza et al has also been utilized to deduce the isothermal compressibility of this mixture. The computed values of Pint, βT, βs and Γ have been compared with the experimental findings available in literature. Satisfactory agreement has been found between experimental and theoretical values.- Estimation of Effective Debye Temperature of Multi Component Liquid Mixtures at 298.15k
Abstract Views :334 |
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Authors
Affiliations
1 Department of Physics, V.S.S.D. College, Kanpur-208002, IN
2 College of Engineering Science & Technology, Lucknow-226010, IN
3 Department of Chemistry, BITS Pilani, K.K. Birla Goa Campus, Zuarinagar, Goa-403726, IN
4 Amity Institute of Applied Sciences, Amity University, Noida-201313, IN
1 Department of Physics, V.S.S.D. College, Kanpur-208002, IN
2 College of Engineering Science & Technology, Lucknow-226010, IN
3 Department of Chemistry, BITS Pilani, K.K. Birla Goa Campus, Zuarinagar, Goa-403726, IN
4 Amity Institute of Applied Sciences, Amity University, Noida-201313, IN
Source
Journal of Pure and Applied Ultrasonics, Vol 41, No 1 (2019), Pagination: 19-23Abstract
The Debye temperature has been computed for four quaternary mixtures over the entire range of composition at 298.15K. We have applied three different approaches and evaluated the Debye temperature using experimental data of ultrasonic velocity and density. This paper aims to portray the comparison of all the three approaches applied on the four quaternary mixtures which is being done for the first time to the best of authors knowledge .A good agreement is observed among the values computed with all the three approaches.Keywords
Debye Temperature, Quaternary Liquid Mixtures, Ultrasonic Velocities, Density.References
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