Indian Journal of Engineering & Materials Sciences

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Effect of acyl chloride functionalized carbon black on mechanical and thermal properties of acrylonitrile butadiene styrene/polyaniline blend


Affiliations
1 Department of Chemistry, National Institute of Technology Agartala, Tripura 799 046, India
2 Department of Mechanical and Industrial Engineering, Indian Institute of Technology Roorkee, Uttarakhand 247 667, India
3 Department of Mechanical Engineering, Netaji Subhas University of Technology, New Delhi 110 078, India

Pristine Carbon Black (CB) has been first oxidised to introduce carboxylic acid functional group on the surface of CB, followed by treating with thionyl chloride. The presence of acyl chloride group in the resultant product has been ascertained by FTIR spectroscopy. The acyl chloride functionalized CB (CB-Ac) has been used as a filler in Acrylonitrile Butadiene Styrene (ABS)/Polyaniline (PANI) blend to improve the mechanical and thermal properties. Further addition of Nanoclay (NC) in the blend has improved the dispersion of fillers in the polymer matrix as confirmed by FESEM images and XRD pattern. The Ultimate Tensile Analysis (UTA) and Dynamic mechanical analysis (DMA) have been studied. The Young modulus has shown increment of 48% and 66% in case of CB-Ac and CB-Ac/NC filled blend, respectively. The ultimate tensile strength has also been found to be increased in CB-Ac and CB-Ac/NC filled blends. DMA has given the insight about the excellent improvement in damping properties of the composites due to filler addition. Themo gravimetric analysis (TGA) and Differential scanning calorimetry (DSC) has been carried out to ascertain the thermal properties. TGA has revealed the excellent augmentation in the flame retardancy and heat resistance of the composites due to CB-Ac/NC loading. DSC study has further verified the improvement in degree of crystallinity due to interfacial attraction between fillers and polymer matrix.
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  • Effect of acyl chloride functionalized carbon black on mechanical and thermal properties of acrylonitrile butadiene styrene/polyaniline blend

Abstract Views: 91  | 

Authors

Narayan Debnath Debnath
Department of Chemistry, National Institute of Technology Agartala, Tripura 799 046, India
Souvik Bag
Department of Mechanical and Industrial Engineering, Indian Institute of Technology Roorkee, Uttarakhand 247 667, India
Vinay Panwar
Department of Mechanical Engineering, Netaji Subhas University of Technology, New Delhi 110 078, India
Mitali Saha
Department of Chemistry, National Institute of Technology Agartala, Tripura 799 046, India
Kaushik Pal
Department of Mechanical and Industrial Engineering, Indian Institute of Technology Roorkee, Uttarakhand 247 667, India

Abstract


Pristine Carbon Black (CB) has been first oxidised to introduce carboxylic acid functional group on the surface of CB, followed by treating with thionyl chloride. The presence of acyl chloride group in the resultant product has been ascertained by FTIR spectroscopy. The acyl chloride functionalized CB (CB-Ac) has been used as a filler in Acrylonitrile Butadiene Styrene (ABS)/Polyaniline (PANI) blend to improve the mechanical and thermal properties. Further addition of Nanoclay (NC) in the blend has improved the dispersion of fillers in the polymer matrix as confirmed by FESEM images and XRD pattern. The Ultimate Tensile Analysis (UTA) and Dynamic mechanical analysis (DMA) have been studied. The Young modulus has shown increment of 48% and 66% in case of CB-Ac and CB-Ac/NC filled blend, respectively. The ultimate tensile strength has also been found to be increased in CB-Ac and CB-Ac/NC filled blends. DMA has given the insight about the excellent improvement in damping properties of the composites due to filler addition. Themo gravimetric analysis (TGA) and Differential scanning calorimetry (DSC) has been carried out to ascertain the thermal properties. TGA has revealed the excellent augmentation in the flame retardancy and heat resistance of the composites due to CB-Ac/NC loading. DSC study has further verified the improvement in degree of crystallinity due to interfacial attraction between fillers and polymer matrix.