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Surface Tension of Polyurethane Solution and Thermodynamic Model


Affiliations
1 School of Chemical Engineering, Zhengzhou University, No. 100 Science Road, Zhengzhou, 450001, China
2 Zhengzhou Museum, No. 168 Songshan South Road, Zhengzhou,450002, China
 

A new improved polyurethane materials was studied to improve the strength of paper, delay the aging of paper, solve the problem of poor permeability of traditional resins to paper, and meanwhile to provide basic data for industrial design and applications, the surface tension of composite solutions consisting of nano-SiO2-based polyurethane, organo silicon-based polyurethane and epoxy cyclohexane-epichlorohydrin polyurethane dissolved in ethyl acetate had been measured at temperatures ranging from 283.15 K to 308.15 K. The surface tension was fitted with the related equation between surface tension and temperature under normal pressure. The mean relative deviations between the calculated value and the experimental value were derived. The results showed that the model estimation of the surface tension of the composite solution were in good agreement with the experimental data, the paper coated by the polyurethane materials had better mechanical property. Therefore, the prepared polyurethane material has great application prospects in the protection of paper.

Keywords

Ethyl Acetate, Linear Correlation, Polyurethane, Surface Tension.
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  • Peng C & Chen Y, Coordin Chem Rev, 51 (2016) 2.

  • Das A & Mahanwar P, Adv Ind Eng Polym Res, 3 (2020) 93.

  • Lin J, Study on polyurethane elastomers based on caser Oil-polyether polyol, Master thesis, Taiyuan University of Technology, Shanxi, 2012.

  • Sierkezos N G & Molinou I E, J Solution Chem, 35(2006) 279.

  • Atashrouz S, Amini E and Pazuki G, Ionics, 21(2015) 1595.

  • Tahery R, Modarress H and Satherley J, J Chem Eng Data, 51 (2006) 1039.

  • Han J & Ma G, J Bingzhou Univ, 26 (2010) 101.

  • Ma G & Feng W, Physics Experiment, 32 (2012) 25.

  • Jiao L & Lu S, Physics Experiment, 22 (2002) 40.

  • Esmaeili H & Hashemipour H, J Mol Liq, 272 (2018) 692.

  • Zhao D, Zhuang Y, Fan C, Yang F, Chen Y, Zhang X, J Chem Thermodynamics, 143 (2020) 106041.

  • Vakili-Nezhaad G R, Al-Wadhahi M, Al-Haddabi S, Vakilinejad A, Acree W E, J Mol Liq, 296 (2019) 112008.


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  • Surface Tension of Polyurethane Solution and Thermodynamic Model

Abstract Views: 174  |  PDF Views: 95

Authors

Jinjie Zhang
School of Chemical Engineering, Zhengzhou University, No. 100 Science Road, Zhengzhou, 450001, China
Yingping Qi
Zhengzhou Museum, No. 168 Songshan South Road, Zhengzhou,450002, China
Pei Lu
School of Chemical Engineering, Zhengzhou University, No. 100 Science Road, Zhengzhou, 450001, China
Yongfeng Shen
Zhengzhou Museum, No. 168 Songshan South Road, Zhengzhou,450002, China
Hua Li
School of Chemical Engineering, Zhengzhou University, No. 100 Science Road, Zhengzhou, 450001, China

Abstract


A new improved polyurethane materials was studied to improve the strength of paper, delay the aging of paper, solve the problem of poor permeability of traditional resins to paper, and meanwhile to provide basic data for industrial design and applications, the surface tension of composite solutions consisting of nano-SiO2-based polyurethane, organo silicon-based polyurethane and epoxy cyclohexane-epichlorohydrin polyurethane dissolved in ethyl acetate had been measured at temperatures ranging from 283.15 K to 308.15 K. The surface tension was fitted with the related equation between surface tension and temperature under normal pressure. The mean relative deviations between the calculated value and the experimental value were derived. The results showed that the model estimation of the surface tension of the composite solution were in good agreement with the experimental data, the paper coated by the polyurethane materials had better mechanical property. Therefore, the prepared polyurethane material has great application prospects in the protection of paper.

Keywords


Ethyl Acetate, Linear Correlation, Polyurethane, Surface Tension.

References