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Co-crystal Growth and Characterizations of Diisopropylammonium Hydrogen Phthalate


Affiliations
1 Department of Physics, Netaji Subhas University of Technology, New Delhi 110 078, India
 

Slow evaporation solution growth approach has been utilized to synthesize the single co-crystal of diisopropylammonium hydrogen phthalate at room temperature. Its structural attributes owing to the refinement of its cell parameters have been successfully confirmed using Debye – Scherrer method. Ultraviolet-visible spectroscopy has further revealed the optical behaviour of the aforesaid crystal having a 301 nm cut-off with a broad direct optical energy band of 4.09 eV. Its vibrational assignments have been determined using Fourier transform infrared spectral study. Photoluminescence spectroscopy has highlighted the violet emission from the crystal when stimulated by 300 nm excitation wavelength. Vickers micro hardness technique has as certained the mechanical strength of the grown crystal along with the work-hardening coefficient thereby claiming its normal ISE behaviour to the external load. Conclusively, this work has featured the prominence of diisopropylammonium hydrogen phthalate co-crystal for optical applications.

Keywords

Co-crystal, Hardness, Photoluminescence, UV- visible optical study, XRD refinement.
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  • Kumar M S, Rajesh K, Vijayaraghavan G V, Krishnan S, Mater Res Express, 5 (2018).

  • Bhat H L, Introduction to crystal growth: principles and practice (CRC Press, Florida) 2015.

  • Sun Y, Tilbury C J, Reutzel-Edens S M, Bhardwaj R M, Li J, Doherty M F, Cryst Growth Des, 18 (2018) 905.

  • Ehmann H M A, Werzer O, Cryst Growth Des, 14 (2014) 3680.

  • Janarthanan S, Rajan Y C, Samuel R S, Pandi S, Adv Mat Res, 584 (2012) 136.

  • Prince S, Suthan T, Gnanasambandam C, J Electron Mater, 51 (2022) 1639.

  • Fu D W, Cai H L, Liu Y, Ye Q, Zhang W, Zhang Y, Chen X Y, Giovannetti G, Capone M, Li J, Xiong R G, Science, 339 (2013) 425.

  • Gino D J, Sidden C, Paulraj R, Ajitha S, Somaily H H, J Mater Sci Mater Electron, 33 (2022) 16923.

  • Vij M, Sonia, Yadav H, Vashistha N, Kumar P, Maurya K K, J Mol Struct, 1206 (2020).

  • Vij M, Yadav H, Goel S, Vashisthaa N, Sonia, Nayaka D, Kumar P, Maurya K K, J MolStruct,1246 (2021) 131177

  • Dhawan P, Saini A, Goel S, Tyagi N, Yadav H, J Mol Struct, 1270 (2022).

  • Altomare A, Cuocci C, Giacovazzo C, Moliterni A, Rizzi R, Corriero N and Falcicchio A, J Appl Cryst, 46 (2013) 1231.

  • Phan V T, Do T T P, Nguyen D T, Nguyen K D, Vo T T N, Le A T Q, Huynh D T, Opt Quantum Electron, 53 (2021).

  • Vij M, Yadav H, Vashistha N, Kumari M, Verma H K, Kumar P, Maurya K K, J Mater Sci, 55 (2020) 16900.

  • Inkrataite G, Laurinavicius G, Enseling D, Zarkov A, Jüstel T, Skaudzius R, Crystals (Basel), 11 (2021).

  • Reena Priya J, Mercina M, Nancy M P, Mary Linet J, Arul Martin Mani J, Mater Today Proc, 65 (2022) 385.

  • Thangavel P, Karuppanan S, Muthusamy Poomalai P, Sakthivel A, Nandagopalan G, Bellucci S, Photonics, 9 (2022).

  • Liu F, Hooks D E, Li N, Rubinson J F, Wacker J N, Swift J A, Chemistry of Materials, 32 (2020) 3952.

  • Fernandes J M, Mahendra K, Udayashankar N K, Opt Mater (Amst), 110 (2020).

  • Farhat, S., Rekaby, M. &Awad, SN ApplSci, 1 (2019)546.

  • Goel S, Sinha N, Yadav H, Hussain A, Kumar B,Mater Res Bult,83 (2016) 77.


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  • Co-crystal Growth and Characterizations of Diisopropylammonium Hydrogen Phthalate

Abstract Views: 61  |  PDF Views: 46

Authors

Preetika Dhawan
Department of Physics, Netaji Subhas University of Technology, New Delhi 110 078, India
Harsh Yadav
Department of Physics, Netaji Subhas University of Technology, New Delhi 110 078, India

Abstract


Slow evaporation solution growth approach has been utilized to synthesize the single co-crystal of diisopropylammonium hydrogen phthalate at room temperature. Its structural attributes owing to the refinement of its cell parameters have been successfully confirmed using Debye – Scherrer method. Ultraviolet-visible spectroscopy has further revealed the optical behaviour of the aforesaid crystal having a 301 nm cut-off with a broad direct optical energy band of 4.09 eV. Its vibrational assignments have been determined using Fourier transform infrared spectral study. Photoluminescence spectroscopy has highlighted the violet emission from the crystal when stimulated by 300 nm excitation wavelength. Vickers micro hardness technique has as certained the mechanical strength of the grown crystal along with the work-hardening coefficient thereby claiming its normal ISE behaviour to the external load. Conclusively, this work has featured the prominence of diisopropylammonium hydrogen phthalate co-crystal for optical applications.

Keywords


Co-crystal, Hardness, Photoluminescence, UV- visible optical study, XRD refinement.

References