Indian Journal of Geo-Marine Sciences

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Adsorption of Chromium from Aqueous Solution Using Chitosan-g-Graphene/Hydroxyapatite Composite


Affiliations
1 Department of Chemistry, Bharathiar university, Coimbatore, Tamil Nadu – 641 046, India
2 School of Advanced Sciences, VIT University, Vellore, Tamilnadu – 632 014, India
3 PG and Research Department of Chemistry, DKM College for Women, Vellore, Tamil Nadu – 632 001, India
 

The preparation and characterisation of a polymeric composite incorporating graphene, hydroxyapatite, and chitosan as an adsorbent to remove chromium (VI) from wastewater. The FTIR and XRD studies supported the composite's production. Analysis of surface morphology and heat stability involved TGA and SEM studies. A batch adsorption was run to determine the efficacy of the adsorbent by varying contact time, adsorbent dose, and pH. The kinetics of the adsorption process were examined using pseudo-first and second order kinetic models after the equilibrium data had been fitted with the Langmuir and Freundlich isotherms. The findings showed that pseudo second order kinetics was utilised for the adsorption of Cr(VI) onto chitosan-grafted graphene/hydroxyapatite (CS-g-Gr/HA) composite.

Keywords

Adsorption, Chitosan, Chromium, Composite, Graphene, Hydroxyapatite.
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  • Guidelines for drinking-water quality, 2nd edn, Vol 2, Health criteria and other supporting information, (World Health Organization, Geneva), 1996.

  • Leyva-Ramos R, Zacobo-Azuara A, Diaz-Flores P E, Guerrero-Coronado R M, Mendoza-Barron J, et al., Adsorption of cadmium (II) from aqueous solution onto activated carbon, Colloids Surf A Physicochem Eng Asp, 330 (2008) 35–41.

  • Manjeet B, Diwan S & Garg V K, A comparative study for the removal of hexavalent chromium from aqueous solution by agriculture wastes’ carbons, J Hazard Mater, 171 (2009) 83–92.

  • Schneider R M, Cavalin C F, Barros M A S D & Tavares C R G, Adsorption of chromium ions in activated carbon, Chem Eng J, 132 (2007) 355–362.

  • Ronak B, Sreedhar B & Padmaja P, Adsorption of chromium from aqueous solutions using crosslinked chitosan–diethylenetriaminepentaacetic acid, Int J Biol Macromolec, 74 (2015) 458-466.

  • Mubarak N M, Sahu J N, Abdullah E C & Jayakumar N S, Removal of Heavy Metals from Wastewater Using Carbon Nanotubes, Sep Purif Rev, 43 (2014) 311–338.

  • Rengaraj S, Yeon K H & Moon S H, Removal of chromium from water and wastewater by ion exchange resins, J Hazard Mater, 87 (2001) 273–287.

  • Xiaoshu L, Jiang X, Guangming J, Jie T & Xinhua X, Highly active nanoscale zero-valent iron (nZVI)–Fe3O4 nanocomposites for the removal of chromium(VI) from aqueous solutions, J Colloid Interface Sci, 369 (2012) 460-469.

  • Hajeeth T, Vijayalakshmi K, Gomathi T & Sudha P N, Removal of Cu(II) and Ni(II) using cellulose extracted from sisal fiber and cellulose-g-acrylic acid copolymer, Int J Biol Macromolec, 62 (2013) 59-65.

  • Suresh G & Babu B V, Experimental Investigations and Theoretical Modeling Aspects in Column Studies for Removal of Cr(VI) from Aqueous Solutions Using Activated Tamarind Seeds, Chem Eng J, 150 (2009) 352-365.

  • Leyva-Ramos R & Juarez-Martinez A, Guerrero-coronado, RM, Adsorption of Chromium(VI) from aqueous solutions on activated carbon, Water Sci Tech, 30 (1994) 191-197.

  • Leyva-Ramos R, Jacobo-Azuara A, Diaz-Flores P E, Guerrero-Coronado R M, Mendoza-Barron J, et al., Adsorption of Chromium(VI) from an aqueous solution on a surfactant – modified zeolite, Colloids Surf A Physicochem Eng Asp, 330 (2008) 35-41.

  • Rajeev K, Muhammad E & Barakat M A, Synthesis and Characterization of carbon/AlOOH composite for adsorption of chromium(VI) from synthetic waste water, J Ind Eng Chem, 20 (2014) 4202-4206.

  • Hajeeth T, Gomathi T & Sudha P N, Adsorption of Cr(VI) from aqueous solution using cellulose extracted from sisal fiber, Indian J App Res, 3 (2013) 1-5.

  • Teoh Wah T, Takuma T & Kazunori S, Sorption of Pb(II), Cd(II), and Ni(II) Toxic Metal Ions by Alginate-Bentonite, J Environ Prot, 4 (2013) 51-55.

  • Qasem Naef A A, Ramy H M & Dahiru U L, Removal of heavy metal ions from wastewater: A comprehensive and critical review, Npj Clean Water, 4 (1) (2021) 1-15.

  • Aydin Y A & Aksoy N D, Adsorption of chromium on chitosan: Optimization, Kinetics and thermodynamics, Chem Eng J, 151 (2009) 188-194.

  • Nithya R, Gomathi T, Sudha P N, Venkatesan J, Sukumaran A, et al., Removal of Cr(VI) from aqueous solution using chitosan-g-poly(butylacrylate)/silica gel nanocomposite, Int J Biol Macromolec, 87 (2016) 545–554.

  • Kyzas G K, Kostoglou M & Lazaridis N K, Copper and Chromium (VI) removal by chitosan derivatives- Equilibrium and kinetic studies, Chem Eng J, 152 (2009) 440-448.

  • Sivakami M S, Gomathi T, Venkatesan J, Hee-Seok J, Se-kwon K, et al., Preparation and characterization of nano chitosan for treatment wastewaters, Int J Biol Macromolec, 57 (2013) 204-212.

  • Rajiv G M, Kousalya G N & Meenakshi S, Removal of copper(II) using chitin/chitosan nano-hydroxyapatite composite, Int J Biol Macromolec, 48 (2011) 119-124.

  • Jayakumar R, Prabaharan M, Reis R L & Mano J F, Graft copolymerized chitosan—present status and applications, Carbohydr Polym, 62 (2005) 142-158.

  • Shukla S K, Mishra A K, Arotiba O A & Mamba B B, Chitosan –based nanomaterials: A state-of –the-art review, Int J Biol Macromolec, 59 (2013) 46-58.

  • Zuoying C, Huacai G & Shengli L, Studies on synthesis and adsorption properties of chitosan cross-linked by glutaraldehyde and Cu (II) as template under microwave irradiation, Eur Polym J, 37 (2001) 2141-2143.

  • Rojas G, Silva J, Flores J A, Rodriguez A, Ly M, et al., Adsorption of chromium onto cross-linked chitosan, Sep Purif Tech, 44 (2005) 31-36.

  • Nalini S, Awantika D, Leela I & Rashmi S, Removal of hexavalent chromium using a novel cross linked xanthated chitosan, Bioresour Technol, 97 (2006) 2377-2382.

  • Wei W, Yang L, Zhong W, Cui J & Wei Z, Poorly crystalline hydroxyapatite: A novel adsorbent for enhanced fulvic acid removal from aqueous solution, Appl Surf Sci, 332 (2015) 328–339.

  • Yu X, Tong S, Ge M & Zuo J, Removal of fluoride from drinking water by celluloe@hydroxyapatite nanocomposites, Carbohydr Polym, 92 (2013) 269-275.

  • Krishna K A S, Shruti S K & Rajesh N, A novel amine impregnated graphene oxide adsorbent for the removal of hexavalent chromium, Chem Eng J, 230 (2013) 328-337.

  • Harijan D K L & Chandra V, Polyaniline functionalized graphene sheets for treatment of toxic hexavalent chromium, J Environmental Chem Eng, 4 (2016) 3006-3012.

  • Pan Y, Wu T, Bao H & Li L, Green fabrication of chitosan films reinforced with parallel aligned graphene oxide, Carbohydr Polym, 83 (2011) 1908-1915.

  • Liu L, Li C, Bao C, Jia Q, Xiao P, et al., Preparation and characterization of chitosan/grapheme oxide composites for the adsorption of Au(III) and Pb(II), Talanta, 93 (2012) 350-357.

  • Li B, Shan C L, Zhou Q, Fang Y, Wang Y L, et al., Synthesis, Characterization, and Antibacterial Activity of Cross-Linked Chitosan-Glutaraldehyde, Mar Drugs, 11 (2013) 1534-1552.

  • Monteiro O A C & Airoldil C, Chitosan based nanomaterial-A state- of -the- art- review, Int J Biol Macromolec, 59 (2013) 46-58.

  • Azzaoui K, Lamhamdi A, Mejdoubi E M, Berrabah M, Hammouti B, et al., Synthesis and characterization of composite based on cellulose acetate and hydroxyapatite application to the absorption of harmful substances, Carbohydr Polym, 111 (2014) 41-46.

  • Hu F, Wang X, Wang J, Liu F, Zhang M, et al., Microwave-assisted covalent modification of graphene nanosheets with chitosan and its electrorheological characteristics, Appl Surf Sci, 257 (2011) 2637-2642.

  • Gower L B, Biomimetic model systems for investigating the amorphous precursor pathway and its role in biomineralization, Chemical reviews, 108 (11) (2008) 4551-4627.

  • Neelgund G M, Oki A & Luo Z, In situ deposition of hydroxyapatite on grapheme nanosheets, Mater Res Bull, 48 (2013) 175-179.

  • Venkatesan J, Zhong-Ji Q, BoMi R, Nanjundan A K & Se-Kwon Kim, Preparation and characterization of carbon nanotube-grafted-chitosan–natural hydroxyapatite composite for bone tissue engineering, Carbohydr Polym, 83 (2011) 569-577.

  • Justin R & Chen B, Body temperature reduction of graphene oxide through chitosan functionalisation and its application in drug delivery, Mater Sci Eng C, 34 (2014) 50-53.

  • Jankovic A, Erakovic S, Mitric M, Matc I Z, Juranic Z D, et al., Bioactive hydroxyapatite/graphene composite coating and its corrosion stability in simulated body fluid, J Alloys Compd, 624 (2015) 148-157.

  • Sun Y, Yue Q, Mao Y, Gao B, Gao Y, et al., Enhanced adsorption of chromium onto activated carbon by microwave assisted H3PO4 mixed with Fe/Al/Mn activation, J Hazard Mater, 265 (2014) 191-200.

  • Ayawei N, Augustus N E & Donbebe W, Modelling and interpretation of adsorption isotherms, J Chem, 2017 (2017) pp. 11.

  • Wassel M, Swlem S A, Hamoda S & Desouky A, Studies on the preparation modified chitosan and its applications, Al-azhar Bull Sci, 24 (1) (2013) 33-48.

  • Liu X & Zhang L, Removal of phosphate anions using the modified chitosan beads: Adsorption kinetic, isotherm and mechanism studies, Powder Technol, 277 (2015) 112-119.


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  • Adsorption of Chromium from Aqueous Solution Using Chitosan-g-Graphene/Hydroxyapatite Composite

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Authors

V. Geetha
Department of Chemistry, Bharathiar university, Coimbatore, Tamil Nadu – 641 046, India
S. Latha
School of Advanced Sciences, VIT University, Vellore, Tamilnadu – 632 014, India
T. Gomathi
PG and Research Department of Chemistry, DKM College for Women, Vellore, Tamil Nadu – 632 001, India
S. Pavithra
PG and Research Department of Chemistry, DKM College for Women, Vellore, Tamil Nadu – 632 001, India
P. N. Sudha
PG and Research Department of Chemistry, DKM College for Women, Vellore, Tamil Nadu – 632 001, India

Abstract


The preparation and characterisation of a polymeric composite incorporating graphene, hydroxyapatite, and chitosan as an adsorbent to remove chromium (VI) from wastewater. The FTIR and XRD studies supported the composite's production. Analysis of surface morphology and heat stability involved TGA and SEM studies. A batch adsorption was run to determine the efficacy of the adsorbent by varying contact time, adsorbent dose, and pH. The kinetics of the adsorption process were examined using pseudo-first and second order kinetic models after the equilibrium data had been fitted with the Langmuir and Freundlich isotherms. The findings showed that pseudo second order kinetics was utilised for the adsorption of Cr(VI) onto chitosan-grafted graphene/hydroxyapatite (CS-g-Gr/HA) composite.

Keywords


Adsorption, Chitosan, Chromium, Composite, Graphene, Hydroxyapatite.

References