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Batch Kinetic Studies of Adsorption of Cu(II) Ions from Aqueous Solutions Onto Alginate Nanoparticles/PEG Binary Blend


Affiliations
1 PG and Research Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu – 632 001, India
 

Among the most prevalent natural biopolymers is alginate. The current effort focuses on creating the binary blend of Alg-Nps/PEG. PEG is a great option because of its many distinctive qualities. Blends of polymers mix the characteristics of the separate polymers. FTIR results show intermolecular hydrogen bonding between Alg-Nps/PEG binary blend. Morphological and cross-sectional studies were analyzed using SEM. Various parameters impacting the Cu(II) ion adsorption, including pH, contact time, and adsorbent concentrations, have been examined in a batch adsorption method utilizing an Alg-Nps/PEG binary blend. Pseudo-first order, pseudo-second order, and intra particle Weber-Morris diffusion parameters have been determined. The experimental data fit the pseudo-second order kinetics model quite well when compared to the pseudo first order and intra-particular diffusion models.

Keywords

Adsorption, Alginate, Blend, Kinetics Model.
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  • Batch Kinetic Studies of Adsorption of Cu(II) Ions from Aqueous Solutions Onto Alginate Nanoparticles/PEG Binary Blend

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Authors

M. Saranya
PG and Research Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu – 632 001, India
T. Gomathi
PG and Research Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu – 632 001, India
S. Pavithra
PG and Research Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu – 632 001, India
A. Mubashirunnisa
PG and Research Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu – 632 001, India
P. N. Sudha
PG and Research Department of Chemistry, D.K.M. College for Women, Vellore, Tamil Nadu – 632 001, India

Abstract


Among the most prevalent natural biopolymers is alginate. The current effort focuses on creating the binary blend of Alg-Nps/PEG. PEG is a great option because of its many distinctive qualities. Blends of polymers mix the characteristics of the separate polymers. FTIR results show intermolecular hydrogen bonding between Alg-Nps/PEG binary blend. Morphological and cross-sectional studies were analyzed using SEM. Various parameters impacting the Cu(II) ion adsorption, including pH, contact time, and adsorbent concentrations, have been examined in a batch adsorption method utilizing an Alg-Nps/PEG binary blend. Pseudo-first order, pseudo-second order, and intra particle Weber-Morris diffusion parameters have been determined. The experimental data fit the pseudo-second order kinetics model quite well when compared to the pseudo first order and intra-particular diffusion models.

Keywords


Adsorption, Alginate, Blend, Kinetics Model.

References