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Solvothermal Synthesis and Characterization Studies of Selenium Decorated Reduced Graphene Oxide Supported Cuse2 Nanoparticles as Efficient Electrochemical Catalyst for Oxygen Reduction Reaction


Affiliations
1 Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai 627 002, Tamil Nadu, India Affiliated to Manonmaniam Sundaranar University, Abishekapatti 627 012,, India
 

In the energy conversion system, oxygen reduction reaction (ORR) is one of the most significant reactions. Pt-based catalysts are commonly used in fuel cells; the replacement with low-cost materials like transition metal oxides is much needed for the wide application of fuel cells. In this paper, the effective synthesis of copper selenide nanoparticles with selenium-reduced graphene oxide has been described. To establish the existence of selenium, graphene, and copper in manufactured samples, X-Ray diffraction analysis (XRD) has been used. Additionally, fourier transform infrared analysis (FTIR) has been used to examine the functional groups. The structure and morphology have been studied under the scanning electron microscope. UV has been used to assess the synthetic nanoparticles' optical performance. The Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) methods have been used to analyze their specific surface area and pore size. Cyclic voltammetry has been used to evaluate the produced nanoparticles' electrochemical performance (CV, LSV).

Keywords

BET, Catalysts, Copper, CV, Oxygen reduction reaction.
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  • Yang D, Zhu Q, Chen C, Liu H, Liu Z, Zhao Z & Han B, Nat Commun, 10 (2019) 1.

  • Bhuse V M, Hankare P P, Garadkar K M & Khomane A S, Mate Chem Phys, 80 (2003) 82.

  • Ellis M W, Von Spakovsky M R & Nelson D J, Proceedings IEEE, 89 (2001) 1808.

  • Felseghi R A, Carcadea E, Raboaca M S, Trufin C N & Filote C, Energies, 12 (2019) 4593.

  • Singla M K, Nijhawan P & Oberoi A S, Environ Sci Pollut Res, 28 (2021) 15607.

  • Lee J M, Han H, Jin S, Choi S M, Kim H J, Seo M H & Kim W B, Energy Technol, 7 (2019) 1900312.

  • Zagal J H & Koper M T, Angewandte Chemie International Edition, 55 (2016) 14510.

  • Goswami C, Hazarika K K & Bharali P, Mater Sci Energy Technol, 1 (2018) 117.

  • Qian Y, Khan I A & Zhao D, Small, 13 (2017) 1701143.

  • Brouzgou A, Song S Q & Tsiakaras P, Appl Catal B: Environ, 127 (2012) 371.

  • Chen Z, Higgins D, Yu A, Zhang L & Zhang J, Energy Environ Sci, 4 (2011) 3167.

  • Long N V, Yang Y, Thi C M, Van Minh N, Cao Y & Nogami M, Nano Energy, 2 (2013) 636.

  • Bak S J, Kim S I, Lim S Y, Kim T, Kwon S H & Lee D H, Int J Mol Sci, 22 (2021) 12300.

  • Wang J J & Ryan K M, Cryst Eng Comm, 18 (2016) 3161.

  • do Nascimento J R, D’Oliveira M R, Veiga A G, Chagas C A & Schmal M, ACS Omega, 5 (2020) 25568.

  • Navalon S, Dhakshinamoorthy A, Alvaro M & Garcia H, Coord Chem Rev, 312 (2016) 99.

  • Ratnayake S P, Mantilaka M MM G P G, Sandaruwan C, Dahanayake D, Murugan E, Santhosh SKumar S, Amaratunga G A J & Nalin de Silva K M, Appl Catal A: Gen, 570 (2019) 23.

  • Santhoshkumar S & Murugan E, Appl Surf Sci, 553 (2021) 149544.

  • Murugan E, Govindaraju S & Santhoshkumar S, Electrochimica Acta, 392 (2021) 138973.

  • Ratnayake S P, Sandaruwan C, Mantilaka M MM G P G, De Silva N, Dahanayake D, Wanninayake U K, Bandara W R L N, Santhoshkumar S, Murugan E, Amaratunga G A J & Nalin de Silva K M, J Ind Eng Chem, 95 (2021) 203.

  • Zhou K & Li Y, Angew Chem Int Ed, 51 (2012) 602.

  • Ajith P, Rajkumar A, Muthu M S, Agnes J & Anand P, Nanjing Youdian Daxue Xuebao (Ziran Kexue Ban)/J Nanjing Univ Posts Telecommun (Nat Sci) (2021).

  • Yang C T, Hsiang H I & Tu J H, Adv Powder Technol, 27 (2016) 959.

  • Kim N H, Kuila T & Lee J H, J Mater Chem A, 1 (2013) 1349.

  • Augustin M & Balu T, Int J Nanosci, 16 (2017) 1650035.

  • Agnes J, Selvakumar M S & Anand D P, Mater Today Proc, 5 (2022) 256.

  • Date E H F & Andrews K W, J Phys D: Appl Phys, 2 (1969) 1373.

  • Suriakarthick R, Pandian M S, Ramasamy P, Raji R K, Muralidharan M, Amaljith C K & Sagadevan S, Inorg Chem Commun, 140 (2022) 109491.

  • Dimiduk D M, Uchic M D & Parthasarathy T A, Acta Mater, 53 (2005) 4065.

  • Murugan E, Santhoshkumar S, Govindaraju S & Palanichamy M, Spectrochim Acta Part A: Mol Biomol Spectrosc, 246 (2020) 119036.

  • Murugan E, Santhoshkumar S, Reshna K M & Govindaraju S, J Mater Sci, 54 (2019) 5294.

  • Kumar P & Singh K, Struct Chem, 22 (2011) 103.

  • Dong Y, Peng Q & Li Y, Inorg Chem Commun, 7 (2004) 370.

  • Sangamesha M A, Pushpalatha K & Shekar G L, Indian J Adv Chem Sci, 2 (2014) 223.

  • Muthu M S, Xavier S S J, Ajith P & Anand D P, Mater Today: Proc, 6 (2022)

  • 36 Ajith P, Agnes J, Muthu M S & Selvakumar M S, Mater Today: Proc, 5 (2022) 287.

  • Santhoshkumar S & Murugan E, Dalton Trans, 50 (2021) 17988. 38 Tashiro Y, Taniguchi K & Miyasaka H, Electrochim Acta, 210 (2016) 655.

  • Xu C, Wei X, Ren Z, Wang Y, Xu G, Shen G & Han G, Mater Lett, 63 (2009) 2194.

  • Murugan E, Rubavathy Jaya Priya A, Janaki Raman K, Kalpana K, Akshata C R, Santhosh Kumar S & Govindaraju S, J Nanosci Nanotechnol, 19 (2019) 7596.


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  • Solvothermal Synthesis and Characterization Studies of Selenium Decorated Reduced Graphene Oxide Supported Cuse2 Nanoparticles as Efficient Electrochemical Catalyst for Oxygen Reduction Reaction

Abstract Views: 131  |  PDF Views: 95

Authors

P Ajith
Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai 627 002, Tamil Nadu, India Affiliated to Manonmaniam Sundaranar University, Abishekapatti 627 012,, India
J Agnes
Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai 627 002, Tamil Nadu, India Affiliated to Manonmaniam Sundaranar University, Abishekapatti 627 012,, India
M Sappani Muthu
Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai 627 002, Tamil Nadu, India Affiliated to Manonmaniam Sundaranar University, Abishekapatti 627 012,, India
D Prem Anand
Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai 627 002, Tamil Nadu, India Affiliated to Manonmaniam Sundaranar University, Abishekapatti 627 012,, India

Abstract


In the energy conversion system, oxygen reduction reaction (ORR) is one of the most significant reactions. Pt-based catalysts are commonly used in fuel cells; the replacement with low-cost materials like transition metal oxides is much needed for the wide application of fuel cells. In this paper, the effective synthesis of copper selenide nanoparticles with selenium-reduced graphene oxide has been described. To establish the existence of selenium, graphene, and copper in manufactured samples, X-Ray diffraction analysis (XRD) has been used. Additionally, fourier transform infrared analysis (FTIR) has been used to examine the functional groups. The structure and morphology have been studied under the scanning electron microscope. UV has been used to assess the synthetic nanoparticles' optical performance. The Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) methods have been used to analyze their specific surface area and pore size. Cyclic voltammetry has been used to evaluate the produced nanoparticles' electrochemical performance (CV, LSV).

Keywords


BET, Catalysts, Copper, CV, Oxygen reduction reaction.

References