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Evaluation of Punica granatum Extract as an Environmentally Safe Corrosion Inhibitor for Carbon Steel in a Solution of 1 M Sulfuric Acid


Affiliations
1 PPG protective and marine coatings PMC, Egypt
2 Misr Higher Institute for Engineering and Technology, Mansoura, Egypt
3 Department Chemistry, Faculty of Science, Mansoura University, Mansoura-35516, Egypt
 

In order to create an eco-friendly corrosion inhibitor Punica granatum extract (PG) was employed as the primary component for use in H2SO4 pickling procedures. The inhibition behaviour of C-steel in H2SO4 has been studied using weight-loss tests, polarization curves, electrochemical impedance spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS).The outcomes demonstrate the extract's effective inhibition in 1 M H2SO4. Both an increase in concentration and temperature boosted the effectiveness of the inhibition. With the greater concentration of PG (300 ppm) and the higher applied temperature (45°C), the inhibition effectiveness reached 91.7%. Nevertheless, the inhibitory efficacy increased synergistically with the addition of potassium iodide, increasing from 81.5% to 95.0% at 25°C using the weight-loss technique. Adsorption on the C-steel caused the inhibitory effect, and this adsorption mechanism was compatible with the Temkin isotherm. According to the free energy of adsorption (ΔG0ads = 39.5 kJ/mol.), the PG extract adheres chemically to the surface of the C-steel. The efficient inhibitor Punica granatum (PG) extract may prevent corrosion of C-steel in H2SO4 solution. The extracts from Punica granatum (PG) are a commonly used green inhibitor that may be used to pickle metals.

Keywords

Adsorption, C-Steel, Punica granatum Extract, Sulfuric Acid, Synergistic Effect, Temkin Isotherm.
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  • Chauhan L R & Gunasekaran G G, Corro Sci, 49 (2007) 1143.

  • Lalitha A, Ramesh S & Rajeswari S, Electro chim Acta, 51 (2005) 47.

  • Quraishi M A & Sardar R, Corros, 28 (2002) 103.

  • Sykes J M, Br Corros J, 25 (1990) 175.

  • Elkadi L, Mernari B, Traisnel M, Bentiss F & Lagrenee M, Corros Sci, 42 (2000) 703.

  • Schmitt G, Br Corros J, 19 (1984) 165.

  • Raja P B & Sethuraman M G, Mater Lett, 62 (2008) 113.

  • Tezeghdenti M, Dhouibi L & Etteye N, J Bio Tribo Corros, 1 (2015) 5.

  • Ali A E, Badr G E & Fouda A S, Biointerface Res Appl Chem, 11 (2021) 14007.

  • Fouda A S, Shalabi K & Alsadeag A, Int J Petrochem Sci Eng, 2 (2017) 228.

  • Abdal-nabi S M & Mahdi S M, Int J Mech Eng Educ, 7 (2022) 2247.

  • Chidiebere M A, Ogukwe C E, Oguzie K L, Eneh C N & Oguzie E E, Ind Eng Chem Res, 51 (2012) 668.

  • Sorkhabi H A, Mirzaee S, Rostamikia T & Bagheri R, Int J Corros, 2015 (2015) 1.

  • Sahraoui M, Boulkroune M, Chibani A, Larbah Y & Abdessemed A, J Bio Tribo Corros, 8 (2022) 54.

  • Cheyad M S & Salman T A, J Mater Sci Sur Eng, 5 (2017) 597.

  • Rani P D & Selvaraj S, J Phytol, 2 (2010) 58.

  • Negi P S, Jayaprakasha G K & Jena B S, Food Chem, 80 (2003) 393.

  • Komorsky-Lovrić Š & Novak I, Int J Electrochem Sci, 6 (2011) 4638.

  • Häkkinen S H, Kärenlampi S O, Mykkänen H M & Heinonen I M, Törrönen A R, Food Res Technol, 212 (2000) 75.

  • Chauhan D & Chauhan J S, Pharm Biol, 39 (2001) 155.

  • El-Toumy S A & Rauwald H W, Phytochem, 61 (2002) 971.

  • Heftmann E, Ko S T & Bennett R D, Phytochem, 5 (1966) 1337.

  • Poyrazoğlu E, Gökmen V & Artιk N, J Food Compos Anal, 15 (2002) 567.

  • Dean P, Exley D & Goodwin T, Steroid in plants: Re-estimation of oestrone in pomegranate seeds, (1971).

  • Wahab S, Fiki N, Mostafa S & Hassan A, Bull Fac Pharm Cairo Univ, 36 (1998) 11.

  • Choi D W, Kim J Y, Choi S H, Jung H S, Kim H J, Cho S Y & Chang S Y, Food Chem, 96 (2006) 562.

  • Brune M, Rossander L & Hallberg L, Eur J Clin Nutr, 43 (1989) 547.

  • Geisser P, Arzneim Forsch, 40 (1990) 754.

  • ASTM, AST G 31-72, Standard Recommended Practice for the Laboratory Immersion Corrosion Testing of Metals, American Society for Testing and Materials, Philadelphia, PA, USA, (1990).

  • Lecante A, Robert F, Blandinières P A & Roos C, Curr Appl Phys, 11 (2011) 714.

  • Barsoukov E & Macdonald J R, Impedance Spectroscopy, Theory, Experiment and Applications, 2nd edn Wiley Inter-science publications, New York, (2005).

  • Emori W, Zhang R H, Okafor P C, Zheng X W, He T, Wei K, Lin X Z & Cheng C R, Colloids Surf A Physicochem Eng Asp, 290 (2020) 124534.

  • Akinbulumo O A, Odejobi O J & Odekanle E L, Results Mater, 5 (2020) 100074.

  • Fouda A S, Shalabi K, Nofal A M & El-Zekred M A, Chem Sci Trans, 7 (2018) 101.

  • Toghan Arafat, Gadow H S, Dardeer H M & Elabbasy H M, J Mol Liq, 325 (2021) 115136.

  • Elabbasy H M & Gadow H S, J Mol Liq, 321 (2021) 114918

  • Gerengi H, Ugras H I, Solomon M M, Umoren S A, Kurtay M & Atar N, J Adhes Sci Technol, 30 (2016) 2383.

  • Usman B J, Umoren S A & Gasem Z M, J Mol Liq, 237 (2017) 146.

  • Zhang Z, Tian N, Zhang W, Huang X, Ruan L & Wu L, Corros Sci, 111 (2016) 675.

  • Pavithra M K, Venkatesha T V, Vathsala K & Nayana K O, Corros Sci, 52 (2010) 3811.

  • Djellab M, Bentrah H, Chala A & Taoui H, Mater Corros, 70 (2019) 149.

  • Yan Y, Li W, Cai L & Hou B, Electrochim Acta, 53 (2008) 5953.

  • Mazkour A, El Hajjaji S, Labjar N, Lotfi E & El Mahi M, Int J Corros, 2021 (2021) 6666811.

  • Şafak S, Duran B, Yurt A & Türkoğlu G, Corros Sci, 54 (2012) 251.

  • Fouda A S, Megahed H E, Fouad N & Elbahrawi N M, J Bio Tribo Corros, 2 (2016) 1.

  • Al-Amiery A A, Kadhum A H, Alobaidy A H M, Mohamad A B & Hoon P S, Materials (Basel), 7 (2014) 662.

  • Elabbasy H M & Fouda A S, Green Chem Lett Rev, 12 (2019) 332.

  • Heakal F E, Deyab M A, Osman M M, Nessim M I & Elkholy A E, RSC Adv, 7 (2017) 47335.

  • Ajmal M, Mideen A S & Quraishi M A, Corros Sci, 36 (1994) 79.

  • Bentiss F, Lebrini M & Lagrenee M, Corros Sci, 47 (2005) 2915.

  • Silverman D C & Carrico J E, Corros, 44 (1988) 280.

  • Macdonald D D & McKubre M C, Impedance measurements in electrochemical systems, Mod Asp Electrochem, Springer, Boston, MA. (1982) 61.

  • Mansfeld F, Corros, 37 (1981) 301.

  • Solmaz R, Kardas G, Ulha M C, Yazıcı B & Erbil M, Electrochim Acta, 53 (2008) 5941.

  • Fouda A S, Mohamed O A & Elabbasy H M, J Bio Tribo Corros, 7 (2021) 135.

  • Khadom A A, Abd N A & Ahmed N A, S Afr J Chem Eng, 25 (2018) 13.

  • Hashim N Z N, Anouar E, Kassim K, Zaki H M, Alharthi A I & Embong Z, Appl Surf Sci, 476 (2019) 861.

  • Meneguzzi A, Ferreira C, Pham M C, Delamar M & Lacaze P C, Electrochim Acta, 44 (1999) 2149.

  • Lebrini M, Lagrene´e M, Traisnel M, Gengembre L, Vezin H & Bentiss F, Appl Surf Sci, 253 (2007) 9267.

  • Eid A M, Shaaban S & Shalabi K, J Mol Liq, 298 (2020) 111980.

  • Moulder J F, Stickle W F, Sobol P E & Bomben K D, Handbook of X-ray Photoelectron Spectroscopy, published by Perkin-Elmer Corporation Physical Electronics Division 6509 Flying Cloud Drive Eden Prairie, MinnCSOla 55344 United States of America, (1992).

  • Wang X, Yang W, Li F, Xue Y, Liu R & Hao Y, Ind Eng Chem Res, 52 (2013) 17140.

  • Fouda A S, NazeerA A& El behairy W T, J Bio Tribo Corros, 4(2018) 7.

  • Boumhara K, Tabyaoui M, Jama C & Bentiss F, J Ind Eng Chem, 29 (2015) 146.

  • Singh P, Srivastava V & Quraishi M A, J Mol Liq, 216 (2016) 164.


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  • Evaluation of Punica granatum Extract as an Environmentally Safe Corrosion Inhibitor for Carbon Steel in a Solution of 1 M Sulfuric Acid

Abstract Views: 70  |  PDF Views: 59

Authors

Mohamed E Elnagar
PPG protective and marine coatings PMC, Egypt
Hanaa M Elabbasy
Misr Higher Institute for Engineering and Technology, Mansoura, Egypt
Abd El-Aziz S Fouda
Department Chemistry, Faculty of Science, Mansoura University, Mansoura-35516, Egypt

Abstract


In order to create an eco-friendly corrosion inhibitor Punica granatum extract (PG) was employed as the primary component for use in H2SO4 pickling procedures. The inhibition behaviour of C-steel in H2SO4 has been studied using weight-loss tests, polarization curves, electrochemical impedance spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS).The outcomes demonstrate the extract's effective inhibition in 1 M H2SO4. Both an increase in concentration and temperature boosted the effectiveness of the inhibition. With the greater concentration of PG (300 ppm) and the higher applied temperature (45°C), the inhibition effectiveness reached 91.7%. Nevertheless, the inhibitory efficacy increased synergistically with the addition of potassium iodide, increasing from 81.5% to 95.0% at 25°C using the weight-loss technique. Adsorption on the C-steel caused the inhibitory effect, and this adsorption mechanism was compatible with the Temkin isotherm. According to the free energy of adsorption (ΔG0ads = 39.5 kJ/mol.), the PG extract adheres chemically to the surface of the C-steel. The efficient inhibitor Punica granatum (PG) extract may prevent corrosion of C-steel in H2SO4 solution. The extracts from Punica granatum (PG) are a commonly used green inhibitor that may be used to pickle metals.

Keywords


Adsorption, C-Steel, Punica granatum Extract, Sulfuric Acid, Synergistic Effect, Temkin Isotherm.

References