Open Access Open Access  Restricted Access Subscription Access

Removal of Lead (II) Ion from Industrial Wastewater by Activated Carbon Prepared from Vitex negundo Using Batch Adsorption Studies


Affiliations
1 Department of Chemistry, Dhanalakshmi Srinivasan Engineering College (Autonomous), Perambalur, Tamil Nadu, India
2 Department of Chemistry, Dhanalakshmi Srinivasan College of Engineering and Technology, Mamallapuram, Chennai, Tamil Nadu, India
3 Department of Chemistry, IFET College of Engineering (Autonomous?), Villupuram, Tamil Nadu, India
4 PG and Research Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirapalli, Tamil Nadu, India
 

The Potential of chemically carbonized Vitex negundo stem (VNC) for the effective removal of lead (II) ion from aqueous solutions has been investigated in batch experiments. The activated carbon prepared from VNC has been modified using the activating agent H2SO4. Lead adsorption significantly depends on the initial concentration of lead (II), pH, adsorbent dosage, particle size, and the effect of temperature. FT-IR used to characterize the functional groups and the powder XRD data elaborated on the active sites predicted in VNC-1. The main structures of activated carbons are amorphous, as expected and predicted. The results indicate that the carbon prepared from VNC-1 activated could be used to effectively adsorb lead (II) ion from aqueous solutions. Further, the optimum conditions for adsorption studies are calculated, and it is concluded that the activated carbon exhibits a good adsorption potential for lead ions.

Keywords

Adsorption Batch Studies, FT-IR, Lead (II) Ions, SEM, XRD.
User
Notifications
Font Size

  • Li Y H, Wang S, Wei J, Zhang X, Xu C & Luan Z, Chem Phys Lett, 357 (2002) 263.
  • Zhang K, Cheung W & Valix R M, Chemosphere, 60 (2005) 1129.
  • Vukovic G D, Marinkovic A D, Skapin S D, Ristic M D, Aleksic R & Peric-Grujic A A,, J Chem Eng, 173 (2011) 855.
  • Vinoth M & Natarajan B, Rasian J Chem, 14 (2021) 768.
  • Sun Y, Yue Q, Gao B, Gao Y, Xu X & Li, J Taiwan Inst Chem Eng, 45 (2014) 681.
  • Yang S, Li J, Shao D, Hu J & Wang X, J Hazard Mater, 166 (2009) 109.
  • Zhang S, Zhang Y, Liu J, Xu Q, Xiao H, Wang X, Xu H & Zhou J, J Chem Eng, 226 (2013) 30.
  • Cheng C, Wang J, Yang X, Li A & Philippe C, J Hazard Mater, 264 (2014) 332.
  • Wang X S, Zhu L & Lu H J, Desalination, 276 (2011) 154.
  • Qaiser S, Saleem A R & Ahmed M, Mater Environ Biotechnol, 10 (2007) 1.
  • Gupta V & Ali K, J Colloid Interface Sci, 271 (2004) 321.
  • IARC Working Group on the Evaluation of Carcinogenic Risks to Humans. Inorganic and organic lead compounds, IARC MonogrEvalCarcinog Risks Hum, 87 (2006).
  • Vinoth M & Natarajan B, Int J Res Pharm Sci, 12 (2021) 234.
  • Vinoth M, Natarajan B & Shanmuga S C, Indian J Chem Technol, 28 (2021) 188.
  • Demirbas A, J Hazard Mater, 157 (2008) 220.
  • Guo J, Xu W S, Chen Y L & Lua A C, J Colloid Interface Sci, 281 (2005) 285.
  • Arunkumar A, Chandrasekaran T & Riaz A K, Int J Inno Technol Explor Eng, 4 (2014) 1.
  • Chen X C, Wang Y P, Lin Q, Shi J Y, Wu W X & Chen Y X, Colloids Surf B, 46 (2005) 101.
  • Al-Qunaibit M H, Mekhemer W K & Zaghloul A A, J Colloid Int Sci, 283 (2005) 316.
  • Mourao P A M, Carrott P J M & Carrott M L R, Carbon, 44 (2006) 2422.
  • Hameed B H & Rahman A A, J Hazard Mater, 160 (2008) 576.
  • Kumar A, Kumar S, Kumar S & Gupta D V, J Hazard Mater, 147 (2007) 155.
  • Mukosha L, Onyango M S, Ochieng A & Kasaini H, Int J Chem Mater Sci Eng, 7 (2013) 7.
  • Manzoor Q, Nadeem R, Iqbal M, Saeed R & Ansari T M, Bioresour Technol, 132 (2013) 446.
  • Saka C, Sahin O, Demir H & Kahyaoglu M, Sep Sci Technol, 46 (2011) 5071.
  • Feng N & Guo X, Trans Nonferrous Met Soc China, 22 (2012) 1224.
  • Feng N, Guo X, Liang S, Zhu Y & Liu J, J Hazard Mater, 185 (2011) 49.
  • Jayaram K, Murthy I Y L N, Lalhruaitluanga H & Prasad M N V, Colloid Surf, 71 (2009) 248.
  • Aziz H M A, Colloids Surf A, 264 (2005) 1.
  • Momcilovic M, Purenovic M, Boji´c A, Zarubica A & Randelovid M, Desalination, 276 (2011) 53.
  • Mittal A, Mittal J, Malviya A, Kaur D & Gupta V K, J Colloid Int Sci, 342 (2010) 518.
  • Depci T, Kul A R, Önal Y, Chem Eng, 200 (2012) 224.
  • Dubey A & Shiwani S, Int J Environ Sci Technol, 9 (2012) 15.
  • Hu X, Zhao M, Song G & Huang H, Environ Technol, 32 (2011) 739.
  • Liu C, Ngo H H & Guo W S, Appl Biochem Biotechnol, 167 (2012) 1699.
  • Njoku V O, Ayuk A A, Ejike E E, Oguzie E E, Duru C E & Bello O S, Aust J Basic Appl Sci, 5 (2011) 101.
  • Vinoth M & Natarajan B, Rasian J Chem, 14 (2021) 166.
  • Taha G M, Arifien A E & El-Nahas S, J Solid Waste Technol Manag, 37 (2011) 128.
  • Arunkumar A, Chandrasekaran T & Riaz A K, J Pharm Res, 5 (2016) 1206.

Abstract Views: 77

PDF Views: 71




  • Removal of Lead (II) Ion from Industrial Wastewater by Activated Carbon Prepared from Vitex negundo Using Batch Adsorption Studies

Abstract Views: 77  |  PDF Views: 71

Authors

A Arunkumar
Department of Chemistry, Dhanalakshmi Srinivasan Engineering College (Autonomous), Perambalur, Tamil Nadu, India
T. Chandrasekaran
Department of Chemistry, Dhanalakshmi Srinivasan College of Engineering and Technology, Mamallapuram, Chennai, Tamil Nadu, India
M. Vinoth
Department of Chemistry, IFET College of Engineering (Autonomous?), Villupuram, Tamil Nadu, India
K. Riaz Ahamed
PG and Research Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirapalli, Tamil Nadu, India

Abstract


The Potential of chemically carbonized Vitex negundo stem (VNC) for the effective removal of lead (II) ion from aqueous solutions has been investigated in batch experiments. The activated carbon prepared from VNC has been modified using the activating agent H2SO4. Lead adsorption significantly depends on the initial concentration of lead (II), pH, adsorbent dosage, particle size, and the effect of temperature. FT-IR used to characterize the functional groups and the powder XRD data elaborated on the active sites predicted in VNC-1. The main structures of activated carbons are amorphous, as expected and predicted. The results indicate that the carbon prepared from VNC-1 activated could be used to effectively adsorb lead (II) ion from aqueous solutions. Further, the optimum conditions for adsorption studies are calculated, and it is concluded that the activated carbon exhibits a good adsorption potential for lead ions.

Keywords


Adsorption Batch Studies, FT-IR, Lead (II) Ions, SEM, XRD.

References