Open Access Open Access  Restricted Access Subscription Access

Removal of Chlorpyrifos, Malathion, Dichlorvos and Profenofos by Nanocomposite Containing AgNP


Affiliations
1 Department of Biotechnology, University Institute of Engineering and Technology, Kurukshetra University, Kurukshetra 136 118, India
2 Agrochemicals Residues Testing Laboratory, Department of Agronomy, CCS Haryana Agricultural University, Hisar 125 004, India
 

Pesticides are frequently used in agriculture, which contaminates both surface and ground water. Surface adsorption, photocatalysis, membrane separation and biodegradation are methods to remove the pesticides. These methods are expensive and time consuming. In this study silver nanoparticles were synthesized by using endophytic bacterial strain VXB8. A nanocomposite (CAB with 20 mg silver nanoparticles) has been designed for the removal of organophosphate compounds from aqueous solution. Individually after passing 100 µg/mL of chlorpyrifos, malathion, dichlorvos and profenofos solution through nanocomposite, the removal efficiency of pesticides has been analyzed by UV/Visible spectroscopy and GC-MS analysis. The removal efficiency of chlorpyrifos, malathion, dichlorvos and profenofos is 88.49, 75.79, 78.2 and 64.1 % respectively. The proposed method is simple, rapid, environmentally friendly with good pesticides removal efficiency.

Keywords

Adsorption, GCMS, Nanocomposite, Pesticides, Silver Nanoparticles.
User
Notifications
Font Size

  • Yousefi S M, Shemirani F & Ghorbanian S A, Talanta, 168 (2017) 73.
  • Jayaraj R, Megha P & Sreedev P, Interdiscip Toxicol, 9 (2016) 90.
  • Syafrudin M, Kristanti R A, Yuniarto A, Hadibarata T, Rhee J, Al-Onazi W A & Al-Mohaimeed A.M, Int J Environl Res Public Health, 18 (2021) 468.
  • Manimegalai G, Shanthakumar S & Sharma C, Int Nano Lett, 4 (2014) 1.
  • Taghizade F T, Mehrdadi N, Baghdadi M & Nabi B G R, Int J Nanosci Nanotechnol, 14 (2018) 43.
  • Zhang Z & Kong J, J Hazard Mater, 193 (2011) 325.
  • Kasher R, Bull Isr Chem Soc, 24 (2009) 10.
  • Balamurugan R, Sundarrajan S & Ramakrishna S, Membranes, 1 (2011) 232.
  • Basri H, Ismail A F & Aziz M, Desalination, 273 (2011) 72.
  • Figueiredo A S, Sánchez‐Loredo M G, Maurício A, Pereira M F, Minhalma M & de Pinho M N, J Appl Polym Sci, 132 (2015) 1.
  • Saifuddin N, Nian C Y, Zhan L W & Ning K X, Asian J Biochem, 6 (2011) 142.
  • Rahmanifar B & Moradi D S, Clean Technol Environ Policy, 16 (2014) 1781.
  • Simeonidis K, Mourdikoudis S, Kaprara E, Mitrakas M & Polavarapu L, Water Res Technol, 2 (2016) 43.
  • Bhatia D, Mittal A & Malik D K, Biotech, 6 (2016) 1.
  • Gurunathan S, Kalishwaralal K, Vaidyanathan R, Venkataraman D, Pandian S R K, Muniyandi J & Eom S H, Colloids Surfaces B: Biointerfaces, 74 (2009) 328.
  • Beisl S, Monteiro S, Santos R, Figueiredo A S, Sánchez-Loredo M G, Lemos M A & De P M N, Water Res, 149 (2019) 225.
  • Chen Y, Xiang Z, Wang D, Kang J & Qi H, RSC Adv, 10 (2020) 23936.
  • Gissawong N, Mukdasai S, Boonchiangma S Sansuk S & Srijaranai S, Chemosphere, 260 (2020) 127590.
  • Suo F, Xie G, Zhang J, Li J, Li C, Liu X & Ji M A, RDC Adv, 8 (2018) 7735.
  • Duhan A, Kumari B & Duhan S, Bullet Environ Contam Toxicol, 94 (2015) 260.
  • Nasiri A, Amirahmadi M, Mousavi Z, Shoeibi S, Khajeamiri A & Kobarfard F, Iranian J Pharm Res, 15 (2016) 809.
  • Sarangadharan S & Nallusamy S, Int J Pharma Med Biol Sci, 4 (2015) 236.
  • Li Z, Wang Y, Ni Y & Kokot S, Sens Actuat B: Chem, 193 (2014) 205.
  • Musarurwa H, Chimuka L & Tavengwa N T, Food Addit Contam: Part A, 37 (2020) 2093.
  • Jebel F S & Almasi H, Carbohydr Polym, 149 (2016) 8.
  • Cacciotti I, Fortunati E, Puglia D, Kenny J M & Nanni F, Carbohydr Polym, 103 (2014) 22.
  • Das S K, Khan M M R, Guha A K, Das A R & Mandal A B, Bioresour Technol, 124 (2012) 495.
  • Shabbir M, Singh M, Maiti S, Kumar S & Saha S K, Bioresour Technol, 263 (2018) 280.
  • Tyagi N, Thangadurai P & Suresh S, Int J Environ Sci Technol, 17 (2020) 1713.
  • Koushik D, Gupta S S, Maliyekkal S M & Pradeep T, J Hazard Mater, 308 (2016) 192.
  • Sahithya K, Das D & Das N, J Mol Liq, 211 (2015) 821.

Abstract Views: 72

PDF Views: 67




  • Removal of Chlorpyrifos, Malathion, Dichlorvos and Profenofos by Nanocomposite Containing AgNP

Abstract Views: 72  |  PDF Views: 67

Authors

Vivek Singh
Department of Biotechnology, University Institute of Engineering and Technology, Kurukshetra University, Kurukshetra 136 118, India
Anil Duhan
Agrochemicals Residues Testing Laboratory, Department of Agronomy, CCS Haryana Agricultural University, Hisar 125 004, India
Deepak Kumar Malik
Department of Biotechnology, University Institute of Engineering and Technology, Kurukshetra University, Kurukshetra 136 118, India

Abstract


Pesticides are frequently used in agriculture, which contaminates both surface and ground water. Surface adsorption, photocatalysis, membrane separation and biodegradation are methods to remove the pesticides. These methods are expensive and time consuming. In this study silver nanoparticles were synthesized by using endophytic bacterial strain VXB8. A nanocomposite (CAB with 20 mg silver nanoparticles) has been designed for the removal of organophosphate compounds from aqueous solution. Individually after passing 100 µg/mL of chlorpyrifos, malathion, dichlorvos and profenofos solution through nanocomposite, the removal efficiency of pesticides has been analyzed by UV/Visible spectroscopy and GC-MS analysis. The removal efficiency of chlorpyrifos, malathion, dichlorvos and profenofos is 88.49, 75.79, 78.2 and 64.1 % respectively. The proposed method is simple, rapid, environmentally friendly with good pesticides removal efficiency.

Keywords


Adsorption, GCMS, Nanocomposite, Pesticides, Silver Nanoparticles.

References