Indian Journal of Chemical Technology

Open Access Open Access  Restricted Access Subscription Access

Isotherm Studies on Removal of Lead(II) Ions from Wastewater by Magnetic Carbon Synthesised from Euphorbia hirta Leaf Extract


Affiliations
1 Departent of Chemistry, Vivekanandha College of Arts and Sciences for Women, Elayampalayam, Tiruchengode-637 205, Tamil Nadu, India
2 Departent of Chemistry, Vivekanandha College of Technology for Women, Elayampalayam, Tiruchengode-637 205, Tamil Nadu, India
 

In this article a magnetic carbon (MEHLC) has been synthesised from Euphorbia hirta leaf (EHL) extract to investigate the adsorption capacity of lead(II) ions from aqueous solutions and industrial wastewater. The prepared magnetic carbon (MEHLC) is compared with raw material (EHL) under the batch adsorption process such as contact time, pH, adsorbent dose and temperature. The adsorbents are characterized by FT-IR, SEM and EDX studies. The maximum removal is obtained at 300 K and the Langmuir isotherm of MEHLC and EHL is found to be with applicable qm value of 385.86 and 21.96 mg g-1, respectively. Various thermodynamic parameters, including the standard Gibbs free energy (∆G°), standard enthalpy (∆H°) and standard entropy (∆S°), are evaluated. The MEHLC and EHL are tested with lead(II) plating wastewater through a batch mode process over five cycles; MEHLC showed better results than EHL.

Keywords

Removal of Lead(II), Euphorbia hirta Leaf, Isotherm, Kinetic Parameters.
User
Notifications
Font Size

  • Unlu N & Ersoz M, J Hazard Mater, 136 (2006) 272.

  • Yurtsever M & Sengil I A, J Hazard Mater, 163 (2009) 58.

  • Jamiu Z A, Saleh T A & Ali S A J R A, RSC Adv, 5 (2015) 42222.

  • Afridi H I, Kazi T G, Kazi G H, Jamali M K & Shar G Q, Biol Trace Elem Res, 113 (2006) 19.

  • Kazi T G, Jalbani N, Kazi N, Jamali M K, Arain M B, Afridi H I, Kandhro A & Pirzado Z, Ren Fail, 30 (2008) 737.

  • Doyurum S & Çelik A, J Hazard Mater, 138 (2006) 22.

  • Gupta S & Babu B V, Chem Eng J, 150 (2009) 352.

  • Salah T A, Mohammad A M, Hassan M A & El-Anadouli B E, J Taiwan Inst Chem Eng, 45 (2014) 1571.

  • Sharma N & Nandi B K, J Mater Environ Sci, 4 (2013) 1052.

  • Kataria N & Garg V K, Chemosph, 208 (2018) 818.

  • Gupta V K & Nayak A, Chem Eng J, 180 (2012) 81.

  • Ngueagni P T, Kumar P S, Woumfo E D, Abilarasu A, Joshiba G J, Carolin C F, Prasannamedha G, Fotsing P N & Siewe M, Chemosph, 272 (2021) 129806.

  • Peighambardoust S J, Foroutan R, Peighambardoust S H, Khatooni H & Ramavandi B, Chemosph, 282 (2021) 131088.

  • Abbaszadeh S, Nodeh H R, Alwi S R W & Zeitschrift A D, Pure Appl Chem, 90 (2018) 79.

  • Jiang R, Tian J, Zheng H, Qi J, Sun S & Li X, J Environ Manage, 155 (2015) 24.

  • Kamal K H, Attia M S, Ammar N S & Abou-Taleb E M, Inorg Chem Commun, 130 (2021) 108742.

  • Sharma R, Sarswat A, Pittman C U & Mohan D, RSC Adv, 7 (2017) 8606.

  • Ho Y S, Bioresour Technol, 96 (2005) 1292.

  • Freundlich H M F, J Phys Chem, 57 (1906) 385.

  • Langmuir I, J Am Chem Soc, 40 (1918) 1361.

  • Dubinin M M & Radushkevich L V, Chem Zent, 1 (1947) 875.

  • Kundu S & Gupta A K, Chem Engg J, 122 (2006) 93.

  • Helfferich F, McGraw-Hill Book Co New York (1962).

  • Chen H, Dai G, Zhao J, Zhong A, Wu J & Yan H, J Hazard Mater, 177 (2010) 228.

  • Jin X, Liu R, Wang H, Han L, Qiu M & Hu B, Environ Sci Pollut Res, 29 (2022) 1.

  • Devasahayam A, Ramanaujam RA & Ramasamy S, Chiang Mai J Sci, 47 (2020) 554.

  • Ismail M S, Yahya M D, Auta M & Obayomi K S, Heliyon, 8 (2022) e09516.

  • Hossain N, Nizamuddin S & Shah K, J Water Proc Eng, 46 (2022) 102620.

  • Adeyemi A F & Olasunkanmi L O, J Dispers Sci Technol, 44 (10) (2022) 1900.

  • Eze S I, Abugu H O, Odewole O A, Ukwueze N N & Alum L O, Sci Afr, 15 (2022) e01123.

  • Ngabura M, Hussain S A, Ghani W A W A K, Jami M S & Tan Y P, J Chem Technol Biotech, 94 (2019) 1384.

  • Srisuwan W, Jubsilp C & Srisorrachatr S, Chem Eng Trans, 70 (2018) 241.

  • Okeola F O, Odebunmi E O, Nwosu F O, Abu T O, Mohammed A A & Samuel A O, Niger J Pure Appl Sci, 30 (2017) 2955.

  • Imamoglu M, Sahin H, Aydin S, Tosunoglu F, Yilmaz H & Yidiz S Z, Desal Water Treat, 57 (2016) 4587.

  • Aboli E, Jafari D & Esmaeili H, Carbon Lett, 30 (2020) 683. 36 Patel H, Sci Rep, 10 (2020) 16895.

  • Van T T, Quynh B T P, Nguyen T D, Ho V T T & Bach L G, Surf Interfaces, 6 (2017) 209.

  • Ahmad A, Khatoon A, Mohd-Setapar S H, Kumar R & Rafatullah M, Desal Water Treat, 57 (2016) 6432.

  • Dhahri R, Yilmaz M, Mechi L, Alsukaibi A K D, Alimi F, Salem R & Moussaoui Y, Sustainability, 14 (2022) 3245.

  • Imran, M, Anwar, K, Akram M, Shah GM, Ahmad I, Shah N S, UI Haq Khan Z, Rashid M I, Akhtar M N, Ahmad S, Nawaz M & Schotting R J, Inter J Phytoremediation, 21(2019) 777.


Abstract Views: 92

PDF Views: 41




  • Isotherm Studies on Removal of Lead(II) Ions from Wastewater by Magnetic Carbon Synthesised from Euphorbia hirta Leaf Extract

Abstract Views: 92  |  PDF Views: 41

Authors

Ramasamy Sudha
Departent of Chemistry, Vivekanandha College of Arts and Sciences for Women, Elayampalayam, Tiruchengode-637 205, Tamil Nadu, India
Kumarappan Latha
Departent of Chemistry, Vivekanandha College of Technology for Women, Elayampalayam, Tiruchengode-637 205, Tamil Nadu, India
Rajendran Jayalakshmi
Departent of Chemistry, Vivekanandha College of Arts and Sciences for Women, Elayampalayam, Tiruchengode-637 205, Tamil Nadu, India

Abstract


In this article a magnetic carbon (MEHLC) has been synthesised from Euphorbia hirta leaf (EHL) extract to investigate the adsorption capacity of lead(II) ions from aqueous solutions and industrial wastewater. The prepared magnetic carbon (MEHLC) is compared with raw material (EHL) under the batch adsorption process such as contact time, pH, adsorbent dose and temperature. The adsorbents are characterized by FT-IR, SEM and EDX studies. The maximum removal is obtained at 300 K and the Langmuir isotherm of MEHLC and EHL is found to be with applicable qm value of 385.86 and 21.96 mg g-1, respectively. Various thermodynamic parameters, including the standard Gibbs free energy (∆G°), standard enthalpy (∆H°) and standard entropy (∆S°), are evaluated. The MEHLC and EHL are tested with lead(II) plating wastewater through a batch mode process over five cycles; MEHLC showed better results than EHL.

Keywords


Removal of Lead(II), Euphorbia hirta Leaf, Isotherm, Kinetic Parameters.

References