Indian Journal of Pure and Applied Physics

Open Access Open Access  Restricted Access Subscription Access

Utilizing Reduced Graphene Oxide-Iron Nanoparticles Composite to Enhance and Accelerate the Removal of Methyl Blue Organic Dye in Wastewater


Affiliations
1 Department of Electronics, Midnapore College (Autonomous), Midnapore 721 101, India
2 Department of Physics, Midnapore College (Autonomous), Midnapore 721 101, India
3 R&D and Innovation, HPCL-Mittal Energy Ltd, Bhatinda (Punjab) 151 301, India
4 Department of Chemistry, Midnapore College (Autonomous), Midnapore 721 101, India
5 Department of Chemistry, IIT Guwahati, Assam 781 039, India
6 Department of Electronics, Vidyasagar University, Midnapore 721 102, India
 

In this work, a nano-composite is used to remove dye from wastewater of different industries. For this purpose, the synthesis of a magnetic 1:1 composite made of iron nanoparticles (NPs) using reduced graphene oxide is a novel technique and tested for Methyl Blue (MB) dye adsorption from aqueous solution. In this study Fe nanoparticles in reduced Graphene composite (FGOC) has been prepared using Graphene Oxide (GO). X-ray diffraction, FTIR spectroscopy and Raman spectroscopy, are used to identify the structures. Many methods have been developed for MB removal in wastewater. One of the most popular methods is adsorption because it is simple and high-efficiency, and the adsorbent is crucial. It reached a maximum MB adsorption at pH 7. The kinetic study indicated that the adsorption of MB process was fitted well to the quasi-first-order and quasi-second-order kinetic models. The isotherm study revealed that the MB adsorption process obeyed the Langmuir and Freundlich adsorption Isotherms models. The GO adding content and absorption conditions on the methyl blue removal efficiencies were investigated. This adsorbent is easily recovered by an external magnetic field from the treated wastewater and has high reusability.

Keywords

Nanoparticle, Graphene Oxide, Dye Removal, Kinetics of Adsorption, Adsorption Isotherm.
User
Notifications
Font Size

  • Ramesha G K, Kumara A V, Muralidhara H B & J Colloid Interface Sci, 361 (2011) 270.

  • Yang S T, Chen S, Chang Y, Cao A, Liu Y & Wang H, J Colloid Interface Sci, 359 (2011) 24.

  • Zhang W, Zhou C, Zhou W, et al., Bull Environ Contam Toxicol, 87 (2011) 86.

  • Liu F, Chung S, Oh G & Seo T S, ACS Appl Mater Interfaces, 4 (2011) 922.

  • Liu T, Li Y, Du Q, Sun J, Jiao Y, Yang G, Xia Y, Zhang W, Wang K, Zhu H & Wu D, Biointerfaces, 90 (2012) 197.

  • Li Y, Du Q, Liu T, Peng X, Wang J, Sun J, Wang Y, Wu S, Wang Z, Xia Y & Xia L, Chem Eng Res Des, 91 (2013) 361.

  • Yang X, Li Y, Yanhui, Du Q, Wang X, Hu S, Chen L, Wang Z , Xia Y & Xia L, J Nanosci Nanotechnol, 16 (2016) 1775.

  • Heidarizad M & Şengör S S, J Mol Liq, 224(A) (2016) 607.

  • Akbar F, Kolahdouz M, Larimian S, Radfar B & Radamson H H, J Mater Sci: Mater Electron, 26 (2015) 4347.

  • Cao J, Liu Q, Du J, Yang L, Wei M, Gao M & Yang J, J Mater Sci: Mater Electron, 28 (2017) 2267.

  • Peng Q Q, Liu Y G, Zeng G M, Xu W H, Yang C P & Zhang J J, J Hazard Mater, 177 (2010) 676.

  • Huang T, Dai J, Yang J H, Zhang N, Wang Y & Zhou Z W, Diam Relat Mater, 86 (2018) 117.

  • Jaleh B, Khalilipour A, Habibi S, Niyaifar M & Nasrollahzadeh M, J Mater Sci: Mater Electron, 28 (2017) 4974.

  • Ranjith R, Ravikumar S, Pandiyan V, Rajaji U, Abualnaja K M, AlMasoud A T S & Ouladsmne M, J Mater Sci: Mater Electron, 33 (2022) 9438.

  • Huong P T L, Son T V, Pham V N, Tam L T & Le A T, J Nanosci Nanotechnol, 18 (2018) 5591.

  • Liu M C, Wen T, Chen C L, Hu J, Li J & Wang X K, Dalton Trans, 42 (2013) 14710.

  • Jinendra U, Bilehal D, Nagabhushana B M, Kumara K S J & Kollur S P, Heliyon, 7 (2021) 6070.

  • Guo J, Wang R, Tjiu W W, Pan J & Liu T, J Hazard Mater, 63 (2012) 225.

  • Pradhan S S, Konwar K, Ghosh T N, Mondal B, Sarkar S K & Deb P, Colloid Interface Sci Commun, 39 (2020) 100319.

  • Zhou C, Zhang W, Wang H, Li H, Zhou J, Wang S, Liu J, Luo J, Zou B & Zhou J, Arab J Sci Eng, 39 (2014) 6679.

  • Huong P T L, Huyen N T, Giang C D, Tu N, Phan V N, Quy N V, Huy T Q, Hue D T M, Chinh H D & Le A T, J Nanosci Nanotechnol, 16 (2016) 9544.

  • Chong S, Zhang G, Tian H & Zhao H, J Environ Sci, 44 (2016) 148.

  • El-Shafai N M, El-Khouly M E, El-Kemary M, Ramadan M S & Masoud M S, RSC Adv, 8 (2018) 13323.

  • Hummers W S & Offeman R E, J Am Chem Soc, 80 (1958) 1339.

  • Ghosh T N, Pradhan S S, Sarkar S K & Bhunia A K, J Mater Sci: Mater Electron, 32 (2021) 19157.

  • Bahrami A, Kazeminezhad I & Abdi Y, 125 (2019) 125.

  • Zhang J, Yang H, Shen G, Cheng P, Zhang J & Guo S, Chem Commun, 46 (2010) 1112.

  • Kumar S, Chinnathambi S, Scanlon L G & Munichandraiah N, Phys Chem Chem Phys, 16 (2014) 22830.

  • Zhu X, Zhu Y, Murali S, Stoller M D & Ruoff R S, ACS Nanomater, 5 (2011) 3333.

  • Zhang G K, Gao Y Y, Zhang Y L & Guo Y D, Environ Sci Technol, 44 (2010) 6384.

  • Muzyka R, Drewniak S, Pustelny T, Gryglewicz G & Sme˛dowski Ł, 11th Conf Integr Opt: Sens, Sens Structu Meth, 100340C (2016).

  • Fang M, Wang K, Lu H, Yang Y & Nutt S, J Mater Chem, 20 (2010) 1982.

  • Wang Y Y, Ni Z H, Yu T, Shen Z X & Wang H M, J Phys Chem C, 112 (2008) 10637.

  • Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y, Wu Y, Nguyen S T & Ruoff R S, Carbon, 45 (2007) 1558.

  • Xing M & Wang J, J Colloid Interf Sci, 474 (2016) 119.

  • El-Shafai N M, El-Khouly M E, El-Kemary M, Ramadana M S & Masoud M S, RSC Adv, 8 (2018) 13323.

  • Saikia K, Bhattacharya K, Sen D, Kaushik S D, Biswas J, Lodha S, Gogoi B, Buragohain A K, Kockenberger W & Deb P, Appl Surf Sci, 464 (2019) 567.

  • Cancado L, Takai K & Enoki T, Appl Phys Lett, 88 (2006) 163106.

  • Sharma P, Hussain N, Borah D J & Das M R, J Chem Eng Data, 58 (2013) 3477.

  • Langmuir I, J Am Chem Soc, 40 (1918) 1361.

  • Freundlich H M F, Z Phys Chem, 57 (1906) 385.

  • Weber T W & Chakravorti R K, J Am Inst Chem Eng, 20 (1974) 228.

  • Ai L H, Zhang C Y & Chen Z L, J Hazard Mater, 192 (2011) 1515.

  • Lin Y F, Chen H W, Lin K L, Chen B Y & Chiou C, J Environ Sci, 23 (2011) 44.


Abstract Views: 99

PDF Views: 60




  • Utilizing Reduced Graphene Oxide-Iron Nanoparticles Composite to Enhance and Accelerate the Removal of Methyl Blue Organic Dye in Wastewater

Abstract Views: 99  |  PDF Views: 60

Authors

Tilak Narayan Ghosh
Department of Electronics, Midnapore College (Autonomous), Midnapore 721 101, India
Sitangshu Sekhar Pradhan
Department of Physics, Midnapore College (Autonomous), Midnapore 721 101, India
Mainak Ray
R&D and Innovation, HPCL-Mittal Energy Ltd, Bhatinda (Punjab) 151 301, India
Barun Mondal
Department of Chemistry, Midnapore College (Autonomous), Midnapore 721 101, India
Subinoy Jana
Department of Chemistry, Midnapore College (Autonomous), Midnapore 721 101, India
Pallabi Paul
Department of Chemistry, IIT Guwahati, Assam 781 039, India
Salil Kumar Sarkar
Department of Physics, Midnapore College (Autonomous), Midnapore 721 101, India
Subhas Chandra Saha
Department of Electronics, Vidyasagar University, Midnapore 721 102, India

Abstract


In this work, a nano-composite is used to remove dye from wastewater of different industries. For this purpose, the synthesis of a magnetic 1:1 composite made of iron nanoparticles (NPs) using reduced graphene oxide is a novel technique and tested for Methyl Blue (MB) dye adsorption from aqueous solution. In this study Fe nanoparticles in reduced Graphene composite (FGOC) has been prepared using Graphene Oxide (GO). X-ray diffraction, FTIR spectroscopy and Raman spectroscopy, are used to identify the structures. Many methods have been developed for MB removal in wastewater. One of the most popular methods is adsorption because it is simple and high-efficiency, and the adsorbent is crucial. It reached a maximum MB adsorption at pH 7. The kinetic study indicated that the adsorption of MB process was fitted well to the quasi-first-order and quasi-second-order kinetic models. The isotherm study revealed that the MB adsorption process obeyed the Langmuir and Freundlich adsorption Isotherms models. The GO adding content and absorption conditions on the methyl blue removal efficiencies were investigated. This adsorbent is easily recovered by an external magnetic field from the treated wastewater and has high reusability.

Keywords


Nanoparticle, Graphene Oxide, Dye Removal, Kinetics of Adsorption, Adsorption Isotherm.

References