Indian Journal of Pure and Applied Physics

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Multiphysics Experimental Approaches for Insight into the Hydrogen Bonded Structures of Ethylene Glycol and Glycerol Mixtures toward Green Solvent Technology


Affiliations
1 Dielectric Research Laboratory, Department of Physics, Jai Narain Vyas University, Jodhpur 342 005, India
 

Alcohols and their mixtures are credited most important polar solvents for advances in pharmaceutical, chemical, biological, thermal, and material technologies. A rigorous study for the characterization of hydrogen bonded heterogeneous intermolecular structures that formed in a mixed solvent based on alcohols containing two and three hydroxyl groups molecules is crucial to specific technological and industrial applications. Hence, in this work, the multiphysics experimental approaches including the measurements of dielectric, electrical, viscous, acoustic, thermal, and optical properties are applied and analyzed to confirm the behaviour of hydrogen bonded molecular structures of ethylene glycol (EG; dihydric alcohol) with glycerol (Gl; trihydric alcohol) over the entire concentration range of EG+Gl mixtures at 298.15 K. The static dielectric permittivity, direct current electrical conductivity, low frequency relaxation time, and refractive index values of the EG+Gl mixtures are reported. Additionally, dynamic viscosity, density, ultrasound velocity, adiabatic compressibility, intermolecular free length, acoustic impedance, free volume, Rao’s constant, Wada constant, and viscoacoustic relaxation time of the EG+Gl mixtures are determined, and also explored their significance to these alcohols molecular interactions. Ultraviolet-visible range absorbance behaviour of the alcohol mixtures is characterized in detail and confirmed the electronic transitions at higher energy ultraviolet radiations. The detailed analysis of all the experimental results along with the consideration of excess properties evidenced the formation of heterogeneous intermolecular hydrogen bonded structures in these Newtonian-type alcohols mixtures. A small to adequate variation in the thermodynamical and other investigated properties with the concentration variation showed that the EG+Gl mixture can be optimized as a green solvent according to the prerequisite properties for huge advances in soft condensed matter technologies.

Keywords

Alcohols, Molecular Interaction, Dielectric Properties, Viscosity, Acoustic Parameters, UV-Vis Absorbance.
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  • Multiphysics Experimental Approaches for Insight into the Hydrogen Bonded Structures of Ethylene Glycol and Glycerol Mixtures toward Green Solvent Technology

Abstract Views: 460  |  PDF Views: 88

Authors

Mukul Saraswat
Dielectric Research Laboratory, Department of Physics, Jai Narain Vyas University, Jodhpur 342 005, India
R J Sengwa
Dielectric Research Laboratory, Department of Physics, Jai Narain Vyas University, Jodhpur 342 005, India

Abstract


Alcohols and their mixtures are credited most important polar solvents for advances in pharmaceutical, chemical, biological, thermal, and material technologies. A rigorous study for the characterization of hydrogen bonded heterogeneous intermolecular structures that formed in a mixed solvent based on alcohols containing two and three hydroxyl groups molecules is crucial to specific technological and industrial applications. Hence, in this work, the multiphysics experimental approaches including the measurements of dielectric, electrical, viscous, acoustic, thermal, and optical properties are applied and analyzed to confirm the behaviour of hydrogen bonded molecular structures of ethylene glycol (EG; dihydric alcohol) with glycerol (Gl; trihydric alcohol) over the entire concentration range of EG+Gl mixtures at 298.15 K. The static dielectric permittivity, direct current electrical conductivity, low frequency relaxation time, and refractive index values of the EG+Gl mixtures are reported. Additionally, dynamic viscosity, density, ultrasound velocity, adiabatic compressibility, intermolecular free length, acoustic impedance, free volume, Rao’s constant, Wada constant, and viscoacoustic relaxation time of the EG+Gl mixtures are determined, and also explored their significance to these alcohols molecular interactions. Ultraviolet-visible range absorbance behaviour of the alcohol mixtures is characterized in detail and confirmed the electronic transitions at higher energy ultraviolet radiations. The detailed analysis of all the experimental results along with the consideration of excess properties evidenced the formation of heterogeneous intermolecular hydrogen bonded structures in these Newtonian-type alcohols mixtures. A small to adequate variation in the thermodynamical and other investigated properties with the concentration variation showed that the EG+Gl mixture can be optimized as a green solvent according to the prerequisite properties for huge advances in soft condensed matter technologies.

Keywords


Alcohols, Molecular Interaction, Dielectric Properties, Viscosity, Acoustic Parameters, UV-Vis Absorbance.

References