Indian Journal of Pure and Applied Physics

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Gd anchored Bismuth Ferrite: Investigations on Structural and Optical Properties


Affiliations
1 Department of Physics, Materials Analysis and Research Laboratory, NSUT, Dwarka, New Delhi 110 078, India
2 Department of Physics, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Haryana 131 039, India
3 Department of Physics, Maharshi Dayanand University, Rohtak, Haryana 124 001, India
 

The potential of rare-earth doping to robust structural, magnetic, electric, and optical characteristics of bismuth ferrite (BFO) has prompted an enormous amount of interest in the field of materials science. Gd-substituted BFO were produced in this work utilizing Pechini’s modified Sol-Gel auto combustion technique. The development of a pure perovskite structure was confirmed by X-ray diffraction (XRD), with no secondary phases identified. The lattice parameters were observed to decrease as Gd concentration increased, showing that Gd ions were successfully incorporated into the BFO lattice. The microstructural characteristics of the produced NPs were investigated using the HRTEM to evaluate particle size and shape. UV-Vis spectroscopy was used to analyze the optical characteristics of the NPs, which revealed a reduction in optical bandgap with Gd substitution. The improved optical characteristics can be attributed to a change in the electronic band structure caused by Gd substitution. Overall, Gd-substituted BFO perovskites displays remarkable optical properties, indicating their potential use in optoelectronic devices and as a catalyst for the degradation of synthetic and organic dyes.

Keywords

Rare-earth doping; Sol-Gel auto combustion technique; Perovskites; Optoelectronic properties.
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  • Sahu A K, Satpathy S K, Rout S K & Behera B, Trans Electr Electron Mater, 21 (2020) 217.

  • Rhaman M M, Matin M A, Al Mamun M A, Hussain A, Hossain M N, Das B C, Hakim M A & Islam, M F, J Mater Sci Mater Electron, 31 (2020) 8727.

  • Sheoran N, Saini M, Kumar A, Kumar V, Kumar T & Sheoran M, MRS Adv, 4 (2019).

  • Das R, Sarkar T & Mandal K, J Phys D Appl Phys, 45 (2012).

  • Pandey R, Panda C, Kumar P & Kar M, J Sol-Gel Sci Technol, 85 (2018) 166.

  • Kumar S K, Ramu S, Sudharani A, Ramanadha M, Murali G & Vijayalakshmi R P, Phys E Low-Dimensional Syst Nanostruct, 115 (2020) 113689.

  • Arora M & Kumar M, Mater Lett, 137 (2014) 285.

  • Arti, Gupta R, Singh S P, Walia R, Kumar V & Verma V, J Alloys Compd, (2022) 908.

  • Guo R, Fang L, Dong W, Zheng F & Shen M, J Phys Chem C, 14 (2010) 21390.

  • Sharma A D & Sharma H B, J Mater Sci Mater Electron, 32 (2021) 20612.


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  • Gd anchored Bismuth Ferrite: Investigations on Structural and Optical Properties

Abstract Views: 91  |  PDF Views: 50

Authors

Sourabh Sharma
Department of Physics, Materials Analysis and Research Laboratory, NSUT, Dwarka, New Delhi 110 078, India
Sonia
Department of Physics, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Haryana 131 039, India
Harita Kumari
Department of Physics, Maharshi Dayanand University, Rohtak, Haryana 124 001, India
Ashok Kumar
Department of Physics, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Haryana 131 039, India
O. P. Thakur
Department of Physics, Materials Analysis and Research Laboratory, NSUT, Dwarka, New Delhi 110 078, India

Abstract


The potential of rare-earth doping to robust structural, magnetic, electric, and optical characteristics of bismuth ferrite (BFO) has prompted an enormous amount of interest in the field of materials science. Gd-substituted BFO were produced in this work utilizing Pechini’s modified Sol-Gel auto combustion technique. The development of a pure perovskite structure was confirmed by X-ray diffraction (XRD), with no secondary phases identified. The lattice parameters were observed to decrease as Gd concentration increased, showing that Gd ions were successfully incorporated into the BFO lattice. The microstructural characteristics of the produced NPs were investigated using the HRTEM to evaluate particle size and shape. UV-Vis spectroscopy was used to analyze the optical characteristics of the NPs, which revealed a reduction in optical bandgap with Gd substitution. The improved optical characteristics can be attributed to a change in the electronic band structure caused by Gd substitution. Overall, Gd-substituted BFO perovskites displays remarkable optical properties, indicating their potential use in optoelectronic devices and as a catalyst for the degradation of synthetic and organic dyes.

Keywords


Rare-earth doping; Sol-Gel auto combustion technique; Perovskites; Optoelectronic properties.

References