Indian Journal of Pure and Applied Physics

Open Access Open Access  Restricted Access Subscription Access

Study on Structural and Dielectric Properties of (Ti, Cr) Co-doped SnO2 Nanoparticles


Affiliations
1 Department of Physics, Institute of Integrated and Honors Studies, Kurukshetra University, Kurukshetra, Haryana 136 119, India
2 Department of Physics, Kurukshetra University, Kurukshetra, Haryana 136 119, India
 

The present study deals with the impact of (Ti, Cr) co-doping on the structural, optical, and dielectric properties of the SnO2 nanoparticles. The traditional solid-state reaction route is adopted to prepare undoped, Ti-doped and (Ti, Cr) co-doped SnO2 nanoparticles. The structural analysis revealed the polycrystalline nature with a single phase of tetragonal rutile type structure for all the prepared samples. The increment in the crystallite size is observed with doping. The Scanning electron microscopy showed that the nanoparticles are spherical and uniformly distributed. A small variation is noticed in the optical band gap energy of doped samples as compared to the undoped SnO2. The significant changes have been reported in parameters such as dielectric function, capacitance, dielectric loss factor, and AC conductivity. Maxwell-Wagner model is suitable to illustrate the decreasing behaviour of dielectric constant and dielectric loss with frequency. Ti and Cr co-doped SnO2 nanoparticles revealed lower dielectric loss contrary to Ti-doped and undoped SnO2 nanoparticles. The ac conductivity of all the prepared samples increases with frequency and doping. Ti-doped SnO2nanoparticles exhibited higher ac conductivity, which can be explained by the hopping of charge carriers.

Keywords

Co-doping; Structural analysis; Crystallite size; Maxwell-wagner model; Dielectric constant.
User
Notifications
Font Size

  • Snaith H J & Ducati C, Nano Lett, 10 (2010) 1259.

  • Azam A, et al., J Alloys Compd, 506 (2010). 237.

  • Pandian S K, et al., Mater Manuf Process, 27 (2012) 130.

  • Tagreed M, et al., Energy Procedia, 157 (2019) 457.

  • Ahmed A, et al., Mater Sci Eng, 577 (2019) 012041.

  • Jahnavi V S, et al., J Electron Mater, 49 (2020) 3540.

  • Mehraj S & Ansari M S, Phys. E Low-dimensional Syst Nanostruct, 65 (2015) 84.

  • Wan N, et al., Scientific Reports, 6 (2016) 1.

  • Narzary R, et al., Mater Sci Semicond Process, 142 (2022) 106477.

  • Duhan M, et al., Vacuum, 181 (2020) 109635.

  • Gopinadhan K, et al., J Appl Phys, 102 (2007) 113513.

  • Kuppan M, et al., Adv Condens Matter Phys, 2014 (2014).

  • Ahmed A, et al., Appl Surf Sci, 483 (2019) 463.

  • Subramanyam K, et al., Solid State Sci, 39 (2015) 74.

  • Lachore W L, et al., Appl Phys A, 128 (2022) 515.

  • Ahmed R, et al., Mater Res Bull, 63 (2015) 32.

  • Rajwali K & Fang M H, Chin Phys B, 24 (2015) 127803.

  • Sahay P P, et al., Curr Appl Phys, 13 (2013) 479.


Abstract Views: 89

PDF Views: 48




  • Study on Structural and Dielectric Properties of (Ti, Cr) Co-doped SnO2 Nanoparticles

Abstract Views: 89  |  PDF Views: 48

Authors

Sangeeta
Department of Physics, Institute of Integrated and Honors Studies, Kurukshetra University, Kurukshetra, Haryana 136 119, India
Anju Dutt
Department of Physics, Institute of Integrated and Honors Studies, Kurukshetra University, Kurukshetra, Haryana 136 119, India
Harpreet Singh
Department of Physics, Institute of Integrated and Honors Studies, Kurukshetra University, Kurukshetra, Haryana 136 119, India
Anand Kumar
Department of Physics, Institute of Integrated and Honors Studies, Kurukshetra University, Kurukshetra, Haryana 136 119, India
Amit Kumar
Department of Physics, Kurukshetra University, Kurukshetra, Haryana 136 119, India

Abstract


The present study deals with the impact of (Ti, Cr) co-doping on the structural, optical, and dielectric properties of the SnO2 nanoparticles. The traditional solid-state reaction route is adopted to prepare undoped, Ti-doped and (Ti, Cr) co-doped SnO2 nanoparticles. The structural analysis revealed the polycrystalline nature with a single phase of tetragonal rutile type structure for all the prepared samples. The increment in the crystallite size is observed with doping. The Scanning electron microscopy showed that the nanoparticles are spherical and uniformly distributed. A small variation is noticed in the optical band gap energy of doped samples as compared to the undoped SnO2. The significant changes have been reported in parameters such as dielectric function, capacitance, dielectric loss factor, and AC conductivity. Maxwell-Wagner model is suitable to illustrate the decreasing behaviour of dielectric constant and dielectric loss with frequency. Ti and Cr co-doped SnO2 nanoparticles revealed lower dielectric loss contrary to Ti-doped and undoped SnO2 nanoparticles. The ac conductivity of all the prepared samples increases with frequency and doping. Ti-doped SnO2nanoparticles exhibited higher ac conductivity, which can be explained by the hopping of charge carriers.

Keywords


Co-doping; Structural analysis; Crystallite size; Maxwell-wagner model; Dielectric constant.

References