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XRD, Electrical, Mechanical, Second and Third-Order NLO Studies of L-Leucinium Perchlorate Crystal


Affiliations
1 Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai- 627002, Tirunelveli, Tamilnadu, India
2 PG and Research Department of Physics, Sri Paramakalyani College, Alwarkurichi, Tenkasi, Tamilnadu 627 412 (Affilated to Manonmaniam Sundaranar University Tirunelveli, 627 012, Tamil Nadu India), India
3 Sri Paramakalyani College, Alwarkurichi, Tenkasi, Tamilnadu 627 412 (Affilated to Manonmaniam Sundaranar University Tirunelveli, 627 012, Tamil Nadu India), India

L-Leucine and Perchloric Acid were combined in a 1:1 molar ratio to synthesize L-Leucinium Perchlorate (LLPC) salt,which was subsequently grown into single crystals using a solution method and slow evaporation process. Characterization of the LLPC crystal involved techniques including single crystal X-ray diffraction (XRD), mechanical analysis, dielectric studies, Second Harmonic Generation (SHG) study, Z-scan study, and LDT study. SHG efficiency of the sample, was found to exceed that of potassium dihydrogen orthophosphate (KDP). Mechanical properties such as hardness, yield strength, work hardening coefficient, and stiffness constant were determined for the crystal. XRD analysis confirmed monoclinic crystallization of the LLPC crystal. The findings from numerous investigations were examined and discussed in this paper.

Keywords

NLO; Amino acid complex; Solution growth; Single crystal; Characterization; XRD; NLO; Vicker’s hardness; LDT; Z-scan
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  • XRD, Electrical, Mechanical, Second and Third-Order NLO Studies of L-Leucinium Perchlorate Crystal

Abstract Views: 60  | 

Authors

M. Arul Tresa
Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai- 627002, Tirunelveli, Tamilnadu, India
B. Helina
PG and Research Department of Physics, Sri Paramakalyani College, Alwarkurichi, Tenkasi, Tamilnadu 627 412 (Affilated to Manonmaniam Sundaranar University Tirunelveli, 627 012, Tamil Nadu India), India
S. C. Vella Durai
Sri Paramakalyani College, Alwarkurichi, Tenkasi, Tamilnadu 627 412 (Affilated to Manonmaniam Sundaranar University Tirunelveli, 627 012, Tamil Nadu India), India

Abstract


L-Leucine and Perchloric Acid were combined in a 1:1 molar ratio to synthesize L-Leucinium Perchlorate (LLPC) salt,which was subsequently grown into single crystals using a solution method and slow evaporation process. Characterization of the LLPC crystal involved techniques including single crystal X-ray diffraction (XRD), mechanical analysis, dielectric studies, Second Harmonic Generation (SHG) study, Z-scan study, and LDT study. SHG efficiency of the sample, was found to exceed that of potassium dihydrogen orthophosphate (KDP). Mechanical properties such as hardness, yield strength, work hardening coefficient, and stiffness constant were determined for the crystal. XRD analysis confirmed monoclinic crystallization of the LLPC crystal. The findings from numerous investigations were examined and discussed in this paper.

Keywords


NLO; Amino acid complex; Solution growth; Single crystal; Characterization; XRD; NLO; Vicker’s hardness; LDT; Z-scan