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Effect of Cross-linking Systems on the Thermal Behaviour of Nylon Copolymer (PA6,66) and Ethylene-Propylene-Diene (EPDM) Rubber Blends and their Kinetic Analysis


Affiliations
1 S N M College, Maliankara- 683 513, Kerala, India
2 Department of PS&RT, Cochin University of Science and Technology, Cochin - 682 022, Kerala, India
3 School of Chemical Science, M.G University, Kottayam - 686 560, Kerala, India
4 Central Power Research Institute, Bengaluru - 560 080, Karnataka, India
     

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The thermal stability of nylon 6,66 and ethylene-propylene-diene rubber of dynamically vulcanised blends were studied by thermogravimetric analysis. The composition of nylon copolymer and EPDM was fixed at 70/30 ratio by weight. The blends were prepared by melt mixing in a Brabender Plasticorder. Thermogravimetric analysis showed that the decomposition proceeds through a single step even though the blends are immiscible and the cross-linked blends were more thermally stable than uncross-linked blends. The kinetic parameter of the degradation process is also studied.

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  • Effect of Cross-linking Systems on the Thermal Behaviour of Nylon Copolymer (PA6,66) and Ethylene-Propylene-Diene (EPDM) Rubber Blends and their Kinetic Analysis

Abstract Views: 218  |  PDF Views: 0

Authors

Cibi Komalan
S N M College, Maliankara- 683 513, Kerala, India
K. E. George
Department of PS&RT, Cochin University of Science and Technology, Cochin - 682 022, Kerala, India
S. Thomas
School of Chemical Science, M.G University, Kottayam - 686 560, Kerala, India
K. T. Varughese
Central Power Research Institute, Bengaluru - 560 080, Karnataka, India

Abstract


The thermal stability of nylon 6,66 and ethylene-propylene-diene rubber of dynamically vulcanised blends were studied by thermogravimetric analysis. The composition of nylon copolymer and EPDM was fixed at 70/30 ratio by weight. The blends were prepared by melt mixing in a Brabender Plasticorder. Thermogravimetric analysis showed that the decomposition proceeds through a single step even though the blends are immiscible and the cross-linked blends were more thermally stable than uncross-linked blends. The kinetic parameter of the degradation process is also studied.

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DOI: https://doi.org/10.33686/prj.v4i2.189163