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Spectrophotometric Determination of Nitrate Ion in Presence of Chloride Matrix


Affiliations
1 Assistant Professor, Department of Chemistry, P.K.R. Arts College for Women, Gobichettipalayam – 638476, Tamil Nadu, India
 

89Sr a radionuclide used for bone pain palliation — is produced in Fast Breeder Test Reactor (FBTR) via the 89Y (n, p) 89Sr reaction. The final 89Sr source is obtained after processing the irradiated Y2 O3 target using nitric acid. The final product 89Sr is injected in HCl medium whose concentration must be 0.05–0.5M. The final product which was obtained after the chemical processing in the nitric acid is converted into its chloride form. The estimation of nitrate ion in the 89Sr source is an indication of i) the efficiency of the conversion and ii) the 89Sr source is free from the nitrate ion impurity. Hence it is necessary to determine the presence of nitrate in the product. So a method was developed in the laboratory to estimate the nitrate ion concentration in presence of bulk chloride ion concentration by spectrophotometric method.

Keywords

Spectrophotometry, Nitrate ion, Chloride matrix, Diazotization
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  • P. Nagaraj, N Gopalakrishna Bhat, K.G. Chandrashekara, International Journal of Chemical Studies, 2016, 4, 106109.

  • Raymond S. Lambert and Ronald J. DuBois, Hercules incorporated, Bacchus Works, Magna, Utah 84044.

  • K. Shanthi, N. Balasubramanian, Journal of AOAC International, 1994, 77, 1639-1646.

  • M.J. Moorcroft, J. Devis, R.G. Compton, Talanta, 2001, 54, 785-803.

  • G. Norwitz, D.N. Keliher, Analyst, 1984,109, 1281- 1286.

  • Badiadka Narayana, Kenchaiah Sunil, Eurasian Journal of Analytical Chemistry, 2009, 4, 204-214.

  • G.F. Chen, Y. Yuan, H. Jiang. et al, Nature Energy, 2020, 5, 605-613.

  • A. Consalteri, A. Rigato, L. Clamor, P. Giandon, Journal of Food Composition and Analysis, 1992, 5, 252-256.

  • B. Schazmann, D. Diamond, New Journal of Chemistry, 2007, 31, 587–592.

  • D. F. Boltz, M. G. Mellon, Analytical Chemistry, 1972, 44, 300-323.

  • Priyanka Singh, Manish Kumar Singh, Younus Raza Beg, Gokul Ram Nishad, Talanta, 2019, 191, 364-381.

  • R. L. Mulvaney, Methods of soil analysis: part 3 chemical methods, 2018, 5, 1123-1184.

  • O. A. Adegoke, O.M. Adegbolagun, E.O. Aiyenale , O. E. Thomas, Journal of Taibah University for Science, 2018, 12, 754-756.

  • P. Kurniawati, R. Gusrianti, B.B. Dwisiwi, T.E. Purbaningtias, B. Wiyantoko, AIP Conference Proceedings 1911, 2017, 020012.

  • J.R.E Thabano, D Abong’o, G.M Sawula, Journal of Chromatography A, 2004, 1045, 153-159.

  • Nafisur Rahman, Yasmin Ahmad, Syed Najmul Hejaz Azmi, S. A. J. Sulaiman, Journal of the Chinese Chemical Society, 2008, 55, 1357-1366.

  • R.A. Peterson, M. M. Metro, P. K. Hopke. International Journal of Environmental Analytical Chemistry, 1974, 3,185-190.

  • D.F. Boltz, J.L. Lambert, C R C Critical Reviews in Analytical Chemistry, 1973, 3, 147-199.


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  • Spectrophotometric Determination of Nitrate Ion in Presence of Chloride Matrix

Abstract Views: 519  |  PDF Views: 202

Authors

P. Rajalakshmi
Assistant Professor, Department of Chemistry, P.K.R. Arts College for Women, Gobichettipalayam – 638476, Tamil Nadu, India
G. Myvizhi
Assistant Professor, Department of Chemistry, P.K.R. Arts College for Women, Gobichettipalayam – 638476, Tamil Nadu, India

Abstract


89Sr a radionuclide used for bone pain palliation — is produced in Fast Breeder Test Reactor (FBTR) via the 89Y (n, p) 89Sr reaction. The final 89Sr source is obtained after processing the irradiated Y2 O3 target using nitric acid. The final product 89Sr is injected in HCl medium whose concentration must be 0.05–0.5M. The final product which was obtained after the chemical processing in the nitric acid is converted into its chloride form. The estimation of nitrate ion in the 89Sr source is an indication of i) the efficiency of the conversion and ii) the 89Sr source is free from the nitrate ion impurity. Hence it is necessary to determine the presence of nitrate in the product. So a method was developed in the laboratory to estimate the nitrate ion concentration in presence of bulk chloride ion concentration by spectrophotometric method.

Keywords


Spectrophotometry, Nitrate ion, Chloride matrix, Diazotization

References





DOI: https://doi.org/10.15613/sijrs%2F2019%2Fv6i2%2F209462