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Effect of Type Groups in Compounds State


Affiliations
1 Department of Chemistry, Iraq
     

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This paper involved preparation of two types of imine compounds differ in the type of terminal group, where one of them has a terminal carboxyl group COOH while the other contains methoxy OCH3 as a terminal group. In the first part of this research it was Identification by spectroscopy methods using infrared IR and nuclear magnetic resonance H NMR spectrum, besides elemental analysis shows the exact chemical structure of the expected synthesized compounds.

In the second part was the study of liquid-crystalline behavior by polarized optical microscopy POM and differential scanning calorimetry DSC that showed a liquid crystal phase in the compounds that has odd number of carbon atoms in the terminal chain compounds in the first series, while the second series compounds showed liquid crystal phase in the compounds that containing even number of atoms of carbon in the terminal chain.


Keywords

Part, Calomer, Termin.
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  • Effect of Type Groups in Compounds State

Abstract Views: 224  |  PDF Views: 2

Authors

Sajida H. Ridha
Department of Chemistry, Iraq
Dhia A. Hanoush
Department of Chemistry, Iraq

Abstract


This paper involved preparation of two types of imine compounds differ in the type of terminal group, where one of them has a terminal carboxyl group COOH while the other contains methoxy OCH3 as a terminal group. In the first part of this research it was Identification by spectroscopy methods using infrared IR and nuclear magnetic resonance H NMR spectrum, besides elemental analysis shows the exact chemical structure of the expected synthesized compounds.

In the second part was the study of liquid-crystalline behavior by polarized optical microscopy POM and differential scanning calorimetry DSC that showed a liquid crystal phase in the compounds that has odd number of carbon atoms in the terminal chain compounds in the first series, while the second series compounds showed liquid crystal phase in the compounds that containing even number of atoms of carbon in the terminal chain.


Keywords


Part, Calomer, Termin.