Asian Journal of Research in Chemistry

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Optical detection of Copper and Cadmium from Aqueous solution using Arylidenemalanonitriles


Affiliations
1 Department of Chemistry, Thiruvalluvar University, Vellore - 632115, India, India
2 Department of Chemistry, Thiruvalluvar University, Vellore - 632115, India., India
3 Department of Chemical Engineering, Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam, Chennai - 603110, India .i, India
4 Department of Chemical Engineering, Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam, Chennai - 603110, India., India
     

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We have synthesized new fluorescent organic molecules namely arylidene malanonitriles, through Knovenegal condensation reaction of aryl aldehydes and malanonitrile, which are capable of detectingCd2+and Cu2+ ions in water with sensitivity. The synthesized molecules are characterized through infrared spectrometry, high resolution Mass spectrometry and Nuclear Magnetic Resonance spectroscopy. The fluorescent organic molecules exhibited a fluorescent emission and significant UV-Vis absorption, the intensity of which is increased proportional to the addition of Cd2+ and Cu2+ ions. The lowest detection limit for the Cd2+and Cu2+ were found to be 2.0×10-10 M and 4×10-12 M, respectively.

Keywords

Knovenegal reaction, Malanonitrile, Fluorescent sensor, Photoluminescence, Heavy metal detection.
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  • Optical detection of Copper and Cadmium from Aqueous solution using Arylidenemalanonitriles

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Authors

R. Parkavi
Department of Chemistry, Thiruvalluvar University, Vellore - 632115, India, India
G. Madhan
Department of Chemistry, Thiruvalluvar University, Vellore - 632115, India., India
K. Srinivasan
Department of Chemistry, Thiruvalluvar University, Vellore - 632115, India., India
K. Sathishkumar
Department of Chemical Engineering, Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam, Chennai - 603110, India .i, India
A. Chandramohan
Department of Chemical Engineering, Sri Sivasubramaniya Nadar College of Engineering, Kalavakkam, Chennai - 603110, India., India
K. Dinakaran
Department of Chemistry, Thiruvalluvar University, Vellore - 632115, India, India

Abstract


We have synthesized new fluorescent organic molecules namely arylidene malanonitriles, through Knovenegal condensation reaction of aryl aldehydes and malanonitrile, which are capable of detectingCd2+and Cu2+ ions in water with sensitivity. The synthesized molecules are characterized through infrared spectrometry, high resolution Mass spectrometry and Nuclear Magnetic Resonance spectroscopy. The fluorescent organic molecules exhibited a fluorescent emission and significant UV-Vis absorption, the intensity of which is increased proportional to the addition of Cd2+ and Cu2+ ions. The lowest detection limit for the Cd2+and Cu2+ were found to be 2.0×10-10 M and 4×10-12 M, respectively.

Keywords


Knovenegal reaction, Malanonitrile, Fluorescent sensor, Photoluminescence, Heavy metal detection.

References