Asian Journal of Research in Chemistry

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Electroorganic Synthesis of Copper and Zinc Complexes with Novel Ligand Oxalic Acid


Affiliations
1 St. Xavier’s College, Department of Chemistry, Ranchi ., India
2 Redt. Professor of PG Department of Chemistry, Ranchi University, Ranchi., India
3 Redt. Associate Professor, R.L.S.Y College, Ranchi University, Ranchi., India
     

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A convenient electroorganic synthesis of divalent metal complexes of empirical formulation [ML2] (M (II) = Cu and Zn; L= oxalic acid) were synthesized at sacrificial metal electrode anode. The metal, as the anode in an undivided cell, is oxidized in the presence of the parent compound of the ligand (HL) in an organic solvent mixture. Gram quantities of complex can be produced in a few hours. Complexes were characterized by elemental analysis, Infrared spectral data, Atomic Absorption spectroscopy and thermal spectral data. The geometrical structure of the synthesized complexes has been identified.

Keywords

Oxalic acid, Electroorganic, Atomic absorption spectroscopy, Infrared spectra, Sacrificial electrode.
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  • Electroorganic Synthesis of Copper and Zinc Complexes with Novel Ligand Oxalic Acid

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Authors

Shreya Gorai
St. Xavier’s College, Department of Chemistry, Ranchi ., India
M. Alam
Redt. Professor of PG Department of Chemistry, Ranchi University, Ranchi., India
B. H Gorai
Redt. Associate Professor, R.L.S.Y College, Ranchi University, Ranchi., India

Abstract


A convenient electroorganic synthesis of divalent metal complexes of empirical formulation [ML2] (M (II) = Cu and Zn; L= oxalic acid) were synthesized at sacrificial metal electrode anode. The metal, as the anode in an undivided cell, is oxidized in the presence of the parent compound of the ligand (HL) in an organic solvent mixture. Gram quantities of complex can be produced in a few hours. Complexes were characterized by elemental analysis, Infrared spectral data, Atomic Absorption spectroscopy and thermal spectral data. The geometrical structure of the synthesized complexes has been identified.

Keywords


Oxalic acid, Electroorganic, Atomic absorption spectroscopy, Infrared spectra, Sacrificial electrode.

References