Asian Journal of Research in Chemistry

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Adsorption Performance and Reuse Potential of a Green Alga for the removal of an Acidic dye from Synthetic Wastewater


Affiliations
1 Assistant Professor, BFIT Group of Institutions, Dehradun, Uttarakhand ., India
2 Associate Professor, KLDAV PG College, Roorkee, Distt. Haridwar, Uttarakhand., India
     

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In the present study a Charophyta green alga Chara sp. has been proven to be a very effective and promising adsorbing biomass for the removal of an acidic dye, Methyl Orange [MO] from synthetic wastewater. Adsorption efficiency of alga was studied as a function of various operative variables, such as the contact time to reach equilibrium, pH of an aqueous solution, adsorbent dosage, and temperature for dye removal. The experimental data were analyzed by Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich (D-R) models of adsorption isotherms, and best fit results were found for the Langmuir isotherm model, based on its correlation coefficient values. Pseudo-first-order and Pseudo-second-order kinetic models were applied to describe the adsorption process. It was found that the adsorption of methyl orange could be best described by the pseudosecond-order model. Values of Gibbs free energy (ΔG), entropy ((ΔS), and enthalpy change (ΔH) indicated the spontaneity, randomness, and endothermic nature of the reaction. FTIR studies showed the involvement of carboxyl, hydroxyl, and amide groups in the adsorption process. SEM micrographs displayed the morphological changes on the adsorbent surface, and BET analysis determined the surface area. To check the adsorbent reusability, repeated adsorption-desorption experiments were carried out for five consecutive cycles. The result shows that Chara sp. could be an effectual and reasonable adsorbent material for the management of MObearing wastewater.

Keywords

Chara sp., Methyl Orange, Adsorption Isotherms, Kinetic models, Synthetic wastewater
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  • Mahtout S, Tariket Y, Electronic and magnetic properties of CrGen (15 ≤ n ≤ 29) clusters: a DFT study. Chem Phys. 2016; 472:270-277. doi.org/10.1016/j.chemphys.2016.03.011

  • Xue-Qing Gong, Annabella Selloni, Olga Dulub, Peter Jacobson, Ulrike Diebold, Small Au and Pt Clusters at the Anatase TiO2(101) Surface: Behavior at Terraces, Steps, and Surface Oxygen Vacancies, J. Am. Chem. Soc. 2008; 130(1): 370-381, doi.org/10.1021/ja0773148

  • Giulia Rossi and Riccardo Ferrando, Global optimization of bimetallic cluster structures. II. Size-matched Ag-Pd, Ag-Au, and Pd-Pt systems, J. Chem. Phys. 2005;122(19):194309.doi.org/10.1063/1.1898224

  • Madhusudhanan J and Sathishkumar K, Gold Nanoparticle for Protein Delivery, Research J. Engineering and Tech. 2013; 4(4):260-263. doi: ijersonline.org/AbstractView.aspx?PID=20134-4-27

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  • Research Chem. 2011; 4(1):58-63.doi not Available

  • Ketan B. Patil, Narendra B. Patil, Sushmita V. Patil, Vaishnavi K. Patil, Pratik C. Shirsath, Metal based Nanomaterial’s (Silver and Gold): Synthesis and Biomedical application, Asian J. Pharm.

  • Tech. 2020; 10(2):97-106. doi: 10.5958/2231-5713.2020.00018.5

  • Sivasankari G, Boobalan S, Deepa D, Dopamine sensor by Gold Nanoparticles Absorbed Redox behaving metal Complex, Asian J.Pharm. Tech. 2018; 8 (2):83-87. doi: 10.5958/22315713.2018.00013.2

  • Yadav OP, Garg VK, Yadav YK, Daoutsali Eleni, Study on Catalytic Oxidation of Carbonmonoxide over Nano-Size Platinum + Alumina Composite, Asian J. Research Chem. 2011;4(6):10051008.doi. ajrconline.org/AbstractView.aspx?PID=2011-4-6-35

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  • Saudagar RB, Kanchan T. Mandlik, A Review on Gold Nanoparticles, Asian J. Pharm. Res. 2016; 6(1):45-48.doi: 10.5958/2231-5691.2016.00008.3

  • Gabriel UG, Reber AC, Khanna SN, Electronic subshell splitting controls the atomic structure of charged and neutral silver clusters. New. J. Chem. 2013;37(12):3928. doi.10.1039/C3NJ01075A.

  • Soler JM, Artacho E, Gale JD, Garcıa A, Junquera J, Ordejon P,. Sanchez-Portal D, J. Phys. Condens. Matter. 2002;14 :2745. doi.org/10.1088/0953-8984/14/11/302

  • Troullier N, Martins JL, Efficient pseudopotentials for plane-wave calculations., Phys Rev B Condens Matter; 1991; 43(11):88618869. doi: 10.1103/physrevb.43.8861.

  • Chang Q. Sun, Wang Y, Tay BK, Li S, Huang H, and Zhang Y.B, Correlation between the melting point of a nanosolid and the cohesive energy of a surface atom, 2002, J. Phys. Chem. B 2002, 106(41): 10701-10705.doi.org/10.1021/jp025868l

  • Ceperley DM and. Alder BJ, Ground State of the Electron Gas by a Stochastic Method, Phys. Rev. Lett. 1980; 45(566), doi.org/10.1103/PhysRevLett.45.566.

  • Peng Shao, Xiao Yu Kunag and YaRu Zhao,Structral, electronic and magentic of gold cluster doped with calcium AunCa(n=1-8), Molecular Physics. 2011;109(2):315-323.10.1080/00268976.2010.521778

  • Nijamudheen A, Ayan Datta, Effects of Charging on the Structural and Electronic Properties of Aun Nanoclusters (n = 2-20), cluster chemistry (2011). International Conference on Nanoscience,

  • Technology and Societal Implications.

  • Yu X, Zhang X, Wang S and Feng G, Adsorption of Aun (n = 1–4) clusters on Fe3O4(001) B-termination, RSC. Adv. 2015; 5(56) 45446-45453.doi. not Available ,


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  • Adsorption Performance and Reuse Potential of a Green Alga for the removal of an Acidic dye from Synthetic Wastewater

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Authors

Surabhi Sagar
Assistant Professor, BFIT Group of Institutions, Dehradun, Uttarakhand ., India
Arshi Rastogi
Associate Professor, KLDAV PG College, Roorkee, Distt. Haridwar, Uttarakhand., India

Abstract


In the present study a Charophyta green alga Chara sp. has been proven to be a very effective and promising adsorbing biomass for the removal of an acidic dye, Methyl Orange [MO] from synthetic wastewater. Adsorption efficiency of alga was studied as a function of various operative variables, such as the contact time to reach equilibrium, pH of an aqueous solution, adsorbent dosage, and temperature for dye removal. The experimental data were analyzed by Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich (D-R) models of adsorption isotherms, and best fit results were found for the Langmuir isotherm model, based on its correlation coefficient values. Pseudo-first-order and Pseudo-second-order kinetic models were applied to describe the adsorption process. It was found that the adsorption of methyl orange could be best described by the pseudosecond-order model. Values of Gibbs free energy (ΔG), entropy ((ΔS), and enthalpy change (ΔH) indicated the spontaneity, randomness, and endothermic nature of the reaction. FTIR studies showed the involvement of carboxyl, hydroxyl, and amide groups in the adsorption process. SEM micrographs displayed the morphological changes on the adsorbent surface, and BET analysis determined the surface area. To check the adsorbent reusability, repeated adsorption-desorption experiments were carried out for five consecutive cycles. The result shows that Chara sp. could be an effectual and reasonable adsorbent material for the management of MObearing wastewater.

Keywords


Chara sp., Methyl Orange, Adsorption Isotherms, Kinetic models, Synthetic wastewater

References